$QDOLVDGRU GH2[LJrQLR GH &RPEXVWmR (QRWHF 86$ (QJHQKDULD (QJH]HU 5LRGH-DQHLUR $FRQWHFLPHQWRV $:HVWLQJKRXVH (OHWULF &RUSIRLSLRQHLUDQR2LQVLWXFRPRSDUWHGR SURJUDPDHVSDFLDO$SROORGHGHVHQYROYLPHQWRGHFpOXODVFRPEXVWtYHLV HP 0DLVWDUGHD:HVWLQJKRXVH (OHWULF &RUS IRUPRXD'LYLVmRGH&RQWUROH GH&RPEXVWmRFRPVHGHHP2UYLOOH2KLR )RFDGDSULQFLSDOPHQWHQRSURGXWRSDUDSODQWDVGHHQHUJLDDFDUYmR 9HQGHXPDLVGHXQLGDGHVHPWRGRRPXQGR 4XDVHHVWmRQRPHUFDGRQRUWHDPHULFDQRQRPHUFDGR HXURSHXHQR([WUHPR2ULHQWH :HVWLQJKRXVH &&'GHL[RXRQHJyFLRHP 4XHP p D(QRWHF" 8PDSHTXHQDFRPSDQKLDSULYDGDLQLFLDGDHP (PHUJLXGDGLYLVmRGHFRQWUROHGH&RPEXVWmRGD :HVWLQJKRXVH (OHWULF &RUS 0DWUL]ORFDOL]DGDHP0DULHQKHLGH $OHPDQKDFRP HVFULWyULRVQRV(8$5HLQR8QLGR&LQJDSXUD XVDQGRXPDUHGHJOREDOGHGLVWULEXLomR HVSHFLDOL]DGD IRFDGDQRQHJyFLRGHFRPEXVWmRGH2 1yV)DEULFDPRVSURGXWRVSDUDXVXiULRVILQDLVH UyWXORSUySULRSDUDDOJXPDVHPSUHVDV%OXH&KLS *OREDLV 4XDO p RQRVVR QHJyFLR" 2QHJyFLR GHHFRQRPLD GHHQHUJLD« 8WLOL]DQGRFpOXODVLQVLWX GH]LUF{QLDFRPRVHQVRUGHR[LJrQLR SDUDPHGLURH[FHVVRGRPHVPRSDUDRWLPL]DURSURFHVVRGH FRPEXVWmRSDUDDWLQJLUXPDPLVWXUDLGHDOFRPEXVWtYHO$USDUD RVSURFHVVRVGHJUDQGHPpGLRHSHTXHQRSRUWHXWLOL]DQGRWRGRV RVWLSRVGHFRPEXVWtYHLVSDUDUHGX]LUFXVWRVHPLQLPL]DUDV HPLVV}HVGHSROXLomRSUHMXGLFLDO 3URGXWRV (QRWHF« 6LVWHPDV (FRQ{PLFRV 0RGHO .(6VHULHV .,6VHULHV .(;VHULHV 60(HOHFWURQLFV 8QLGDGH EiVLFD VHP IUHVFXUDV 6LVWHPDGHFDOGHLUD SHTXHQD 6LVWHPDGH2 FRPSULPHQWRVGLVSRQtYHLV 6LVWHPD GH2 ,QFRQHO (; 8QLGDGHV 0LFURSURFHVVDGDV HP FDL[DV GHDoR SDUD UDFN HSDUD (; (127(&'HVFULomRJHUDOGRVSURGXWRVGH DQiOLVHGHR[LJrQLR,QVLWX OXITEC-ECONOMY O2 Sistema analisador para pequenas aplicações OXITEC 5000 O2-Sistema analisador de usinas Termoelétricas OXITEC 132 O2- Sistema analisador para aplicações médias OXITEC 5000 O2-Sistema analisador para áreas perigosas 2[LJrQLR &RPEXVWmR« 2[LJrQLRp DIRQWHGHWRGDYLGD 6HPR[LJrQLRQmRKi YLGDRXFRPEXVWmR 1RDUTXHUHVSLUDPRVH[LVWHXPYDORUQRPLQDOGHR[LJrQLR FRPREDODQoRFRPSRVWRSULQFLSDOPHQWHGH QLWURJrQLRJiVHV LQHUWHVHXPLGDGH &RPEXVWmRp EDVLFDPHQWHXPSURFHVVRGHR[LGDomR$ FRPELQDomRGHFRPEXVWtYHOHDUR[LJrQLRSDUDSURGX]LU FDORU 2LGHDOp TXHWRGRRFRPEXVWtYHOHWRGRRR[LJrQLRVH FRPELQHPSDUDSURGX]LUFDORU1RHQWDQWRp HVVHQFLDO TXHWRGRRFRPEXVWtYHOVHMDTXHLPDGRSDUDPD[LPL]DUD SURGXomRGHFDORUHUHGX]LUDVHPLVV}HVSUHMXGLFLDLV 3RUWDQWRDPHGLomRH[DWDGDSURSRUomRDUFRPEXVWtYHOp GHH[WUHPDLPSRUWkQFLDSDUDDFRPEXVWmRHILFLHQWH 2DUHPH[FHVVRp LGHDOSDUDXPD FRPEXVWmRRWLPL]DGD A eficiência de 100%, ideal de um processo de combustão é atingido, se a concentração de combustíveis, bem como de O2 é zero (ponto estequiométrico). Na prática, não é possível chegar a este ponto, porque o queimador e o design das caldeiras possuem menos de 100% de eficiência. Portando, uma área alvo de 1-2% de O2 é uma zona desejável em função do combustível utilizado Os valores constituem exemplos a partir de um carvão 300 unidades MW Uma quantidade de O2 superior a 2% conduz a um efeito resfriador desnecessário. Uma diminuição da quantidade de O2 inferior a 1% resulta na combustão incompleta e crescente volume de moléculas inflamáveis não queimadas! O ponto ideal de medição Material resistente ao calor e caro é necessário, escórias de fluidos podem grudar na sonda de medição. Problemas de alta estratificação O combustível não queimado não está totalmente oxidado Erros de medição por, possíveis vazamentos de ar. Mistura de gases de combustão está muito melhor do que nas zonas mais quentes acima. Nenhum vazamento de ar do pré-aquecedor de ar Exemplo: caldeira de carvão 300MW com a tecnologia do queimador tipo ciclone 2;,7(& ,QVWDODomR HFRQILJXUDomR GRVLVWHPD 'XWRVGRVJDVHVGHFRPEXVWmR 3RUFHQWDJHPGRVYDORUHVGHR[LJrQLRHPXPGXWRWtSLFRGRVJDVHVGH FRPEXVWmRFRPHVWUDWLILFDomRQDVDtGDGRGXWRGDFDOGHLUDFRPGLYHUVDV FDUJDV 6m 8m 7HFQRORJLDGH&pOXODVGH=LUFRQLD =U2 $HTXDomRGH1HUQVW :DOWKHU+HUPDQQ1HUQVWDJHG P1 R mV = .T .Log 10 ( ) + Cmv P2 4F 5 *iV &RQVWDQWH ) )DUDGD\VFRQVWDQWH 3 5HIHUrQFLD GR$U FRQVWDQWH23UHVVmR 3DUFLDO 3 *iV GHFDOLEUDomR SURFHVVR YDULDYpO23UHVVmR 3DUFLDO &PY &RQVWDQWH GD &pOXOD WHUPRSDUHVGHHIHLWRVGDFRQVWUXomR 7 7HPSHUDWXUDGDFpOXODFRQVWDQWH *UiILFRGH(TXDomR1HUQVW 20.95% 209,500 ppm T 6DtGDGHFpOXODWtSLFD P9'pFDGD 2.095% 20,950 ppm Log 10 O2 Escala 0.2095% 2,095 ppm 0.02095% 209 ppm 0.002095% 20 ppm P9 P9 P9 P9 &pOXODVRVLQDOGHVDtGDHPPLOLYROWV &iOFXOR1HUQVW &iOFXORGDWHPSHUDWXUDYHUGDGHLUDGDFpOXOD R P1 mV = .T.Log10( ) +Cmv 4F P2 6RQGDp SUpDTXHFLGDD &GDWHPSHUDWXUDRSHUDFLRQDO *iVWHVWHp XPDUGHLQVWUXPHQWR2 P9 7HVWHGH*iVHVWi 2HPHTXLOtEULR1 P9 7RWDOFRQVWDQWHGDFpOXOD&09 P9 mV = 0.0496.T .Log 10( T= T = P1 ) P2 Mv .0496 xLog 10 ..2095 0208 52 .58 .0496 x 1 .00312 7 JUDXV .HOYLQ 7 °&± 9HUGDGHLURVFiOFXORGHWHPSHUDWXUDGH]LUF{QLD 7HPSHUDWXUDGHRSHUDomRFHOXODU 7HPSHUDWXUDWHyULFDGDFpOXODp GH & $WXDOp & $YDULDomRp & 1RWDPXLWR LPSRUWDQWH ,VVRVy SRGHVHUFRQVHJXLGRVHDFpOXOD GHWHPSHUDWXUDGH]LUF{QLDSRVVXLU XPDSURYDGHJiVHPGD FRQVWUXomRGH*ROG %UD]HG &RPRDVFpOXODV GH]LUF{QLD WUDEDOKDP" 115v Elemento Aquecedor Vedação Gold Braze T/C Processos secundários 3% O2 Célula de Zircônia Reference Air Side 20.95% O2 Catalisador de platina Eletrodo superficial Sinal de Fio de saída MV Almofada Contato de platina Corpo em aço inoxidável 2[LWHF 0RQWDJHPLQWHUQDGD6RQGD +DVWHGH&HUkPLFD 6XSRUWH GRDTXHFHGRU (OHPHQWR $TXHFHGRU 7HUPRSDUHV . &DER GHVLQDO 7XERGHDUGHUHIHUrQFLD 3Up0RQWDGR &DOLEUDo}HV 2[LWHF« $HTXDomRGH1HUQVW SRVVXLWRGDVFRQVWDQWHV 1HQKXPDIXQomRQDHTXDomRGDYLGD~WLO 6HPWHPSRFDOLEUDJHPPHQFLRQDGR 1mRPHQFLRQDGRRWDPDQKRGDVFpOXODV 4XDLVDVPXGDQoDVQDFDOLEUDomR" R 7HPSHUDWXUDFHOXOD )XQomRGRVFRPSRQHQWHVHOHWU{QLFRV R &pOXODFRQVWDQWH )XQomRGDVFRQGLo}HVGHSURFHVVRDRORQJRGRWHPSR &RPRRVHOHWURGRVGDFpOXODVPXGDPTXLPLFDPHQWHDRORQJRGRWHPSRRFRQMXQWRGRV³HIHLWRVGRVWHUPRSDUHV´FRPDV PXGDQoDVGDFRQVWUXomRQRPHWDOGDVFpOXODVWRUQDQGRDFRQVWDQWHGDFpOXODPDLVQHJDWLYDV (127(&UHFRPHQGDFDOLEUDJHPXPDGXDVYH]HV SRUDQRVy(FRQRPL]DWHPSRGLQKHLURHPDLRU YLGD~WLODQDOLVDGRU $&pOXOD2[LWHF =U2 &pOXOD *ROG%UD]HG GD YHGDomR DR *iV & 7HPS (OHWURGRV GH3ODWLQD &RUSRHPDoRLQR[LGiYHO SDUDIXVRVGHIL[DomRQR IODQJH 7UDGXomRGRLQJOrVSDUD SRUWXJXrV 7DPSDGDFpOXODSDUD UHWHQomRGHFDORU 'LVFRSODQR 'HVLJQGHERWmR /RQJDH'XUiYHO 9LGDÒWLO 0/7HPFDPDGDGHRSomR FHOXOD 3RUTXHDVFpOXODVGH2VmRVXEVWLWXtGDV" ([LVWHPDSHQDVGXDVUD]}HVSHODVTXDLVDVFpOXODVGHR[LJrQLR GHYHPVHUWURFDGDV $FpOXODp TXHEUDGDILVLFDPHQWHGHYLGRDRXVRLQFRUUHWRRX iJXDQRDEDVWHFLPHQWRGHDUGHUHIHUrQFLDTXHEUDQGRD FpOXOD 2HOHWURGRGHSODWLQDQRODGRGRSURFHVVRIRLHVJRWDGRD FpOXODGH]LUF{QLDH[SRVWDRXRHOHWURGRGHSODWLQDWRUQRXVH EORTXHDGRFRPSURGXWRVGDFRPEXVWmR $VFpOXODV2[LWHF QRUPDOPHQWHSRGHPGXUDUHQWUHDQRV HPFRQGLo}HVQRUPDLVGHJiVGHFRPEXVWmR(OHVVmRPDLRUHV GRTXHDPDLRULDGDVFpOXODVWrPXQVHOHWURGRVPDLVJURVVRVH PDLVGXUDGRXURVFRPRXPDFRQVWUXomR~QLFDGR2[LWHF *DV 7LJKW JROG EUD]HG 'HVLJQ2;,7(& 'HVLJQGD &pOXOD *ROGEUD]HGJDVWLJKW 0/72SomR GHSURWHomRHQ[RIUHSDUDDOWD FRQFHQWUDomR &RQVWUXomR UREXVWDVRQGD DSURYD GHJiV 6RQGDWRWDOPHQWHUHSDUiYHOHPFDPSR 7RGDVDV3HoDV 'LVSRQLELOLGDGHGHSHoDVHPRQWDJHQV PRGXODUHV &RQVWUXomRGHWHFQRORJLDFRPSURYDGDGHXVR LQGXVWULDO :HVWLQJKRXVHHUDP RV SLRQHLURV 0DVD(127(&WrP PHOKRUDGR VLJQLILFDWLYDPHQWHR GHVLJQGHVHXV 0DWHULDLVHD FRQILDQoDGH H[HFXomR 6RQGD 2;,7(& 6RQGD .(6 .(6 6HHQFDL[DGLUHWR HPORFDLVHPVXD PDLRULDMi H[LVWHQWHV 7HPSHUDWXUD FHOXOD & )LOWUR GHPHWDO VLQWHUL]DGR 'HIOHWRU HP ³9´ DQRV GHJDUDQWLD (OHWU{QLFD 2;,7(& 60( 3DFRWHV HOHWU{QLFRV SDGUmR 'LVSOD\/&' 7HFODGR VLPSOHV &DL[D GHDoR &RQMXQWR GHDU LQWHUQR 9HUVmR GH5DFN³´ 9HUVmR DSURYD GH H[SORVmR 6HPLRX WRWDOPHQWH DXWRPiWLFR FDO 2So}HV +$57)) 2;,7(& 'LVSOD\(OHWU{QLFR 2;,7(& $SOLFDo}HV 7HUPRHOpWULFDV ,QFLQHUDGRUHV 3ODQWDV GHFLPHQWR 6LGHUXUJLFDV 3HWURTXtPLFR )iEULFDV GHSDSHO H FHOXORVH 9DQWDJHQV SDUD RV FOLHQWHV $(QRWHF PHOKRURXRVDQDOLVDGRUHVGHR[LJrQLRHP JDVHVGHFRPEXVWmRHVWmRFRPSOHWDPHQWH UHSDUiYHLVHPFDPSRFRPVXEVWLWXtYHLV&pOXODV $TXHFHGRUHV7&HSHoDVGRLQWHULRU 9DORUDSUHoRVDFHVVtYHLVHEDL[RFXVWRGH SURSULHGDGH DQRV GHJDUDQWLD FRPSOHWD ± SHoDV HPDQXWHQomR 6LPSOHVPRQWDJHP HP ORFDOH[LVWHQWH $MXVWH HHVTXHoD 2;,7(& &DUDFWHUtVWLFDV H9DQWDJHQV GRSURGXWR 3URMHWR WRWDO,QVLWX 6LVWHPD GHHQFDL[H HHVTXHoD 6HP ILOWURV SDUD OLPSDU 6HP MXQWDVSDUD YD]DPHQWR 7HPSRGH6HUYLoR PtQLPR /HLWXUDV SUHFLVDV /HLWXUDV FRQWtQXDV $SURSULDGRSDUDWRGRVRV FRPEXVWtYHLV ,GHDOHPFKDPLQpVVXMDVH HPSRHLUDGDV (OHPHQWR'LIXVRUHPPHWDO VLQWHUL]DGR GHIOHWRU9 GH*DUDQWLD GXUDQWH DQRV &DOLEUDJHQVPHQRV QHFHVViULDV /RQJDYLGD GD FpOXOD GH R[LJrQLR 0DLRU HFRQ{PLD GH FRPEXVWtYHO 0HQRUHV FXVWR GH PDQXWHQomR 5HGXomR GHFXVWRV RSHUDFLRQDLV %DL[R FXVWR GHSURSULHGDGH )iFLO PDQXWHQomR )iFLO GHPDQWHU &RQVWUXomR PRGXODU 0DQXDOGHHFRQRPLD PHOKRUDGR 2;,7(& SUHFLVmR GRVLVWHPD PHOKRU TXH GHOHLWXUD 1RUPDOPHQWHYH]HVPHOKRUGRTXHD FRQFRUUrQFLDFRPFpOXODGHFRQVWUXomR FLPHQWDGDUHDMXVWiYHO GD OHLWXUD 5HJUDV GHRXUR EiVLFDV $UHGXomRGHHPR[LJrQLRQDFRPEXVWmRHTXLYDOHD DSUR[LPDGDPHQWHGHHFRQRPLDGHFRPEXVWtYHOHHPLVV}HVUHGX]LGDV 0DQXDOGH(FRQRPLD 2;,7(& 0DQXDOGHHFRQRPLDFRPSUHFLVmRPHOKRUDGDGRDQDOLVDGRU2[LWHF Table currency values are in US Dollars. The Additional Savings referred to in the table below are based on full systems with +/- 0.2% Oxygen of Measured value compared to other Insitu Zirconium Cell devices with +/- 1% measured value error. Even greater savings are achievable when compared with other manufacturers offering +/- 3% of measured value. Higher Reading Measured Value Differential Operational OXITEC Oxygen Reading 0.2% Competition 1% Variance (Can be + 3%) Annual Fuel Bill Typical Payback $94,900,000 Period in Months Savings Per Month using Investment (4x3ft systems) OXITEC O2 Analyzers Annual Savings From Improved Efficiency $23,000 2.5% 0.005% 0.025% 0.020% $18,980 15 $1,582 2.6% 0.005% 0.026% 0.021% $19,739 14 $1,645 2.7% 0.005% 0.027% 0.022% $20,498 13 $1,708 2.8% 0.006% 0.028% 0.022% $21,258 13 $1,771 2.9% 0.006% 0.029% 0.023% $22,017 13 $1,835 3.0% 0.006% 0.030% 0.024% $22,776 12 $1,898 3.2% 0.006% 0.032% 0.026% $24,294 11 $2,025 3.5% 0.007% 0.035% 0.028% $26,572 10 $2,214 4.0% 0.008% 0.040% 0.032% $30,368 9 $2,531 4.5% 0.009% 0.045% 0.036% $34,164 8 $2,847 5.0% 0.010% 0.050% 0.040% $37,960 7 $3,163 Example : 560MW Coal fired utility using 4,000 tons coal per day Tons used per day Price per ton 4000 $65 Typical COMTEC Package Includes: Probe 3ft KES 5002 Std Head/sintered Metal Filter Sol Cal. Gas Valve in Probe Head Protection/Mounting Tube This example assumes proper installation of 4 systems and calibration with Reference Air & Certified known Oxygen Test Gas (typically 2.1% Oxygen in Nitrogen) Mounting Flange & Fittings SME 5 Microprocessor Electronics Integral "electronic" Air Set Cable & Tube 40ft 29DORU GRFOLHQWH &DUDFWHULVWLFDV &pOXODHPRSHUDo}HVPDLV TXHQWH (OHWURGRVGDVFpOXODVPDLV HVSHVVRV 5HI $UQRLQWHULRUGDFpOXOD 6ROGDGRFRPFpOXODDSURYDGH JiV &RPSDWtYHLVIODQJHV 7RGDVDVSHoDVGLVSRQtYHLV &RPSDWLELOLGDGHGHSHoDV DQRVGHJDUDQWLD 9DQWDJHQV 0DQWpPRVSRURVGDVFpOXODV OLPSRV 9LGD~WLOPDLVORQJD 5HVSRVWDGHSURFHVVRPDLV UiSLGR /HLWXUDVSUHFLVDV 5HWURILW 'LUHWR .LWVQmRGLVSHQGLRVR &RPSUHRTXHYRFrQHFHVVLWD 7UDQTLOLGDGHPHQWDO &RQFOXVmR $(127(&DSHUIHLoRRX RDQDOLVDGRU GHR[LJrQLR 6LPSOHVGHFRQILJXUDUHRSHUDU 6HPVXEVWLWXLo}HVGHFpOXODURWLQHLUDVQHFHVViULDV &RQVWUXomRUHVLVWHQWHHGXUiYHO 5HFXSHUiYHOQR&DPSR 7RGRVRVLWHQVFRPGLVSRQLELOLGDGHGHSHoDVGH UHSRVLomR 0HOKRUHVGRTXHGHSUHFLVmRGHOHLWXUD 0HQRUFXVWRGHSURSULHGDGH 9LGD~WLOPDLVORQJDHFRQILiYHO 6DWLVIDomRGRFOLHQWH (127(&,QF &RPSRUWDPHQWRGHXPDQDOLVDGRUGH$OWD TXDOLGDGHVHPFRPSURPLVVR 6HUJLR)HUUHLUD Rua Braúlio Cordeiro 730 Jacaré – Rio de Janeiro Tel.: 21 – 2128 5300 www.engezer.com.br