Espectro de NMR de 1H [400,13 MHz, CDCl3] de H2TPP
Ph
Ph
N
HN
-2.770
N
Ph
1.544
8.857
8.587
8.237
8.221
7.789
7.773
7.755
7.741
7.260
NH
Ph
6
5
4
3
2
1
0
-1
-2
-3
1.81
7
12.06
8
8.11
8.00
9
ppm
8.2
8
7
6
7.786
7.769
7.752
7.737
8.232
8.214
Ph
NH
N
8.0
5
7.8
4
3
2
1
0
-1
1.94
9
12.27
8.21
8.00
-2.777
1.558
2.177
2.176
8.232
8.214
7.786
7.769
7.752
7.737
7.260
8.851
Espectro de NMR de 1H [400,13 MHz, CDCl3] de H2TPP
Ph
N
HN
Ph
Ph
ppm
-2
-3
ppm
12
7.1
11
7.0
6.9
10
9
8
7
6
5
2.16
13
7.2
1.01
1.05
1.01
1.05
7.3
1.06
1.00
6.877
6.858
6.840
6.955
6.935
7.316
7.312
7.294
7.277
7.273
7.260
7.238
7.234
7.219
7.215
3.932
8.353
7.316
7.312
7.294
7.277
7.273
7.260
7.238
7.234
7.219
7.215
6.955
6.935
6.877
6.858
6.840
13.229
Espectro de NMR de 1H [400,13 MHz, CDCl3] de H2salen
ppm
4
ppm
Espectro de NMR de 1H [400,13 MHz, CDCl3] de H2salen
Espectro de NMR de 1H [CDCl3, 400,13 MHz] de [Co(dmgH)2(py)Cl]
ppm
11
10
9
8
7
6
5
4
3
2
12.00
12
1.247
7.260
7.237
7.221
7.5
2.99
13
ppm
1.06
14
7.2
2.09
8.0
15
7.3
7.723
7.704
7.686
8.270
8.257
7.4
2.403
8.270
8.257
7.723
7.704
7.686
7.260
7.237
7.221
Cl
ppm
16
15
14
13
12
11
10
9
8
7
6
5
4
3
2
3.04
17
7.5
12.00
18
8.0
1.02
1.96
8.5
1.94
19
1.75
18.351
7.337
7.321
7.304
7.260
7.738
7.720
7.701
8.606
8.594
0.814
1.669
2.122
8.606
8.594
7.738
7.720
7.701
7.337
7.321
7.304
7.260
18.351
Espectro de NMR de 1H [CDCl3, 400,13 MHz] de [Co(dmgH)2(py)Me]
CH3
19 18 ppm
ppm
ppm
Espectro de NMR de 1H [CDCl3, 400,13 MHz] de [Co(dmgH)2(py)Me]
(nota: produto mais seco, obtido em ano anterior; ver a diferença)
15
14
13
12
11
10
9
8
7
6
5
4
3
2
1.696
0.806
1 ppm
3.03
16
12.21
17
1.00
2.00
1.90
18
ppm
2.00
8.8 8.6 8.4 8.2 8.0 7.8 7.6 7.4
19
2.118
7.333
7.316
7.299
7.260
7.736
7.717
7.698
8.605
8.592
8.605
8.592
7.736
7.717
7.698
7.333
7.316
7.299
7.260
18.304
CH3
[Co(dmgH)2(py)Me]
[Co(dmgH)2(py)Cl]
Piridina (py)
[Co(dmgH)2(py)Me]
[Co(dmgH)2(py)Cl]
5.5
5.0
4.0
3.5
3.0
2.5
1.661
2.167
2.394
4.203
4.503
4.5
1.60
6.0
2.45
6.5
1.02
7.0
1.00
7.5
4.770
7.260
Espectro de NMR de 1H [CDCl3, 400,13 MHz] de acetilferroceno
2.0
1.5
1.0
0.5 ppm
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
3.5
3.0
2.5
1.590
2.173
4.237
7.260
Espectro de NMR de 1H [CDCl3, 400,13 MHz] de ferroceno
2.0
1.5
1.0
0.5 ppm