ANALISE BIODIESEL – (Diego)
6
3
(x10,000,000)
1.3 TIC
7
1.2
1.1
1.0
0.9
0.8
0.7
0.6
0.5
9
0.4
0.3
6.0
4
7.0
8.0
Figura 1: Cromatograma.
9.0
10.0
11.0
5
2
1
0.1
8
0.2
12.0
13.0
14.0
15.0
Tabela 1: Identificação dos picos do cromatograma.
Pe
ak
Ret.
time
Start
time
End
time
Area
%
Name
1
6.13
6.07
6.20
0.39
Tetradecanoic acid, metil ester
2
9.08
8.97
9.20
0.69
9-hexadecenoic acid, metil ester
3
9.50
9.32
9.55
15.97
Hexadecanoic acid, metil ester
4
11.04
10.95
11.17
0.50
10,13-eicosadienoic acid, metil ester
5
11.54
11.45
11.66
0.48
Heptadecanoic acid, metil ester
6
14.06
13.36
14.12
63.31
8,11-octadecadeinoic acid, metil ester
7
14.21
14.13
14.32
14.97
7-octadecenoic acid, metil ester
8
14.38
14.32
14.45
0.54
9,12,15-octadecatrienoic acid, metil ester
9
14.60
14.47
14.66
3.15
Octadecanoic acid, metil ester
%
74
100.0
87
75.0
50.0
25.0
143
55
43
97 101
32
0.0
30
40
50
60
70
80
90
100
110
199
129
111
120
130
157
140
150
185
171
160
170
180
211
190
200
210
242
220
230
240
Figura 2: Fragmentograma do pico 1.
%
55
100.0
69
75.0
83
74
97
41
50.0
110
123
25.0
137
135
32
152
194
165
0.0
30
40
50
60
70
80
90
100
110
120
130
Figura 3: Fragmentograma do pico 2.
140
150
160
236
207
179
170
180
190
200
210
218
220
230
240
%
74
100.0
87
75.0
50.0
143
43
25.0
55
101
115
31
0.0
50.0
75.0
100.0
227
129
125
171
157
125.0
150.0
185
199
175.0
239
213
200.0
270
272
275.0
255
250.0
225.0
Figura 4: Fragmentograma do pico 3.
%
81
55
100.0
67
75.0
96
41
50.0
110
111
25.0
123
135
152
32
166
30
40
50
60
70
80
90
100
110
120
130
Figura 5: Fragmentograma do pico 4.
140
150
160
250
208
206
0.0
170
180
190
200
210
220
230
240
250
%
74
100.0
87
75.0
50.0
25.0
43
143
55
101
129
111
32
0.0
25.0
50.0
75.0
100.0
157
125.0
150.0
171
185
241
199
213
175.0
200.0
227
255
225.0
284
250.0
275.0
Figura 6: Fragmentograma do pico 5.
%
67
100.0
75.0
81
55
95
41
50.0
109
25.0
123
150
31
0.0
25.0
50.0
75.0
100.0
125.0
150.0
Figura 7: Fragmentograma do pico 6.
164
178
175.0
262
191
205
200.0
220
225.0
235
245
250.0
294
275.0
300.0
%
55
100.0
75.0
69
41
83
97
50.0
111
25.0
264
123
138
166
180
193
31
0.0
25.0
50.0
75.0
100.0
125.0
150.0
222
175.0
235
207
200.0
225.0
246
250.0
296
278
275.0
300.0
Figura 8: Fragmentograma do pico 7.
%
79
100.0
67
75.0
95
55
50.0
41
108
121
25.0
135
149
163
173
0.0
50.0
75.0
100.0
125.0
Figura 9: Fragmentograma do pico 8.
150.0
175.0
180
191
222
200.0
225.0
236
264
250.0
%
74
100.0
87
75.0
50.0
143
43
25.0
55
101
31
0.0
25.0
50.0
75.0
100.0
157
111
125.0
255
199
129
150.0
Figura 10: Fragmentograma do pico 9.
171
175.0
185
227
200.0
225.0
241
298
267
250.0
275.0
300.0