CARBONIFEROUS BLACK-SHALES and SHALE-GAS POTENTIAL in SOUTHWESTERN PORTUGAL Paulo FONSECA Nuno PIMENTEL Rui PENA DOS REIS Gabriel BARBERES AAPG – Europe Region Annual Conference & Exhibition Post-Conference Field-trip 20th -21st May 2015 Field Trip Guide Carboniferous Black-Shales and Shale-Gas Potential in Southwestern Portugal Paulo Fonseca Nuno Pimentel Rui Pena dos Reis Gabriel Barberes ISBN : 978-989-20-5741-5 CARBONIFEROUS BLACK-SHALES and SHALE-GAS POTENTIAL IN SOUTHWESTERN PORTUGAL This field trip will address the characterization and shalegas potential of Carboniferous units in southern Portugal. Most of the trip will be along wild coastal cliffs and beaches of the Southwest Coast Natural Park (PNSACV). We will look at deep marine turbiditic sequences, containing black-shales, affected by the variscan orogeny and low-grade metamorphism. Maturation and deformation issues are therefore crucial and will be discussed. We will also look at the Mesozoic cover, namely the impressive Carboniferous-Triassic unconformity (Telheiro beach) and Jurassic limestones (Carrapateira beach) which may eventually act as potential reservoir units for the Paleozoic gas. The trip will end with a short stop at Ponta da Piedade, with karstic cliffs, natural grottoes and arches. Main topics to be adressed: Carboniferous black-shales – lithostratigraphy, sourcerock potential, maturation and deformation. Mesozoic cover - reservoir potential of Triassic red-beds and Jurassic dolomites. LIST OF PARTICIPANTS Paulo Bizarro , Partex Oil and Gas Arkadiusz Buniak, ORLEN Upstream Ltd. Bizhu He, Chinese Academy of Geological Sciences Roger Higgs, Geoclastica Ltd. Nuno Ines, Partex Oil and Gas Fraser Keppie, Nova Scotia Department of Energy Piotr Krzywiec, Institute of Geological Sciences, PAS Carolina Libório, Galp Energia Gil Machado, Galp Energia Luca Mancinelli, Trinity College Dublin Mariusz Paszkowski, University of Silesia Magdalena Piatkowska, ORLEN Upstream Ltd. Agnieszka Pisarzowska, Institute of Geological Sciences, PAS Maciej Rybicki, University of Silesia Justyna Smolarek, University of Silesia Jaroslaw Zacharski, ORLEN Upstream Ltd. Hydrocarbon potential – unconventional and conventional, onshore and offshore, Algarve and Alentejo basins. 1 ITINERARY DAY 1 DAY 2 Lisboa - Grândola (2 hours drive, mostly highway) Breakfast at 8.00, Check-out at 8.30h Hotel – Carrapateira (20 min drive) STOP 1 – Serra de Grândola Introduction - regional geology. Mértola Formation STOP 2 - Cabo Sardão Black-shales of the Mira formation STOP 3 - Monte Clérigo Black-shales of the Brejeira formation LUNCH - Monte Clérigo beach STOP 4 - Arrifana beach Black-shales of the Brejeira formation STOP 5 – Bordeira Black-shales of the Brejeira Formation STOP 6 – Castelejo Black-shales of the Brejeira formation Dinner & Overnight - Hotel Memo Baleeira (Sagres) STOP 7- Carrapateira Mesozoic cover of the Carboniferous basement STOP 8 - Telheiro Paleozoic – Mesozoic unconformity LUNCH - Bag-lunch close to Sagres STOP 9 – Sagres Jurassic dolomites STOP 10 – Lagos Tertiary karstified cover Lagos-Lisboa (3 hours drive, highway) TIDES LOW HIGH 20th May – 10.40 (0.64) and 17.00 (3.50) 21st May – 11.10 (0.79) and 17.35 (3.35) 2 STRUCTURE OF THE FIELD-TRIP OBSERVATIONS STOP 1 Grândola - Sines STOP 2 Cabo Sardão Coastal Abrasion & Sedim.Cover (70m) Coastal Abrasion Platform (40m) Mesozoic Uplift and erosion Uplift and erosion Uplift and erosion Uplift and erosion Late Carbonifer. Gentle folding Tabular & gentle folding Intense Folding Carbonifer. Shales & sedimentation Moscovian Greywackes BlackShales Mira Fm BlackShales Brejeira Fm Tertiary deformation Serpukhovian Mértola Fm STOP 3 Monte Clérigo -- STOP 4 Arrifana STOP 6 Castelejo STOP 7 Carrapateira STOP 8 Telheiro STOP 10 Lagos Coastal Abrasion Platform (80m) Coastal Abrasion Platform (20m) Coastal Abrasion Platform (80m) Emersion Karstif. Infill Uplift and erosion Uplift and erosion Uplift and erosion Trias-Jura subsidence Uplift and erosion Tabular & gentle folding Folding and Thrusting Tabular + Intense folding Metamorf. basement Metamorf. basement -- BlackShales Brejeira Fm BlackShales Brejeira Fm BlackShales Brejeira Fm Basement Basement -- Coastal Abrasion Platform (100m) STOP 5 Bordeira -- 3 FRANCE PORTUGAL LISBOA SINES SPAIN CABO SARDÃO MOROCCO This field-trip will take us from Lisbon to the southern coast of Portugal, mostly along the Atlantic coast. All the stops will be on the seaside and inside SW Coast National Park (PNSACV), which extends from Sines to Sagres. LAGOS Monte CLÉRIGO ARRIFANA CARRAPATEIRA CASTELEJO SAGRES Most of this atlantic coast corresponds to vertical cliffs cut on Carboniferous blackshales, with the exception of some Mesozoic cover outcrops. Our overnight will be in Sagres, a former fishermen village, now a place for summer holidays and nature week-ends. 4 WEIL ET AL., 2009 http://jgs.lyellcollection.org/content/167/1/127/F1.large.jpg This field-trip will be focused on Carboniferous units of the Southern Portuguese Zone (SPZ) in SW Iberia. These units are part of the External Thrust Belt of the Ibero-Armorican Arc. Its geodynamic equivalents may be found in SW Ireland SW England and Rhenish Massif. In SW Iberia the Gondwana terranes are represented by the Ossa-Morena Zone, which contacts with the SPZ by the subduction-related BejaAcebuches ophiolithc complex (BAOC). 5 CARBONIFEROUS BLACK-SHALES - THE BAIXO ALENTEJO FLYSH GROUP The Mértola, Mira and Brejeira Fms and its structures may be identified by its Total Radioactivity (ng/h) variations (Aerial Gamma Ray Spectrometry, collected RioTintoZinc (1991), courtesy of LNEG). by Tertiary The Baixo Alentejo Flysh Group (BAFG) is composed of three different Formations, considered to be diachronic. They represent a few kms of accumulated turbiditic deposits whih are considered to be SWwards increasingly: i) younger; ii) more distal and finner-grained; iii) thicker. The proportion of greywackes and shales varies accordingly and therefore it may be considered that the Brejeira Formation is the most promising in terms of black-shales accumulated thicknesses, although organic-rich facies are present all along this Flysh sequence. The BAFG covers the Volcano-Sedimentary Complex and the organicrich Paraíso Formation, part of the Iberian Pyrite belt. 6 LATE PALEOZOIC REGIONAL GEODYNAMIC EVOLUTION OF SOUTWESTERN IBERIA N LATE CARBONIFEROUS – EARLY PERMIAN COLLISION AND INTENSE DEFORMATION Iberia Mauritania ? Fonseca et al., 2015, (unpublished) Brejeira Fm ? ? LATE CARBONIFEROUS Mira Fm Mértola Fm ? VS Early Carboniferous VS – VolcanoSedimentary Complex PQ S Late Devonian PQ – PhyllitoQuartzitic Group 7 SW Carrapateira Aljezur Brejeira Mira SW NE Aljustrel Odemira Mértola PL VS+PQ PL – Pulo do Lobo Formation; VS – Volcano-Sedimentary Group; PQ – Phyllito-Quartzitic Group; SW – Southwest Group 24.7 % SHORTENING due to folding DEFORMATION AND SHORTENING in the SOUTHERN PORTUGUESE ZONE (in BOLACHA, 2014) 18% SHORTENING due to thrusting 27 km 36.3 % SHORTENING due to folding 97 km 70 km 8 STRUCTURAL LEVELS AND DEFORMATION The concept of structural level (as defined by Mattauer 1973) is based on the observation that the style of deformation changes with depth due to a large number of constraints such as: changes in temperature, confining pressure (overburden), geometry and vicinity of major accidents (thrusts), etc. In a thin-skin deformation model as SPZ, with extreme plastic units (black-shales), the presence of very closed to major thrusts changes dramatically the style of the structural levels. Near the thrusts, structures become more pervasive and subvertical, with a large number of advanced faults and fractures. At SPZ this scenario generally occurs on top of isopach to slightly stretched (A style) folds. At the base of the section, far away from the main thrusts, the bedding and early fabrics are always recognizable, locally with gentle folds or locally overturned folds, with an axial planar schistosity present. 9 39% 36% 52% DEFORMATION and SHORTENING Compression and folding modeling indicates regional shortening values around 35%. Major Thrusts may be responsible for up to 18% shortening. Geometric reconstruction of foldings at outcrop scale (photos) shows shortenings up to 52 %. 10 CARBONIFEROUS BLACK-SHALES AND SHALE-GAS POTENTIAL The potential of the Southern Portuguese Zone Carboniferous units for shale-gas is, at the moment, a line of scientific research supporting a future exploration pathway. There are clear lithological and faciological indicators of good source-rocks, allthough the present-day outcropping TOC values are naturally low. Organic matter maturation attained gas-window and there are also clear indicators of hydrocarbon generation, with pirobetumen in many samples. Deeply buried gas accumulations have been identified in some mining exploration wells, aiming at the Iberian Pirite Belt massive sulphides of the Sub-Culm. Permian deformation may have disrupted the continuity and integrity of these accumulations, but it may also have preserved some tectonic blocks from deeper overburdens, bringing them upwards along large-scale thrusts. Carboniferous accumulation of a few thousand meters of turbidites with some organic-rich layers has been followed by intense subsidence and overburden at the end of the Carboniferous. Most probably there has been abundant generation of hydrocarbons. Terranes collision promoted intense deformation, with folding and thrusting to the SW, throughout the early permian. Permo-Triassic times have witnessed mostly uplift and coeval erosion of up to 5 km (?). Since the Late Triassic, Pangea’s break-up and Atlantic opening, promoted extension, subsidence and development of Mesozoic basins on the western and southern borders of the Iberian Massif (Alentejo and Algarve basins). UNCONVENTIONAL HYDROCARBON SYSTEM CHART SEDIMENTATION OM ACCUMULATION COMPRESSION & FOLDING THRUSTS HC GENERATION UPLIFT & EROSION POST-OROGENIC OVERBURDEN 11 Black – McCormack et al, 2007 Yellow – Fernandes et al., 2012 Green – Partex/Repsol, 2013 Red – Partex/Repsol, 2013 TOC data are scarce and do not seem to be very promising. However, is must be noticed that these are present-day outcrop values. This means that we are dealing with residual values - generation attained the Gas-window and most of the original Organic Matter has allready been lost. Over-maturation, related to greenshist metamorphic facies has been the main obstacle to consider these units as having some shale-gas potential. However, Vitrinite Ro% data show some interesting heterogeneities and values below 3.0 (dark blue) or 3.5 (light blue), partucularly in the SW sectors between Arrifana and Castelejo. 12 SW IBERIA Southern Portuguese Zone 2 Cabo Sardão ALENTEJO Mesozoic Basin MIRA Fm (offshore) 3 Monchique intrusion 4 1 2 6 7 10 5 6 6 5 4 3 ALGARVE Mesozoic Basin Lagos 8 9 BREJEIRA Fm 10 Sagres BREJEIRA Fm 2 MIRA Fm Pre-CULM Oliveira et al., 1984 Geological Map 1:200.000 13 Mte CLÉRIGO 3 CARRAPATEIRA 4 ARRIFANA 5 7 6 8 Manupella et al., 1992 Geological Map 1:100.000 9 14 STOP 1 – SERRA DE GRÂNDOLA Introduction to Carboniferous shales This stop shows the characteristics of the Mértola Formation, with a predominance of Greywackes and minor intercalations of black-shales. Stratification shows large-scale folding with inverted short limbs and vergence towards SW. Thrusts to the SW may also be seen, indicating an overall compression with that orientation. Deformation style B WSW Further down the highway, towards West, the contact with the Mesozoic is exposed, showing Late Triassic redbeds, clays and CAMP-related volcanics, followed by a Jurassic carbonate sequence, part of the Alentejo basin. These units are mostly covered by Plio-quaternary coastal sands. WSW ENE 15 STOP 2 – CABO SARDÃO Carboniferous black-shales These high cliffs show the main sedimentary characteristics of the Carboniferous sequence of the Mira Formation, with alternating greywackes and shales. These rhytmic deposits correspond to median to distal turbiditic facies. Deformation style B Deformation is moderate, with mainly ondulated layers and some decametric folds, with a southwards vergence. The clif is around 40 m high and is topped by a PlioQuaternary marine abrasion surface with rounded pebbles. White stork nests on sea cliffs are characteristic of this place a and unique feature worldwide. 16 STOP 3 – MONTE CLÉRIGO Carboniferous black-shales The cliffs at Monte Clérigo show a predominance of intensively folded black-shales. ATENTION – Wet rocks covered by green algae are extremelly slippery ! Deformation style B Towards the base (closer to the beach) deformation is less intense, whereas towards the top (southwards and upwards) some incipient thrusting may be identified. This outcrop shows that slightly different deformation styles may occur allmost side-by-side. This may be due to depth-dependent factors, but also due to major thrusting accidents. These large accidents have been identified along this coast, putting in contact units with strikingly different deformation and maturation intensities, as well as units with biostratigraphic gaps as long as 15 My. This fact has strong implications to thermal maturation, sampling, analysis and interpretation, within an exploration framework. 17 STOP 4 – ARRIFANA Carboniferous black-shales This bay exposes deposits from the Brejeira Formation, with black-shales and fine-grained greywackes. Deformation is moderate, with large-scale ondulated folds, characteristic of deeper structural layers. The cliff goes up to 100 m high, with a distinct abrasion surface. At the far-end horizon it is possible to see a lower surface, corresponding to the Mesozoic Carrapateira outlier (Stop 6). Deformation style A 18 STOP 5 – BORDEIRA Carboniferous black-shales This small outcrop shows rich organic facies with apparently not very high maturation. A big thrust is exposed on the left side, indicating that this deformation occured mostly in upper structural levels, related with the Late Paleozoic up-lift. Deformation style C 19 STOP 6 – CASTELEJO Carboniferous black-shales This long outcrops extends from the Castelejo beach northwards, untill the Cordoama beach. The Northern half exposes highly deformed black-shales and fine-grained greywackes, with complex folds and inverted polarities. An important sub-vertical thrust, brings to contact the previously described layers and much less deformed tabular layers, exposed at the Castelejo beach. Thermal maturation seems to be lower in this southern sector. C A 20 STOP 7 - CARRAPATEIRA Mesozoic cover N 7A - BORDEIRA BEACH On this western mostly Paleozoic coast, a Mesozoic outlier may be seen at the Carrapateira promontory. It corresponds to a downthrown block, with a clear tectonic eastern limit, preserving most of the Mesozoic sequence. This infill may be correlated with Alentejo offshore basin as welll as with the Algarve basin (only 20 km away). Carboniferous basement U. Triassic redbeds Basin’s tectonic border Middle Jurassic (?) dolomites ALENTEJO Basin 21 STOP 7 - CARRAPATEIRA Mesozoic cover N 7A Along the Carrapateira promontory a Late Triassic to Late Jurassic sequence can be seen. This Mesozoic cover may eventually act as a conventional reservoir for Paleozoic sourced hydrocarbons, a play which has been successfully tested in other Portuguese basins (Upphoff, 2005) Late Triassic redbeds are covered by Hettangian red clays and dolomites, followed by Early and Middle Jurassic carbonates with intense dolomitisation, ending with Late Jurassic marls. Magmatic intrusions may be observed, mainly related to the Late Jurassic doleritic Alentejo-dyke. 7A – Bordeira beach 7B – Três Angras bay 7C – Amado beach 7A 7B 1 km UPPER JURASSIC Volcanic tuffs and breccias Marly limestones (*dolom) Limestones and Dolomites Middle JURASSIC Dolomites Lw JURASSIC Marls & dolomites HETTANGIAN Red clays & marls UPPER TRIASSIC Redbeds 7B Ribeiro et al., 1987 Geological Map 1:50.000 7C 7C 22 7B - TRÊS ANGRAS BAY Upper Jurassic interbedded limestones and marls at Três Angras. Calciclastic marls and bioclastic limestones pass into interbedded grey marls and limestones, with some potential as source-rock. The uppermost limestone beds are rich in macrofossils including well preserved corals. Vitrinite Reflectance studies point to an uplift of about 2 km, part of it from the Late Cretaceous to the Paleogene (Fernandes et al., 2013). STOP 6 CARRAPATEIRA N Kimmeridgian marls with Source-rock potential STOP 7 CARRAPATEIRA 23 7C - AMADO BEACH S The cliifs North of this beach expose the Upper Triasic red-beds, with alluvial-fan coarse lags and eolian-like fine-grained sands, covered by sabkha deposits. This pair of sands/clays may act as a Reservour/Seal for Paleozoic gas, as proven in the Lusitanian Basin. Looking Northwards this sequence is interrupted by a magmatic intrusion related to the CAMP event. Looking southwards, Carboniferous units appear again. N Upper Triassic aeolian like redbeds STOP 7 CARRAPATEIRA N N Hettangian red clays & dolomites 24 STOP 8 – TELHEIRO Unconformity Carboniferous shales vs. Mesozoic cover This major unconformity between Carboniferous shales and Triassic redbeds resulted from a long geological evolution: i) deposition of marine clays and sands in a distal turbiditic environment, c. 320 My ago; ii) intense orogenic subsidence, heating and ductile deformation (5km depth?), c.320-300 My: iii) post-orogenic uplift and erosion of 4.5 km (?), until exposure and weathering, c.300-230 My; iv) deposition of fluvio-aeolian sands (c.230 My) unconformably covering folded Carboniferous. Pliocene marine abrasion surface Carboniferous folded metasedimentary basement Hettangian red clays and marls U.Triassic redbeds N 25 STOP 8 TELHEIRO Pliocene abrasion surface S. Vicente Cape Sinemurian dolomites Quaternary consolidated aeolian dunes Hettangian red clays and marls N Carboniferous metasedimentary basement Hettangian red clays and marls S Hettangian red clays and marls Carboniferous metasedimentary basement U. Triassic redbeds U. Triassic redbeds 26 Sagres is the “Promontorium Sacrum”, considered by the Romans as “the western end of the inhabited world”. This is a place with a tremendous historical importance. It was at least as important during the Age of Discovery as Cape Canaveral was during the early years of space exploration. STOP 9 – SAGRES Jurassic dolomites 1 km N TELHEIRO It was to this place that Prince Henry the Navigator, came in the 15th century to work on his obsession to push back the frontiers of the known world, and opened the phase in Portuguese history called The Discoveries. These high vertical cliffs correspond to Lower Jurassic dolomites, which may act as conventional reservoir (both primary and fractured) for Paleozoic gas. St. Vincent CAPE SAGRES Rocha et al., 1979 27 STOP 10 – PONTA da PIEDADE This touristic spot shows well developed karstic erosion in Miocene limestones. After the Mesozoic infill of the Algarve Basin, intense inversion resulted in uplift and erosion during the Late Cretaceous and Paleocene in the present day onshore areas. Sedimentation resumed in Middle Miocene with deposition of rhythmic fossiliferous limestones and marls in coastal environments. This coastal landscape is also a result of the the post-Miocene uplift of the Western Algarve during the Plio-Quaternary. Karstic features are partially filled up by Pliocene red sands, which after collapse of the karstic vertical wall give place to the present-day holes and arches. Offshore, coeval formations may act as conventional reservoirs, sealed by Plio-Quaternary clays. 28 29 Barberes, G.A.; Pena dos Reis, R.; Pimentel, N.L.; Fonseca, P.E.; Azevedo, M. (2014) - Hydrocarbon anomalies in the Carboniferous units of the South Portuguese Zone using the ThoriumNormalized method (Gamma radiation). GEOSHALE 2014 Barberes, G.A.; Pena dos Reis, R.; Pimentel, N.L.; Fonseca, P.E.; Azevedo, M. (2014) - Shale gas potential in Carboniferous units of the South Portuguese Zone: a preliminary assessment . GEOSHALE 2014 Bolacha, Edite (2014) – Modelos de Dinâmica da Terra aplicados à Geologia de Portugal: Relevância da Experimentação Análoga no Ensino e na divulgação da Geologia. PhD, FCUL, Lisbon University (in Portuguese, not published). Dias, R. (2007). Evolução, Portugal de Antes da História. Estremoz: Associação Centro Ciência Viva de Estremoz. Dias, R. & Basile, C. (2013). Estrutura dos Sectores Externos da Zona Sul Portuguesa; implicações geodinâmicas. In R. Dias, A. Araújo, P. Terrinha & J. Kullberg (Eds.), Geologia de Portugal. Lisboa: Livraria Escolar Editora. Fernandes, P.; Borges, M.; Matos, V.; Clayton, G. (2013) – Organic maturation of the Algarve Basin (Southern Portugal) and its bearing on thermal history and hydrocarbon exploration. Marine and Petroleum Geology, 46, 210-233. Fonseca, P.E.; Azevedo, M.; Pimentel, N.L.; Pena dos Reis, R.; Barberes , G.A. (2014) - Tectonic deformation: good or bad for shale gas exploration? The case of the SW Iberian Variscan Chain . GEOSHALE 2014 Mattauer Maurice (1973) - Les deformations des materiaux de l'ecorce terrestre (Collection Methodes) (French Edition). McCormack, N.; Clayton, G.; Fernandes, P. (2007) - The thermal history of the Upper Palaeozoic rocks of southern Portugal. Marine and Petroleum Geology, 24 (3), 145-150. Oliveira, J. T. (1983). The Marine Carboniferous of South Portugal: a Stratigraphic and Sedimentological Approach. In Lemos de Sousa, J. & Oliveira, J. T. (Eds.) The Carboniferous of Portugal. Memórias dos Serviços Geológicos de Portugal, No 29, pp. 3-37. Oliveira, J. T. (1990). Stratigraphy and Synsedimentary Tectonism. In Dallmeyer, R. D. & Matínez García (Eds.). Pre-Mesozoic Geology of Iberia. (pp. 334-347). Berlin:Springer-Verlag. Ribeiro, A. (1983). Structure of Carrapateira Nappe in the Bordeira Area, SW Portugal. In Lemos de Sousa, J. & Oliveira, J. T. (Eds.) The Carboniferous of Portugal (pp. 91-97). Memórias dos Serviços Geológicos de Portugal, nº 29. Ribeiro, A. & Silva, J. B. (1983). Structure of the South Portuguese Zone. In Lemos de Sousa, J. & Oliveira, J. T. (Eds.) The Carboniferous of Portugal (pp. 83-89). Memórias dos Serviços Geológicos de Portugal, No. 29. Ribeiro, A.; Munhá, J.; Dias, R.; Mateus, A.; Pereira, E.; Ribeiro, L.; Fonseca, P.; Araújo, A.; Oliveira, T.; Romão, J.; Chaminé, H.; Coke, C. & Pedro, J. (2007). Geodynamic evolution of the SW Europe Variscides. Tectonics, vol. 26, TC6009. Silva, J. B.; Oliveira, J. T. & Ribeiro, A. (1990). Structural Outline. In Dallmeyer, R. D. & Matínez García (Eds.). Pre-Mesozoic Geology of Iberia (pp. 348- 362). Berlin:Springer-Verlag. Simancas, J. F.; Carbonell, R.; González Lodeiro, F.; Pérez Estaún, A.; Juhlin, C.; Ayarza, P.; Kashubin, A.; Azor, A.; Martinez Poyatos,D.; Almodóvar, G. R.; Pascual, E.; Sáez, R. & Expósito, I. (2003). Crustal structure of the transpressional Variscan orogen of SW Iberia: SW Iberia deep seismica reflection profile (IBERSEIS). Tectonics, vol. 22, No. 6, 1062, pp. 1-19. Main References