Report of the Brazilian Committee for Phase Diagrams of Materials 2015 APDIC Meeting Loano, Italy May 2015 L L Highlights • Phase Diagram Sessions – ABM International Conference 2014, São Paulo, SP – ABM International Conference – ABM WEEK (Organization) 2015 Rio de Janeiro • • Brazil- Germany ABM-DGE Joint Symposium 2014 Organization 1st Meeting Brazilian-German Symposium on Materials Science and Engineering – Fernando Rizzo (PUC-Rio) , Pedro Portella (BAM-Berlin) – Technical-Scientific Sessions in Darmstadt – “Thermodynamics” (ACS & RSF) • Intense activity in steelmaking, oil and nuclear industries and in collaboration with these industries. L L ABM Conference 2014 • Phase Diagram Seminar in the 69th International ABM, 2014 Conference, São Paulo. • Two Computational Thermodynamics Workshop together with the ABM 69th Conference. One in Rio, one in SP 30 participants in each!: Academia + Industry A Costa e Silva, F Beneduce, R Avillez, A Jansson http://equilibriumtrix.net/workshop2014/workshop2014.html Organizing 70th ABM Conference in Rio 2015 “ABM Week” L L L L USIMINAS Dr Fabio Murari The Committee in 2014 EEL-USP Lorena Prof. G. Coelho, Prof C Nunes Pof Sandim Calc./Exp Intermetallics UFC- Fortaleza Prof Hamilton UFF-Volta Redonda Prof. A. Costa e Silva Prof Flavio Ferreira Calc./Exp., St eels,Slags Intermetallics Catholic University -Rio (PUC) Prof. R. Avillez - Exp./Calc. E.MAT, Coatings Prof. F.Rizzo - Exp. Coatings, Oxidation UFRJ Prof Dilson UFSCar-São Carlos Prof. W.Botta C Kiminami C Bolfarini. Exp.Alloys, Amorphous mat. AM Monlevade Dr Joaquim C Neto Universidade Estácio/INT Prof Brant GERDAUSteelmaking Dr Raimundo Fortes Mauricio W Scal Villares Metals Dr Alexandre - UFPR Prof Ana Sofia UFSC Prof A Klein IPT São Paulo Dr. M Bocallini Exp.(calc.) Slags, liquid metals UFRGS-Porto Alegre Prof Villela, Prof Heck UNISINOS- Prof Moraes Exp./ Calcl. Alloys USP-São Paulo Prof.H.Goldstein Dr.C.Schoen, Prof Beneduce Exp/Calc. Alloys L L ArcelorMittal Monlevade 2015 Researchers André Luiz Assunção Angelo Máximo Fernandes Marins César Takaci Sato Ermani Vinícius Oliveira Lima Fábio Cardoso Felipe Gabriel Oliveira Hélder Carvalho Ferreira Joaquim Gonçalves Costa Neto Leandro Aparecido Marchi Luciana Spindola Sales Luciano de Castro Reis Roney Eduardo Lino Engineer Team Ironmaking 4 Steelmaking 4 Refractories 1 Rolling Mill 4 Product 5 L L ArcelorMittal Monlevade Ongoing and concluded projects - Kinetics of inclusion dissolution during secondary refining - Strain aging phenomena in low carbon steel - Control of decarburization in wire rod hot rolling process - Equilibrium of precipitates in microalloyed steel - Improve wear in the ladle slag line on steel shop - Phase diagram of high manganese steel grades - Use of computational thermodynamics to improve desulfurization - Optimization of calcium treatment in ladle furnace process using Thermocalc - Determination of secondary refining slag properties using computational resources - Improve the billet quality using the Solidification Software - Effect of chemical composition on steel liquidus temperature - Billet bending solution for molybdenum alloyed grades L L ArcelorMittal Monlevade Publications COSTA NETO JG, LINO RE, MARINS AMF, MARCHI LA, FERREIRA HC. Computational Thermodynamics: steelmaking aplications. 67º ABM Congress – International – 2012 – RJ – Brasil. LINO RE, MARINS AMF, PENNA LV, COSTA NETO JG, CALDEIRA JHP, COSTA e SILVA AV. Determination of steel liquidus temperatures. 68º ABM Congress – International – 2013 – BH – Brazil. LINO RE, MARINS AMF, MARCHI LA, MENDES JA, PENNA LV, COSTA NETO JG, CALDEIRA JHP, COSTA e SILVA AV. Influence of chemical composition on steel casting performance. 69º ABM Congress – International – 2014 – São Paulo – SP – Brazil. FERREIRA HC, BORATTO FJM, BUONO VLT. Efeito da taxa de resfriamento na ocorrência de austenita retida em um aço para eletrodos de solda. Tecnol. Metal. Mater. Miner., ABM, São Paulo, Brasil, 2015. FERREIRA HC, BORATTO FJM, BUONO VLT. Determination of low levels of retained austenite in lowcarbon high-manganese steel using X-ray diffraction. Materials Science and Engineering A., 628 (2015) pp.110–115. HELDER CARVALHO FERREIRA. Efeito de bandeamento e taxa de resfriamento na ocorrência de Austenita retida em aço baixo carbono com adições de Manganês e Silício. Tese de doutorado – UFMG. 2015. L L ArcelorMittal Monlevade External Event - 2014 Quality Round Table - ArcelorMittal Long Carbon America. 16 and 17 December 2014, Montreal – Quebec – Canada Internal Event - XII Steelmaking Seminar - ArcelorMittal Monlevade. 18 and 19 September 2014, João Monlevade – MG – Brazil Visits of Researchers - Dan Kruse (ArcelorMittal R&D Chicago): BOF and refractory support - Michael Lowry (ArcelorMittal R&D Chicago): CC and CEQCSI Support - Jean Lehmann (ArcelorMittal R&D Maizieres): CEQCSI Support - Fabrice Cangialosi and Randolfo Villegas (ArcelorMittal R&D Gadrange): Secondary refining - Meeting by conference call with R&D wire team (ArcelorMittal R&D Maizieres) L L Companhia Siderúrgica Nacional (CSN) South America Galvanized and Pre-Painted Development Team (GDZ) • RESEARCHERS • • • • • Flávia Tereza dos Santos Fernandes Tolomelli, MSc Fabio Moreira da Silva Dias, MSc Augusto Cesar Lacerda de Oliveira , DSc Daniel Alexandre da Costa Ximenes José Eduardo Ribeiro de Carvalho, MSc PROJECTS • CONCLUDED: All projects carried out in collaboration with UFF - Universidade Federal Fluminense – Volta Redonda – Rio de Janeiro - Brazil 1-Precipitation prediction in low carbon microalloyed steels by means of computational thermodynamics. Published in the 50º ABM Rolling seminar. November/2013. 2-HSS and AHSS - assessment of the phase transformation temperatures A1 and A3 by means of computational thermodynamics and comparison with empirical formulations. Published in the 50º ABM Rolling seminar. November/2013. L L Companhia Siderúrgica Nacional (CSN) South America (cont.) CONCLUDED PROJECTS (cont) : All projects carried out in collaboration with UFF - Universidade Federal Fluminense – Volta Redonda – Rio de Janeiro Brazil 3-AHSS and HSS - selective oxidation assessment in Continuous Annealing Lines under reducing atmospheres. Published in the 63º ABM seminar. July/2008. 4-Precipitation assessment of the HSLA340 steel aiming Cold rolling mill loads control. Published in the 51º ABM Rolling seminar. October/2014. 5-Evaluation of phase transformation temperatures using computational thermodynamics, dilatometry and pilot hot rolling in a low carbon niobium microalloyed steel. . Published in the 51º ABM Rolling seminar. October/2014. 6-Develppment of the 180BH Galvannealed Steel and precipitation evaluation to predict bake hardening effect. Published in the 63º ABM seminar. July/2008. 7-Using of computational thermodynamics to evaluation of the precipitation in Ti and Nb-TiIF Steels. Master’s degree – UFF/EEIMVR - 2011. L L GERDAU (Long Products Steelmaker) • Donation of a Computational Steelmaking Teaching Lab to UFF: THERMO-CALC and Computers • Institution of a undergraduate scholarship at UFF dedicated to the learning and application of Computational Thermodynamics to Steelmaking and Refining. First student already started in 2015/1 • Work with PUC-RIO and UFF in computational thermodynamics calculation of slags for Electric Arc Furnace L L LNNano – (spin off LNLS) 2015 Researchers: Areas of Research: L L IPT - São Paulo SP 2015 Research staff Mário Boccalini Jr Eduardo Albertin João Batista Ferreira Neto Sandra Lúcia de Moraes Cátia Fredericci Tiago Ramos Ribeiro Moyses Leite Lima Camila Peres Massola Ana Paola Vilalva Braga Pamela Karina dos Santos Bomfim André Lotto Research áreas - Pirometallurgy - Foundry and solidification - Ore and industrial residues treatment - Mechanical forming - Powder metallurgy L L IPT - São Paulo SP Main research areas in 2014 Development of Metallurgical route for the production of solar grade silicon Advanced system for the design of alloys to be ued for hot working tools. Nodular cast iron for rolling mil rolls core. Interface formation in bimetallic castings Use of steelmaking slag in Portland cement manufacture Cast steel piston engine rings Production of Neodimium from Nd2O3 L L IPT - São Paulo SP SAMPLE PUBLICATIONS Boccalini Jr, M. Corrêa, AVO. The effect of sulfur on the contact angle between liquid eutectic Fe-V-C alloy and VC substrate and on the microstructure of the alloy. In: INTERNATIONAL CONFERENCE ON SOLIDIFICATION AND GRAVITY, 6., 2014, Miskolc. Papers. ROÓSZ A.; TOMOLYA, K. Solidification and gravity 6. Zurich: Trans Tech Publi., 2014. p.361-366. (Materials Science Forum, v.790-791). 7 p. Coronado, J. J. Sinatora, A; Albertin, E . Cementite solidification in cast iron. Metallurgical and Materials Transactions, v.45B, n.3, p.181-814, jun., 2014. 3 p. Ferreira Neto, JB; Ribeiro, TR; Lima, ML; Lotto, AA ; Vilca, JB . Obtenção de silício grau solar por rota metalúrgica. In: CONGRESSO BRASILEIRO DE ENERGIA SOLAR, 5., 2014, Recife. Anais10 p Lima, ML. Martorano, MA; Ferreira Neto, JB . Metallurgical silicon refining by transient directional solidification. In: TMS ANNUAL MEETING AND EXHIBITION, 143., 2014, San Diego, California. Proceedings... WANG, Cong. et al. (Eds.). Energy technology 2014: carbon dioxide management and other technologies. New Jersy: Wiley, 2014. p.279-286. 10 p. Ribeiro, TR; Ferreira Neto, JB; Martorano, MA, Effects of Solidification Rate and Settling Time of SiC Particles on the Macrosegregation of Carbon in Silicon Ingots: Metallurgical and Materials Transactions E -Edição: online setembro L L IPT - São Paulo SP C Fredericci; M.F. de Campos; A.P. V. Braga; R.V. Martin; F.J. G. Landgraf; E. A. Périgo - Nd-enriched particles prepared from NdFeB magnets: A potencial separation route Journal of Alloys and Compounds - 615 - p. 410-414 - 2014 Thesis and Dissertations Lotto, AA, Remoção de fósforo de silício por fusão a vácuo, 2014, MSc Relevant Systems and calculations Steelmaking slag solidification for cement study applications Interactions between agglomerating agentes and iron ore and the phase formation and evolution during pellet firing Solar grade silicon refining Solidification of alloys in the system Sistema Fe-C-X (X = Si e/ou Cr e/ou Mo e/ou V e/ou W) L L PUC-Rio de Janeiro RJ • Research staff: – Prof. Fernando Cosme Rizzo Assunção – Prof. Roberto Ribeiro de Avillez • Research areas: – – – – – – Thermodynamics of steel processing (TECOMAT, oxides) Steel coatings (Galvanizing and other zinc coating processes). High temperature corrosion and oxidation. Microstructural evolution in steels (Q&P process). Nanostructured oxide synthesis. Negative thermal expansion coefficient materials. L L PUC-Rio de Janeiro -2015 • Prof F. Rizzo’s group – Dr. Antonio Mario Leal Martins – Dr. Valter Rocha dos Santos • Prof Rizzo as a visiting scientist in BAM-Berlin during 2014. Returning in 2015 to head the INT- National Institute of Technology, Rio de Janeiro. L L PUC – Prof Rizzo’s Projects • Materials development for energy production from fosssil fuels with low CO2 emission • Synthesis, Processing, Modeling and Characterization of Functional Oxides • Synthesis and Characterization of Ceramic Oxides/ Materials with Negative Thermal Expansion • Study of the photocatalytic degradation of toxic gases resulting from FCC process and development of photocatalytic materials • Morphological and crystallographical characterization of catalysts • Characterization of catalysts by Transmission Electronic Microscopy • Characterization of nanomaterials by X-ray diffraction • Development of thermoplastic based nanocomposites using titanate nanotubes and nanofibers • Qualification of wet welding procedures of steel • Implementation of Laboratory for Photocatalysis for study of pollutant gases reduction forming during refinement of petroleum • Characterization of the materials important for Petroleum Industry (Catalysts and advanced materials) by XRPD and TEM • High Temperature Corrosion in Industrial Systems of Oil and Gas Field L L PUC-Rio Prof Rizzo’s group recent activities • • • • • K. Chandra, A. Kranzmann, R. Saliwan Neumann, G. Oder, F. Rizzo High Temperature Oxidation Behavior of 9-12 % Cr Ferritic/Martensitic Steels in a Simulated Dry Oxyfuel Environment. Oxidation of Metals. , v.83, p.291 - 316, 2015. PONTÓN, PATRICIA I. ; D ALMEIDA, JOSÉ R.M. ; Marinkovic, Bojan A. ; SAVI', SLAVICA M. ; MANCIC, Lidija ; REY, NICOLÁS A. ; MORGADO, EDISSON ; Rizzo, Fernando C. . The effects of the chemical composition of titanate nanotubes and solvent type on 3-aminopropyltriethoxysilane grafting efficiency. Applied Surface Science , v. 301, p. 315-322, 2014. M. Mosquera Feijoo; A. Kranzmann; F. Rizzo; G. Oder, R. SalliwanNeumann.Influence of Single Surface Ash Layer on Dual Corrosion. Eurocorr 2014 (European Corrosion Congress), Italy, 2014. Daniel Massari de Souza Coelho; Axel Kranzmann, Fernando Rizzo.Influência da Atmosfera Dupla e Simples Na Corrosão de Ligas de Ferro a 600º. Congresso ABM 2014, Brasil, 2014. Organizing the German Brasil Materials Science and Engineering Meeting toghether with ABM and DGM PORTELLA, P. D. ; ASSUNCAO, F. C. R. . Materials Science Engineering - MSE 2014. 2014. PORTELLA, P. D. ; ASSUNCAO, F. C. R. . 1st Brazilian-German Symposium on Materials Science and Engineering – Congresso ABM 2014. Brasil, 2014. L L PUC- Prof Avillez 2015 Roberto R. de Avillez • • • Relevant activities: Studies in the Fe-Al-O system with USP and UFF Thermodynamic calculations together with UFF and GERDAU to support an Electric Arc Furnace model L L Universidade Federal do Ceará- Fortaleza UFC Researchers: Prof. Dr. Hamilton Ferreira Gomes de Abreu (UFC) Prof. Dr. Marcelo José Gomes da Silva (UFC) Dr. Luis Flávio Gaspar Herculano (UFC) Dr. Miloslav Beres (UFC)) Dr. Litzy Lina Choquechambi Catorceno (UFC) Prof. Dr. Francisco Nélio da Costa Freitas Dr. Neuman Fontenele Viana Main Research Themes: Metallic alloys development Crystallographic texture- macrotexture Microtexture Physical metallurgy of steels Martensitic transformation L L UFC – Main projects • Maraging 350 Steel Projetos Maraging 350: microstructure, phase transformations and forming. CAPES-SAE ProjectStrategic Materials- 2012 • Physical metallurgy of steels for the Oil Industry- Strategic Areas Program CAPES-FUNCAP, 2013. • Development and characterization of new metallic alloys with high corrosion resistance to face the new challenges in the oil and gas industry - PRONEM/FUNCAP/CNPq – Edital FUNCAP 09/2010 L L UFC- Thesis and dissertations • • Thesis and Dissertations Doctoral work – Lorena Braga de Moura, High Mo alloys for naftenic corrosion – Francisco Evaristo Uchoa Reis, Welding of high Mo+Cr alloys – Francisco das Chagas Oliveira Júnior, Mössbauer characterization of surface oxide films in Fe-Cr-Mo model alloys under corrosion – Luis Flávio Gaspar Herculano, Influence of Mo content on corrosion resistance and phase stability in model Fe-Cr-Mo alloys – Rodrigo Freitas Guimarães, Effect of Mo content on the weld joint microstructure of Fe-Cr-Mo alloys – Cristiana dos Santos Nunes, Dissimilar welds using Mar 350 e 250 as filler metal – Wellinson da Silva Tavares, Dissimilar welds using Mar 350 e 250 as filler metal – Jorge Luiz Cardoso, Evaluation of pitting resistance of superaustenitic steel AL 6XN PLUS TM and austenitic stainless steels AISI 304L, 316L E 317L L L UFC Publications • • • • • • Cruz, J. A.; Rodrigues, T. F. M.; Viana, V. D. C.; Abreu, H. F. G.; Santos, D. B.; Influence of Temperature and Time of Austempering Treatment on Mechanical Properties of SAE 9254 Commercial Steel. Steel Research International, v. 83, p. 22-31, 2012. Moura, L. B.; Guimaraes, R. F. (aluno de doutorado); Abreu, H. F. G.; Miranda, H. C.; Tavares, S. S. M.; Naphthenic corrosion resistance, mechanical properties and microstructure evolution of experimental Cr-Mo content with high Mo. Materials Research (São Carlos. Impresso), 2012. TAVARES, S.S.M., RODRIGUES, C.R., PARDAL, J.M.; BARBOSA, E.S.; ABREU,H.F.G.; Effects of post weld heat treatments on the microstructure and mechanical properties of dissimilar weld of supermartensític stainless steel, Materials Research,, 2014. ABREU, H.F.G. ; TAVARES, W.S. ; DE MIRANDA, HÉLIO CORDEIRO ; FONSECA, MARIA P. CINDRA ; VIRGENS-NETO, H.N. ; BÉRE , M. . Effect of Multipass Welding Using a Low Transformation Temperature Filler Metal on Residual Stress and Toughness. Materials Science Forum (Online), v. 783-786, p. 627-632, 2014. SARAIVA, D. L. ; BÉRE , M. ; SILVA, C. C. ; NUNES, C. S. ; SILVA, J. J. M. ; ABREU, H. F. G. . Application of low M s temperature consumable to dissimilar welded joint. Materials Science and Technology, v. 30, p. 1743284714Y.000-1062, 2014. MOURA, LORENA BRAGA ; DE ABREU, HAMILTON FERREIRA GOMES ; NEGREIROS, YURI SOARES . Computational thermodynamic analysis of secondary phases in super ferritic stainless steels. Journal of Materials Research and Technology, v. 2, p. 282-287, L L 2013. UFC relevant systems - Applications • • Systems Fe-Cr-Mo e Fe-Cr-Mo-Ni Systems involved in the design of Co- containing maraging steels L L UFPR- Paraná- Curitiba • Research staff L L UFPR – Research Projects In course: • Coatings for gas turbines, ANEEL, Petrobrás • Surfaces and coatings for high temperature- in-situ synthesis and performance CNPq • Pseudo-functional coatings in-situ processed CNPq • National Institute of Surface Engineering – INCT/ MEC-CNPq Concluded: • Innovation Laboratory- Surface engineering- FINEP L L UFPR- Publications • • • • • • • Benegra, M. ; Pintaúde, G. ; D'Oliveira, A. S. C. M. Microstructural stability of nickel aluminide coatings processed by PTA with different contents of aluminum. Acta Microscópica - Interamerican Committee of Societies for Electron Microscopy, v. 23, p. 70-77, 2014. - Brunetti, C. ; Pintaúde, G. ; D'Oliveira, Ana Sofia C. M. . The Influence of Fe Content on the Mechanical Properties of NiAl Coatings Processed In-Situ. Journal of Materials Engineering and Performance, p. 1, 2014. - Brunetti, C. ; Belloti, L. ; Pintaúde, G. ; D'Oliveira, Ana Sofia C. M. .Influence of Fe on the room and high-temperature sliding wear of NiAl coatings. Surface & Coatings Technology, v. 258, p. 160-167, 2014. - Sippel, J. F. ; D Oliveira, A. S. C. M. . Evaluation of Plasma Transferred Arc FeAl Alloyed Coatings. Journal of ASTM International (Online), v. 9, p. 103454-336354, 2012. - D´Oliveira, A. S. C. M. ; Takano, Edson Hiromassa ; Belloti, L. ;Cardoso. R. P. . Solidification of aluminide PTA coatings. International Journal of Materials Research, v. 9, p. 1159-1162, 2012. - Graf, K. ; D´Oliveira, A. S. C. M. . PTA hardfacing of Nb/Al coatings.Soldagem e Inspeção v. 17, p. 158-165, 2012. - Silva, R. L. ; D'Oliveira, A. S. C. M. . Influence of pack cementation parameters on the alumina formation on Ni based. In: Materials Science and TechnologyL 2013, Montreal. MST' 13, 2013. p. 2914- 2919. L UFPR- cont. • Patent D'Oliveira, Ana Sofia C. M. ; Drozda, F. O. ; Takano, E. ; Pianaro, S. A. Revestimentos cerâmicos soldados. 2014. • Visiting professor and courses • Dr Sten Wessman, from Swerea KIMAB AB,Sweden, visiting in 2014. as visiting researcher Sept-Dec 2014 • Courses: 2 graduate students and 1 professor took part in the Thermodynamic workshops in São Paulo and Rio. Computational Thermodynamic course at UFPR for 20 participants- sudents and researchers. L L Universidade Federal do Rio Grande do Sul – UFRGS 2015 •Research Staff - HECK, Prof. Dr.-Ing. Nestor Cezar - Coordenador do NTCM Núcleo de Termodinâmica Computacional para a Metalurgia UFRGS - BUZIN, Pedro – DSc student - SILVA, MSc Daniel dos Reis Silva - DSc student CNPq. - REIS, Bruno – MSc student CNPq - ROMEIRO, Lauro - DSc student - VILELA, Prof. Dr.-Ing. Antônio Cezar Faria - Coordenador do Laboratório de Siderurgia UFRGS - BIELEFELDT, Prof. Dr. Wagner Viana - LaSid e NTCM - UFRGS - ALMEIDA, Rodolfo – MSc student CNPq - VIEIRA, Deisi – MSc student - CARDOSO, Vinicius – MSc student - BELTRAMI, Júlia – MSc student CNPq L L UFRGS- (cont.) Research Themes • • • • • Waelz furnace modeling SOFC type biogás cell modeling Evaluating hydroxil capacity in CMSAT slags Evaluation of Electric Arc Furnace dust Development of secondary steelmaking slags for improvement of steel cleanness • Evaluation of EAF slags • Characterization of steelmaking slags via laboratory testing and computational thermodynamics L L UFRGS - Publications REIS, B. ; BIELEFELDT, W V. ; VILELA, ACF. Efficiency of Inclusion Absorption by Slags during Secondary Refining of Steel. ISIJ International, v. 54, p. 1584-1591, 2014. BIELEFELDT, W V. ; VILELA, ACF . STUDY OF INCLUSIONS IN HIGH SULFUR, AL-KILLED CATREATED STEEL VIA EXPERIMENTS AND THERMODYNAMIC CALCULATIONS. Steel Research International, v. 7, p. 1-10, 2014. BIELEFELDT, W V. ; HECK, N. C. ; VILELA, ACF . Thermodynamic Evaluation of the Slag System CaO-MgO-SiO2-Al2O3. In: AISTech 2014 Conference and Exposition, 2014, Indianápolis. AISTech 2014 Conference and Exposition, 2014. p. 1433-1445. PAULINO, M. A. S. ; KLUG, J. L. ; BIELEFELDT, W V. ; VILELA, ACF ; HECK, N. C. . OBTENÇÃO DE ESCÓRIA ESPUMANTE EM FORNO ELÉTRICO A ARCO: DETERMINAÇÃO DAS COMPOSIÇÕES PARA O SISTEMA CaO-SiO2-MgO-FeO. In: 45o Seminário de Aciaria da ABM - Internacional, 2014, Porto Alegre. 45o Seminário de Aciaria da ABM, 2014. p. 1-10. BARTOSIAKI, B. ; BIELEFELDT, WV. ; PEREIRA, J. A. M. ; VILELA, ACF. ESTUDO DE INCLUSÕES NÃO-METÁLICAS EM AÇOS APÓS DESOXIDAÇÃO E DURANTE TRATAMENTO EM FORNOPANELA. In: 45o Seminário de Aciaria da ABM - Internacional, 2014, Porto Alegre. 45o Seminário de Aciaria da ABM - Internacional, 2014. BARTOSIAKI, B. ; BIELEFELDT, WV. ; PEREIRA, J. A. M. ; VILELA, ACF. ESTUDO DE INCLUSÕES NÃO-METÁLICAS EM AÇOS DURANTE TRATAMENTO EM DESGASEIFICADOR A VÁCUO E INÍCIO DO LINGOTAMENTO CONTÍNUO. In: 45o Seminário de Aciaria da ABM - Internacional, 2014, L Porto Alegre. 45o Seminário de Aciaria da ABM - Internacional, 2014. p. 1-11. L UFRGS - Publications • CRUZ, R. T. ; BIELEFELDT, WV. ; BRAGANCA, S. R. ; PELISSER, G. F. . INFLUÊNCIA DA COMPOSIÇÃO DA ESCÓRIA DE PANELA NA DISSOLUÇÃO DO COATING (C2S). In: 45o Seminário de Aciaria da ABM - Internacional, 2014, Porto Alegre. 45o Seminário de Aciaria da ABM - Internacional, 2014. p. 1-9. • Bielefeldt, W V ; HECK, N. C. ; PAULINO, M. A. S. ; KLUG, J. L. ; VILELA, ACF. ESTUDO DA ESCÓRIA ESPUMANTE EM FORNO ELÉTRICO A ARCO. In: 69th ABM International Annual Congress, 2014, São Paulo. 69th ABM International Annual Congress, 2014. p. 114. • FRAGA, C. A. S. ; Bielefeldt, W V ; VILELA, AC F . ESTUDO DE CARACTERIZAÇÃO DE INCLUSÕES DE ÓXIDOS EM AÇO ALTO CARBONO. In: 14 ENEMET, 2014, São Paulo. 14 ENEMET, 2014. p. 1-11. • CAMACHO, B. I. ; Bielefeldt, W V; PEREIRA, J. A. M. ; VILELA, A C F . ESTUDO EXPERIMENTAL DO AVANÇO DE INCLUSÕES NÃO-METÁLICAS ATRAVÉS DO TRATAMENTO COM CÁLCIO. In: 69th ABM International Annual Congress, 2014, São Paulo. 69th ABM International Annual Congress, 2014. p. 1-15. • BUZIN, P. J. W. K. ; VILELA, A. C. F. ; HECK, N. C. . Thermodynamic study of EAFD genesis in the presence of chlorine in electric arc furnace. In: 69 Congresso anual da ABM, 2014, São Paulo. Anais do 69 Congresso anual da ABM, 2014. L L UFRGS - Publications HATWIG, R. A. ; HECK, N. C. ; ROCHA, A. S. . Caracterização das fases de aços super duplex através da simulação termodinâmica computacional. In: 69 Congresso da ABM, 2014, São Paulo. Anais do 69 Congresso da ABM, 2014. SILVA, A. L. ; HECK, N. C. . Metallic interconnects for application in high temperature solid oxide fuel cells (SOFCs): thermodynamic study of the oxidation of ferritic stainless steels. In: 69 Congresso anual da ABM, 2014, São Paulo. Anais do 69 Congresso anual da ABM, 2014. SILVA, A. L. ; HECK, N. C. . Solid oxide fuel cell (SOFC) with Cu-ceria anodes running on methane or biogas mixtures: thermodynamic analysis. In: 69 Congresso anual da ABM, 2014, São Paulo. Anais do 69 Congresso anual da ABM, 2014. BUZIN, P. J. W. K. ; VILELA, A. C. F. ; HECK, N. C. . EAFD generation - thermodynamic analysis of the Fe-Zn-O-Cl-H-C system. In: 45 Seminário de aciaria, 2014, Porto Alegre. Anais do 45 Seminário de aciaria, 2014. HECK, N. C. ; PEREIRA, J. M. ; VILELA, A. C. F. . Thermodynamic evaluation of the slags of the FeO-CaO-CrOx-MgO system at 1,873 K. In: 45 Seminário de aciaria, 2014, Porto Alegre. Anais do 45 Seminário de aciaria, 2014 L L UFSC- Santa Catarina, Florianópolis • Research Staff • • • • • • • • Prof. Aloísio Nelmo Klein Prof. Cristiano Binder Prof. Jose Daniel Biasoli de Mello Profª Sônia Maria Hickel Probst Prof Valderes Drago Prof João Batista Rodrigues Neto Prof Guilherme Mariz Barra Prof Alexandre Lago • + 3PhD, 11MSc and 13 Engineers. L L UFSC • CURRENT PROJECTS • • 2014 - Present Development of new metallic materials to increase the energy efficiency and sustainability of compressors 2014 - Present Development of low friction materials via powder moulding via injection 2012 - Present Materiais de elevado desempenho para novas funções de engenharia produzidos via metalurgia do pó. (PRONEX/FAPESC) 2012 - Present Powder Metallurgical Synthesis of Metals and Ceramics Challenges and Prospects for Advanced Composites and Components. 2012 - Present Development of wear resistant and dry self-lubricating coatings on sintered steels from polymer-derived ceramics (PDCs). [BRAGECRIM] 2010 - Present Desenvolvimento de Novos Materiais Sinterizados- Projeto PQ/CNPq 2010 2015 • • • • • • • • • • L L UFSC- Publications • Klein, Aloisio N. ; FURLAN, KP. ; SCHROEDER, R M. ; HAMMES, G ; Binder, C; RODRIGUES NETO, J B. ; PROBST, SH. ; DE MELLO, J D. Thermodynamic aspects during the processing of sintered materials. Powder Technology (Print) , v. 18, p. 193-203, 2014. • FURLAN, K P ; DE ASSUNÇÃO, J Z ; PAZ, G ; Binder, C ; KLEIN, AN . Sintering Studies and Microstructural Evolution of Fe-MoS2 Mixtures. Materials Science Forum (Online) , v. 802, p. 415-420, 2014. • Bendo, T. ; MALISKA, A.M. ; ACUÑA, J.J.S. ; Binder, C. ; DEMETRIO, K.B. ; KLEIN, A.N. . Nitriding of surface mo-enriched sintered iron: Structure and morphology of compound layer. Surface & Coatings Technology , v. 258, p. 368-373, 2014. • HAMMES, G ; DA COSTA GONÇALVES, P; Binder, C ; FURLAN, K P ; KLEIN, A N. Fe-hBN Composites Produced by Double Pressing and Double Sintering. Materials Science Forum (Online) , v. 802, p. 311-316, 2014. • RAMOS FILHO, A I ; Schroeder, R ; Binder, C ; Klein, A N. . Development of Fe-P Matrix Composites Containing Embedded Solid Lubricants. Materials Science Forum (Online) , v. 802, p. 96-101, 2014. • DEMÉTRIO, K B ; KLEIN, A N ; SCHAEFFER, L ; CONSONI, DR; MARTINELLI, A E; BENDO, T. Sinterability and microstructure evolution during sintering of ferrous powder mixtures. Materials Research (São Carlos. Impresso) , v. 16(5), p. 1030-1038, 2013. • PARUCKER, MOISÉS LUIZ ; KLEIN, ALOISIO NELMO ; Binder, Cristiano ; RISTOW JUNIOR, WALTER ; BINDER, ROBERTO . Development of self-lubricating composite materials of nickel with molybdenum disulfide, graphite and hexagonal boron nitride processed by powder metallurgy: preliminary study. Materials Research (São Carlos. Impresso) , v. 17, p. 180-185, 2013. • SCHROEDER, R. ; Schroeder, Renan ; Klein, A. N. ; Ramos Filho, A. I. ; Binder, Cristiano . Powder Injection Molding of Multimaterial Parts - Self Lubricating Steel Combined with Plain-Carbon Steel. Materials Science L L Forum (Online) , v. 727-728, p. 243-247, 2012. • FURLAN, K. P. ; BINDER, C. ; Klein, A. N. ; De Mello, JDB . Thermal Stability of the MoS2 Phase in Injection UFSC- Publications (cont.) • DEMÉTRIO, K B ; KLEIN, A N ; SCHAEFFER, L ; CONSONI, DR; MARTINELLI, A E; BENDO, T. Sinterability and microstructure evolution during sintering of ferrous powder mixtures. Materials Research (São Carlos. Impresso) , v. 16(5), p. 1030-1038, 2013. • PARUCKER, MOISÉS LUIZ ; KLEIN, ALOISIO NELMO ; Binder, Cristiano ; RISTOW JUNIOR, WALTER ; BINDER, ROBERTO . Development of selflubricating composite materials of nickel with molybdenum disulfide, graphite and hexagonal boron nitride processed by powder metallurgy: preliminary study. Materials Research (São Carlos. Impresso) , v. 17, p. 180-185, 2013. • SCHROEDER, R. ; Schroeder, Renan ; Klein, A. N. ; Ramos Filho, A. I. ; Binder, Cristiano . Powder Injection Molding of Multimaterial Parts - Self Lubricating Steel Combined with Plain-Carbon Steel. Materials Science Forum (Online) , v. 727-728, p. 243-247, 2012. • FURLAN, K. P. ; BINDER, C. ; Klein, A. N. ; De Mello, JDB . Thermal Stability of the MoS2 Phase in Injection Moulded 17-4 PH Stainless Steel. Journal of Materials Research and Technology, v. 1, p. 134-140, 2012. L L UFSC – Some Patents (most deposited and awarded in many countries) • • • • • Patente: Privilégio de Inovação. Número do registro: PI 0803956-9, data de depósito: 12/09/2008, título: "Composição metalúrgica de materiais particulados, produto sinterizado autolubrificante e processo de obtençao de produtos sinterizados autolubrificantes. Pedido de patente depositado em 12/09/2008 no INPI, No.: PI 0803956-9" . Patente: Privilégio de Inovação. Número do registro: PI 0805606-4, data de depósito: 15/12/2008, título: "Composição de materiais particulados para a formação de produtos autolubrificantes em aço sinterizado, produto em aço sinterizado autolubrificante e processo de obtenção de produtos autolubrificantes em aço sinterizado. Pedido de Patente de número PI 0805606-4, depositado em 15/12/2008." . Instituição(ões) financiadora(s): EMPRESA BRASILEIRA DE COMPRESSORES. Binder, R. ; BINDER, C. ; Hammes, G. ; Klein, A N . Plasma process and reactor for treating metallic pieces. 2009, França. Patente: Privilégio de Inovação. Número do registro: WO2009149526A8, data de depósito: 17/12/2009, título: "Plasma process and reactor for treating metallic pieces" , Instituição de registro:WIPO - World Intellectual Property Organization. Patente: Privilégio de Inovação. Número do registro: US2011286873-A1, data de depósito: 09/12/2009, título: "Composition of particulate materials for forming self-lubricating products in sintered steel, comprises iron as a main particulate metallic material, at least one particulate alloy element, and a non-metallic compound " , Instituição de registro:United States Patent and Trademark Office Patente: Privilégio de Inovação. Número do registro: JP2012502183(A), data de depósito: 26/01/2012, título: "'Metallurgical composition of particulate materials, self-lubricating L sintered products and process for obtaining self-lubricating sintered products." , Instituição de registro:Japanese Patent Office. L UFSC – Some Patents (most deposited and awarded in many countries) • Patente: Privilégio de Inovação. Número do registro: BR1020140054944, data de depósito: 10/03/2014, título: "Processo para síntese de partículas ocas metálicas nanoestruturadas na qual o metal é depositado sobre máscaras de sacrifícios pelo método de deposição autocatalítica sem potencial externo, partículas ocas metálicas nanoestruturadas, material particulado." , Instituição de registro:INPI - Instituto Nacional da Propriedade Industrial. • Patente: Privilégio de Inovação. Número do registro: CN104144760A, data de depósito: 12/11/2014, título: "Process for manufacturing a porous body by powder metallurgy and metallurgic composition of particulate materials" , Instituição de registro:Chinese Patent Office. Patente: Privilégio de Inovação. Número do registro: WO2014057346, data de depósito: 17/04/2014, título: "MANUFACTURING PROCESS OF A POROUS COMPONENT AND A POROUS COMPONENT " , Instituição de registro:WIPO - World Intellectual Property Organization. • L L USIMINAS- Ipatinga Steelmill MG, Brazil -2015 Leonardo José da Silva Oliveira Melt Shop Evaluation of inclusion formation in secondary steelmaking (system CaO-Al2O3-CaS); Studies in steel solidification; Studies in slag/metal equilibrium. Blast Furnace Beatriz Fausta Gandra Thiago Pinto Silva Evaluation of use of silica-alumina refractories together with the metallic charge of the Blast-Furnaces Effects of MgO on the sintering process and on the metallurgical characteristics of the produced sinter. L L USIMINAS –cont. Fabio Dias Murari Meire Lage Hot Rolled Steels • Evaluation of reheating conditions of slabs in the dissolution of precipitates on mechanical properties and toughness of thick plates of microalloyed steels • Result: Optimization of the processing conditions and alloy compositions in the thick plate line of USIMINAS. Wear Resistant Materials Ivênio de Oliveira Teixeira • Characterization of wear resistant steels • Optimization of chemical composition and structure of sintering machine bed. L L USIMINAS – Some publications Submitted: • M G Lage, A Costa e Silva, EVALUATING SEGREGATION IN HSLA STEELS USING COMPUTATIONAL THERMODYNAMICS, Journal of Materials Research and Technology Published: • Murari FD, da Costa e Silva ALV, de Avillez RR. Cold-rolled multiphase boron steels: microstructure and mechanical properties. Journal of Materials Research and Technology. 2015 Apr;4(2):191–6. L L UFF – Volta Redonda RJ - 2015 • Research staff: – Prof. André Luiz V. da Costa e Silva – Prof Flavio Ferreira, Prof Thales • Research areas: – – – – Steelmaking process modeling: refractory –slag -metal interactions. Non-metallic inclusion formation in steel. Microstructural evolution in steels. Slag viscosity modeling coupled with thermodynamic models • Highlights – Two Computational Thermodynamics Workshop simultaneous with ABM Conference. Annual short course for UFF undergraduates. Workshops in some Brazilian Universities – Donation by GERDAU Aços Longos S.A. of the Teaching Laboratory for Computational Steelmaking. Start of the GERDAU Computational Thermodynamics for Steelmaking scholarship – Industry interaction for teaching, on-site learning,motivation of students. – IOM3 Hume Rothery Prize 2014 L L Prof Andre Costa e Silva awarded IOM3 2014 Hume-Rothery Prize L L UFF – publication examples COSTA E SILVA, A. Computational Thermodynamics as a tool in Integrated Computational Materials Engineering- Invited Talk – 2nd ECEM-SanCas Materials Science and Engineering Meeting, São Carlos, SP, UFSCar-USP, Invited Talk. A. Costa e Silva, SEGREGAÇÃO EM AÇOS ALTA-RESISTÊNCIA BAIXA LIGA (ARBL) PARA APLICAÇÕES EM SERVIÇO COM H2S- AVALIAÇÃO POR TERMODINÂMICA COMPUTACIONAL. Tecnologia em Metalurgia, Materiais e Mineração , v.11, p.3 - 13, 2014. de Avillez, R R., Siqueira, RNC, A. Costa e Silva.MODELO DE ENERGIA DE GIBBS PARA O ESPINÉLIO Al2MnO4 BASEADO NO FORMALISMO DA ENERGIA COMPOSTA;. Tecnologia em Metalurgia, Materiais e Mineração, v.10, p.311 - 317, 2013. PALUMBO, M., BURTON, B., COSTA E SILVA, A., FULTZ, B., GRABOWSKI, B., GRIMVALL, G., HALLSTEDT, B., HELLMAN, O., LINDAHL, B., SCHNEIDER, A., TURCHI, P. E. A., XIONG, W. Thermodynamic modelling of crystalline unary phases. Physica Status Solidi. B, Basic Research. , v.251, p.14 - 32, 2013. Beneduce, F. Magnabosco R, Costa e Silva, AAVALIAÇÃO DE TRINCAS A QUENTE EM FUNDIDOS DE PRECISÃO EM SUPERLIGAS POR TERMODINÂMICA COMPUTACIONAL In: 69 CONGRESSO ANUAL DA ABM - INTERNACIONAL, 2014, São Paulo. Anais do 69º Congresso Anual da ABM - Internacional. São Paulo: ABM, 2014. p.1 - 7 Mercier MF, Ferreira Neto, O. Tavares, RP Costa e Silva, A CÁLCULO DE ADIÇÃO DINÂMICA DE CÁLCIO SILÍCIO PARA AÇO MICROLIGADO AO CROMO E MOLIBDÊNIO In: 69 CONGRESSO ANUAL DA ABM - INTERNACIONAL, 2014, São Paulo. Anais do 69º Congresso Anual da ABM - Internacional. São Paulo: ABM, 2014. p.1 - 7 L L UFF publications ex. (Cont) Lino, R. E., Marins A. M. F., Marchl, L.A., Mendes, J. A., Penna, L.V., J G Costa Neto, Caldeira, J. H. P., Costa e Silva, A INFLUÊNCIA DA COMPOSIÇÃO QUÍMICA NA LINGOTABILIDADE DE AÇOS In: 69 CONGRESSO ANUAL DA ABM - INTERNACIONAL, 2014, São Paulo Anais do 69º Congresso Anual da ABM - Internacional. São Paulo: ABM, 2014. p.1 - 12 Costa e Silva, A, Avillez, R RO EFEITO DA ENERGIA INTERFACIAL NO MODELAMENTO DA CINÉTICA DE PRECIPITAÇÃO DE CARBONETOS DE CROMO EM AÇOS INOXIDÁVEIS In: 69 CONGRESSO ANUAL DA ABM - INTERNACIONAL, 2014, São Paulo. Anais do 69º Congresso Anual da ABM - Internacional. São Paulo: ABM, 2014. p.1 - 10 Costa e Silva, A, APPLICATION OF COMPUTATIONAL THERMODYNAMICS TO STEELMAKING AND PROCESSING In: 19a Conferencia del Acero IAS 2013 - Reducción, Acería, Laminación y Productos de Acero = 9th IAS Steel Conference 2013 - Ironmaking, Steelmaking, Rolling and Steel Products, 2013, Rosario, Argentina. 9th IAS Steel Conference 2013 - Ironmaking, Steelmaking, Rolling and Steel Products. San Nicolás: Inst. Argentino de Siderurgia, 2013. p.1 - 21 Beneduce F, Magnabosco, R, Costa e Silva A, SUPERALLOYS HOT TEARING EVALUATION USING COMPUTATIONAL THERMODYNAMICS In: 14th DISCUSSION MEETING ON THERMODYNAMICS OF ALLOYS - TOFA 2014, BRNO. 14th DISCUSSION MEETING ON THERMODYNAMICS OF ALLOYS - TOFA 2014. , 2014. p.O31 - L L Linkedin Phase Diagrams of Materials Group • Created by A Costa e Silva in 2009 (closed, not moderated*) 2009 April 2014 L L UFRJ – Federal University of Rio de Janeiro Main researcher – Prof Dilson Silva dos Santos • • Themes Alloy 718 processing for Nuclear Applications (PhD research) Leonardo Sales Araujo Evaluation of pseudo-binary systems, calculation of phase fractions. Solidification modeling (Scheil) Comparison with experimental determination (EDS). Laves phase compostion. Evaluation of the effect of Nb content and the delta phase solvus line. • Corrosion and microstructure of Alloy 718 (PhD research) Lena de Castro Menezes Estimation of delta phase as a function of cooling rate and chemical composition, in special Nb content. • Development of an alloy for hydrogen storage (PhD research) Alejandro David Martinez Thermodynamic studies (including binary, pseudo-binaries and ternary diagrams) of the systems Ti-Cr-V e Ti-Cr-Nb. Evaluation of effects of cooling rate. • Processing of Alloy X750 for springs MSc research) Gabriela Regina Xavier Phase diagram, constitution diagrams and phase fraction variation wrt to chemical composition and temperature for the alloy. L L UFRJ – Federal University of Rio de Janeiro Hydrogen embrittlement in hyper-duplex stainless steels Felipe Salvio Hydrogen embrittlement in super-duplex stainless steels Bruno Raphael de Souza Analysis of hydrogen permeation in Alloy 625 Gustavo Brandolin L L USP – São Paulo 2015 • Research staff: – Prof. Hélio Goldenstein • Main activities: – Magnetic materials Co-Sm • Publication at XL CALPHAD in cooperation with UFF – Oxides – (Al-Mn-Ti-O) • Publications (CALPHAD 2010 and CALPHAD 2011) – Precipitation during aging heat treatment of in Inconel 718 • Publication at XL CALPHAD in cooperation with UFF – Precipitates in 12%Cr stainless steels. Modelling of the thermodynamics and kinetics of austenite eutectoid decomposition. L 53 L USP Research area: Alloy thermodynamics and development of innovative metallic materials Research staff – – – – – – Cláudio Geraldo Schön Luiz Tadeu Fernandes Eleno Helena Maria Petrilli Cynthia Miwa Noda Marina Moretão Felipe Eduardo de Paula Santos Highlights: – TOFA2016 will take place in Brazil (tentative venue: Santos). Strong collaboration with: –Instituto de Física da Universidade de São Paulo, –Universidade Nacional Tecnologica del Cono Sur de Lima (UNTECS, Peru) L L USP Projects: • Assessment of subsystems targeting a description of U-Mo-Nb-Zr • Ab initio calculation of systems Fe-X (X = Ti,Zr,Hf,V,Nb,Ta,Mo,W) and Al-M (M= Sc,Y,Ti,Zr,Hf,V,Nb,Ta,Cr,Mo,W) • Development of a CD-CVM implementation for the irregular tetrahedron approximation • Investigation of the non-extensive spinodal line in Tsallis' formalism Some publications: • Eleno, L. T. F., Schön, C. G. "Ternary interaction parameters in CALPHAD solution models" Braz. J. Phys. 44 (2014) 208-214 • Eleno, L. T. F. et al. "Ordering phase relationships in ternary iron aluminides, CALPHAD 44 (2014) 70 - 80. L L EEL-USP (formerly FAENQUIL)- Lorena, SP Prof. Hugo Sandim L L L L L L L L L L L L L L L L L L L L L L L L L L APDIC 2011 Report Villares Metals S/A – Sumaré SP • Specialty Steels and Alloys • R&D • New alloys, alloy and process development. • Researchers Alexandre Bellegard Farina, MsC José Britti Bacalhau, MSc Alexandre Sokolowski, MSc Eduardo Netto de Souza, PhD Roberto Tibúrcio Frota, MSc Mario Mantovani, PhD Fernanda Moreno Rodrigues L L APDIC 2011 Report Work in Progress • Researcher : Alexandre Bellegard Farina, MSc • Development of new valve alloys and Ni-based alloys using thermodynamic simulations with Thermo-Calc software coupled with TCFE6 and TTNI8 thermodynamic databases. • Researcher: José Britti Bacalhau, MsC • Development of new tool steels and high speed steels using thermodynamic simulations with Thermo-Calc software coupled with TCFE6 thermodynamic database. • Researcher: Alexandre Sokolowski, MSc : • Development of a new stainless steels using thermodynamic simulations with Thermo-Calc software and TCFE6 thermodynamic database. • Researcher: Fernanda Moreno Rodrigues : • Development of a new stainless steels using thermodynamic simulations with Thermo-Calc software and TCFE6 thermodynamic database. L L APDIC 2011 Report Work in Progress • Researcher: Eduardo Netto de Souza, PhD: • Simulations of the solidification process with dedicated software coupled with thermodynamic data extracted from Thermo-Calc software using TCFE6 and TTNI8 thermodynamic databases. • Definition of parameters for continuous casting process using data from thermodynamic simulations with Thermo-Calc software coupled with SLAG and TCFE6 database. • Researcher: Mario Mantovani, PhD • Thermodynamic modeling of slag/metal reactions for nom-metallic inclusions control and process optimization using Thermo-Calc software coupled with TCFE6, SLAG and TTNI8 thermodynamic databases. • Researcher: Roberto Tibúrcio Frota, MSc: • Thermo mechanical modeling of rolling and forging process of alloys with dedicated software coupled with thermodynamic simulations of alloys using Thermo-Calc software and TCFE6 and TTNI8 thermodynamic databases. L L