REVISTA DA FACULDADE DE CIÊNCIAS NÚMERO 1 EDIÇÃO ESPECIAL 2004 THE USE OF GEOGRAPHIC INFORMATION SYSTEMS (GIS) IN THE TREATMENT OF MULTIELEMENTAL GEOCHEMICAL DATA. AN EXAMPLE FROM THE SANTIAGO DE CACÉM BASIN, SOUTHWEST PORTUGAL Nogueira, P1., Inácio, D.2, Noronha, F.3 & Oliveira, V.4 1 Departamento de Geociências da Universidade de Évora. 2 Aluno Finalista do Curso de Engenharia de Recursos Geológicos. 3 Departamento de Geologia da Faculdade de Ciências da Universidade do Porto. 4 Instituto Geológico e Mineiro. Resumo Numa campanha de prospecção geoquímica o investigador tem de lidar com um conjunto complexo de dados que necessitam de ser interpretados. Para tal pode ser efectuada uma abordagem baseada em métodos de estatística multivariada. A análise factorial e de componentes principais são dois exemplos deste tipo de abordagem. A informação geológica, tal como as litologias, as idades das formações, entre outros, devem ser igualmente considerados e tomados em conta. O que estas técnicas não consideram é a distribuição espacial da amostragem. Para este tipo de situações é necessária uma abordagem baseada no recurso a sistemas de informação geográfica (SIG). Neste trabalho é apresentada uma abordagem deste tipo para estudar um conjunto de dados geoquímicos para diversos elementos e aplicada ao caso de uma bacia Mesocenozóica do Sudoeste de Portugal. Abstract After a geochemical campaign, the researcher is confronted with a multiset data that has to be interpreted. For this, an approach based on the multivariate statistics methods can be applied. Factorial analysis and principal components are two examples of such techniques. The geological information, such as lithologies, ages of formations and others can be considered and taken into account. What these techniques cannot consider is the spatial distribution of the samples. A GIS based approach is necessary for these situations. In this work, this approach is applied to study a multielemental set of data from a Southwest Portuguese Mesocenozoic basin’s case study. Introduction During a campaign of geochemical exploration for base metals in the Mesocenozoic basin in Southwest Portugal a set of different techniques were applied to evaluate its potential. Two types of samples were collected and treated: stream sediment 333 REVISTA DA FACULDADE DE CIÊNCIAS NÚMERO 1 EDIÇÃO ESPECIAL 2004 samples and soil samples. These samples were treated for geochemical analysis and mineralogical studies. The geological context is of a marginal basin related to a pre-rift context associated with the Atlantic aperture. This is a favourable context for the deposition of base metals such as Cu, Pb, Zn and particularly of Gold. A set of 29 elemental analyses of 109 samples for stream sediment samples and 28 elemental analyses of 27 soil samples were run in an international geochemical laboratory. This data combined with the mineralogical studies (10 different mineral species identified) of the samples would provide a total of 65 different thematic maps. It is reasonable to accept that it is impossible to a researcher to combine by him self all this information and to reliably interpret it. Herein a tentative approach for the treatment and interpretation of such type of sets is presented, using a multivariate statistic approach combined with the construction of a GIS based model. Geochemical univariate and multivariate analysis In another presentation (Inácio et alia, this conference) the principles used in the univariate and multivariate analysis are discussed. A principal factors analysis was selected to describe the data. The cluster analysis demonstrated that gold does not correlate with any element. This might be due to nugget effect on gold. Another effect that becomes obvious is the presence of outlier and zero values that contribute to a poor correlation of the data. On what concerns the geochemical exploration, this kind of studies are a previous approach to understand elemental behaviour and is used to select which are the relevant elements to the understanding of the geochemical pattern. The GIS based approach to geochemical exploration For the interpretation of the data a GIS project was developed. The topographic, geological and structural information was collected from available cartography and digitised. The geochemical information was digitised as a set of coordinated points and linked to the table with the geochemical data (figure 1), 334 REVISTA DA FACULDADE DE CIÊNCIAS NÚMERO 1 EDIÇÃO ESPECIAL 2004 Atributes Faults 1 Geology 1 Atributes Geology 1 1 Figure 1. The data structure for the GIS project. Geodesic info Atributes Geochemical data Topography 1 1 Samples Atributes 1 1 Provenience 1 Concession 1 Atributes 1 Concentration factor 1 1 Atributes 1 Figure 1 (Continued). The data structure for the GIS project Data analysis The different thematic maps were analysed considering a mineralogical, geological and geochemical basis. The analysis of the thematic maps allows us to consider two types of elemental behaviour. Elements such as As and Fe that can be consider to reflect the geological background, that is the separation between the different geological units (Palaeozoic, Mesozoic and Cenozoic). The other type of behaviour is the one that does not relate directly with the geologic background. Elements such as Au and Cu present this type of behaviour. 335 REVISTA DA FACULDADE DE CIÊNCIAS NÚMERO 1 EDIÇÃO ESPECIAL 2004 This analysis points to the conclusion that thematic maps for Au and Cu represent true concentration maps whereas thematic maps of elements such as Fe and As only reflect the geologic background. Suggestions for exploration The geochemical maps of Cu and Au point to two areas of overlapping interest. These areas are the potential areas for further mineral exploration campaigns. These areas are the ones were the Mesozoic basin is more deep (the basin as a synclinal form and the areas are near its axis). These should correspond to the maximum deep of the sandstone sedimentation and therefore the places were the dynamic conditions of sedimentation promoted the deposition of the gold. Final considerations The main objective of a mineral exploration campaign is to reduce the areas of study, improving the knowledge on those areas and defining potential targets for further exploration. Within a geochemical campaign a great amount of data is obtained and only the combination of statistical and geographical oriented methods of analysis permits the full assessment of the data significance. Nowadays the ease of access and use of GIS systems provides the geochemical exploration a tool for further developing the analysis of the data obtained. References Inácio, D., Nogueira, P., Noronha, F. & Oliveira, V. (2003). Sugestão de procedimento base para o tratamento estatístico de dados referentes à prospecção geoquímica. VII Congresso de geoquímica dos países de língua portuguesa. Maputo. 336