193 Isotopic, elemental and molecular composition of Lago Coari, AM, Brazil aCunha T S, b6LP}HV(9cLandau L, dBernardes M C /DNH&RDULZDVVWXGLHGWKURXJKJHRFKHPLFDOSDUDPHters to understand its hydrochemical function and assess possible environmental impacts arising from the hydrocarbon exploration activities at Petroleum Province of Urucu and from the Solimoes River Oil TermiQDO762//LNHZLVHWKLVZRUNLQFOXGHVDQDVVHVVPHQW of the possible impacts from Coari City and its anthropogenic activities pushed by exponential population JURZWKGXULQJODVWGHFDGHV7RDFKLHYHWKLVWDVNLW ZDV FKDUDFWHUL]HG WKH FRPSRVLWLRQ RI RUJDQLF PDWWHU&1UDWLRVWHUROVOLJQLQDQGQDONDQHVPROHFXODU FRQWHQWVLQVXUIDFHVHGLPHQWVDQGLQVKRUWFRUHVDW the inlet and inside the lake. This approach intends to understand the spatial and seasonal distribution of organic matter from natural and anthropogenic VRXUFHV+LJKHU&DQG1YDOXHVDQG&1UDWLRFORVHWR ZHUHIRXQGZLWKLQWKHODNHVXJJHVWLQJDSUHGRPLnance of autochthonous organic matter. Higher lignin FRQWHQWZDVIRXQGWRZDUGWKHODNHLQOHW'HVSLWHWKH ORZHU OHYHOV RI RUJDQLF PDWWHU UHIUDFWRU\ OLJQLQ SUHGRPLQDQFHZDVUHODWHGWRYDVFXODUSODQWVLQSXWE\WKH 6ROLP}HV5LYHU7KHVHGLPHQWSURÀOHVVKRZHGODUJHU ÁXFWXDWLRQV LQ VHGLPHQW FRPSRVLWLRQ DW WKH LQOHW RI WKH ODNH DQG JUHDWHU VWDELOLW\ ZLWKLQ WKH ODNH +RZHYHU WKHUH KDYH EHHQ WZR HYHQWV RI LQFUHDVHG DW DQGFP3LQOHWDQGFP3FHQWHUUHODWHGWR vascular plants material input during intense rainfalls. This could also be related to increased soil erosion from exposed areas due to land cover changes. AnRWKHU HYHQW FKDUDFWHUL]HG E\ D VWHURO FRQFHQWUDWLRQ SHDN FP 3FHQWHU VXJJHVWHG D SHULRG RI SURORQJHGGURXJKWZKHUHDVDORZHUZDWHUYROXPHLQWHQVLÀHGWKHSULPDU\SURGXFWLRQELRPDVV7KHUHVXOWVRI DOLSKDWLF K\GURFDUERQV QDONDQHV ZHUH FRQVLGHUHG W\SLFDO RI XQFRQWDPLQDWHG VHGLPHQW VDPSOHV ZLWK D predominance of n-alkanes C29 and C31, typical of vascular plants. The mean carbon preference index &3, RI DQG WKH PHDQ UDWLR RI WHUULJHQRXV WR DTXDWLFQDONDQHV7$5RIFRQÀUPHGWKLVVRXUFH The absence of unresolved complex mixture and the even predominance of odd chaining pairs of n-alNDQHVFRPSRXQGVFRQÀUPWKHDEVHQFHRISHWURJHQLF contamination. The organic compounds distribution VXJJHVWHGDQDWXUDOVRXUFHVSUHGRPLQDQFHVZLWFKLQJ EHWZHHQDOORFKWKRQRXVVRLOVZLWKYDVFXODUSODQWGHEULVDQGDXWRFKWKRQRXVSURGXFHUVSK\WRSODQNWRQ (YHQ ZLWK WKH LQFUHDVH RI &RDUL &LW\ DQG 3HWUROHXP neighbor activities the possible impacts measured by WKRVH RUJDQLF FRPSRXQGV ZHUH QRW \HW GHWHFWHG LQ WKHVHDQDO\]HGVHGLPHQWV a Instituto de Engenharia Nuclear (IEN), Laboratório de Impactos Ambientais (LIMA), Ilha do Fundão, Rio de Janeiro, RJ, CEP:21941-972 ([email protected]) b Instituto Federal de Ciência e Tecnologia do Rio Grande do Sul (IFRS), Campus Feliz, RS, Brasil, CEP:95770-000 c Universidade Federal do Rio de Janeiro, Programa de Engenharia Civil (UFRJ-PEC-COPPE), Ilha do Fundão, Rio de Janeiro, RJ, Brasil, CEP:24941-909 d Universidade Federal Fluminense, Departamento de Geoquímica, Instituto de Química 5 andar, Campus Valonguinho, Niterói, RJ, Brasil, CEP:24020-141 9th International Symposium on Environmental Geochemistry