ANALISE BIODIESEL – (Daiani)
(x10,000,000)
TIC
2.00
1.75
8
3
7
1.50
1.25
1.00
0.50
12
10
11
4
0.75
6
5
1
2
9
0.25
0.00
6.0
7.0
8.0
9.0
Figura 1: Cromatograma.
10.0
11.0
12.0
13.0
14.0
15.0
16.0
Tabela 1: Identificação dos picos do cromatograma.
Peak
1
2
3
4
5
6
7
8
9
10
11
12
Ret.
time
6.13
9.07
9.48
10.77
11.03
11.53
13.99
14.11
14.30
14.53
15.61
15.74
Start
time
6.02
8.99
9.29
10.66
10.95
11.45
13.29
14.05
14.25
14.39
15.41
15.67
End
time
6.24
9.15
9.60
10.86
11.13
11.64
14.04
14.24
14.36
14.58
15.65
15.88
Area %
Name
0.46
0.53
14.19
5.21
0.42
0.37
53.52
11.67
0.57
3.52
6.21
3.33
Tetradecanoic acid, methyl ester
9-hexadecenoic acid, methyl ester
Hexadecanoic acid, methyl ester
Hexadecanoic acid, ethyl ester
10,13-eicosadienoic acid, methyl ester
Heptadecanoic acid, methyl ester
8,11-octadecadeinoic acid, methyl ester
7-octadecenoic acid, methyl ester
9,12,15-octadecatrienoic acid, methyl ester
Octadecanoic acid, methyl ester
9,12-octadecadienoic acid, ethyl ester
9-Octadecenoic acid (Z)-, ethyl ester
%
74
100.0
87
75.0
50.0
25.0
143
55
43
97101
39
0.0
50.0
75.0
111
100.0
199
129
157
125.0
185
171
150.0
175.0
211
200.0
242
225.0
Figura 2: Fragmentograma do pico 1.
%
55
100.0
69
74
75.0
83
97
50.0
41
110
123
25.0
0.0
137
135
152
50.0
75.0
100.0
125.0
Figura 3: Fragmentograma do pico 2.
236
194
165
32
150.0
207
179
175.0
200.0
218
225.0
%
74
100.0
87
75.0
50.0
143
43
25.0
55
101
31
0.0
50.0
75.0
227
129
115
100.0
171
157
125
125.0
150.0
185
175.0
199
239
213
200.0
270
272
275.0
255
250.0
225.0
Figura 4: Fragmentograma do pico 3.
%
88
100.0
75.0
101
50.0
25.0
43
0.0
30
25.0
157
70
55
50.0
115
75.0
100.0
129
125.0
143
150.0
Figura 5: Fragmentograma do pico 4.
171
175.0
185
199
200.0
241
213
255
225.0
250.0
284
275.0
%
81
100.0
55
67
75.0
96
50.0
41
110
111
123
25.0
135
152
166
0.0
50.0
75.0
100.0
125.0
150.0
250
208
32
175.0
200.0
225.0
250.0
Figura 6: Fragmentograma do pico 5.
%
74
100.0
87
75.0
50.0
25.0
43
143
55
101
0.0
25.0
129
111
32
50.0
75.0
100.0
157
125.0
150.0
Figura 7: Fragmentograma do pico 6.
171
175.0
185
199
200.0
241
213
227
225.0
255
250.0
284
275.0
%
67
100.0
81
75.0
55
95
41
50.0
109
25.0
123
150
31
25.0
0.0
50.0
75.0
100.0
125.0
164
150.0
178
175.0
262
191
205
200.0
294
220
235 245
225.0
250.0
275.0
300.0
Figura 8: Fragmentograma do pico 7.
%
55
100.0
75.0
69
41
83
97
50.0
111
264
123
25.0
138
166
0.0
31
25.0
50.0
75.0
100.0
125.0
150.0
Figura 9: Fragmentograma do pico 8.
222
180
193
175.0
235
207
200.0
225.0
246
250.0
278
275.0
296
300.0
%
79
100.0
75.0
67
95
55
50.0
108
41
121
25.0
135
149
39
163
173
0.0
50.0
75.0
100.0
125.0
150.0
191
175.0
207
200.0
236
222
225.0
264
250.0
Figura 10: Fragmentograma do pico 9.
%
74
100.0
87
75.0
50.0
143
25.0
0.0
43
31
25.0
55
50.0
101
75.0
100.0
129
111
125.0
255
199
157
150.0
Figura 11: Fragmentograma do pico 10.
171
175.0
185
213
200.0
241
225.0
267
250.0
275.0
298
300.0
%
81
100.0
95
75.0
55
50.0
109
41
123
25.0
135
150
164
0.0
262
178
205
30
25.0
50.0
75.0
100.0
125.0
150.0
175.0
200.0
220
225.0
234
245
308
279
250.0
275.0
300.0
Figura 12: Fragmentograma do pico 11.
%
55
100.0
69
97
101
75.0
41
50.0
123
137
25.0
0.0
152
30
25.0
166
235 246
207
50.0
75.0
100.0
125.0
264
222
180
150.0
Figura 13: Fragmentograma do pico 12.
175.0
200.0
225.0
250.0
281
275.0
292
300.0
310