!#"%$&'$#( $#( !)+*, !)- .
/103254036786 9;:<650346 =2>0@?50@AB6
CEdonMDGFIpqHJFsDGrtKMRuLGDONQSUvwPQVxR-SUYoTWg\VXbeTZhyY\[^[^]+]+_a`z_a`cbebed\d\f f5g\behEbai^h^j-kmlEi+bed\f3b
j+d\PXP|pI{}wrtP}R-+SUrwvZpI|Yope~-DPMj+Rh^WVMi^ vwd->h~ud-uh^^`j-]bed\`fE}
St`vw@j+~uf\`^h j-bed-hYj+~ubed\fE
CELr
PXHNMrNWeMW^£¤Fqo¥¦RFaIfnQLOB§¨rwFUpeRIP}wQSPXWnQvyLGPY\V|©ªv|rwv|§t
r«XV|`zv|PwvWHq¬QYP|M|xrf+kmNMP|r}{}YUDOSUpIxr«
Brw{F+UMFsPXeNWpIe^rWYF +pIUP[3Y\M¡ ¢\d\~+
¯ ®u°W±²¨³M´¶µ·o¸
b¶NWepIrBBnQ¹UºXrPXrwFuHr|NQHDOerwF\»¼nQNQMPX{UNwqPXDF-B½[EnM¾G{DGHUP½b¶NQr|pIw¿XNQDGHUP
ÀÁ ·Â ÁMÃÄÅÃ
d\SwOP|S KM¾ÆInMCELGrÇDGFsS epIDO§QnMb¶DGNW¹UIºXper«rBBBnQrW¹UFuºXrLGÈ{ÉwnQNW¾Oe{rWFuDHNQP}PDONQ~r|UpIpewpq¿XP NQDGHUP
dVM\SwOP|VS KM¾ÆInM+CELGr«DUFsVFeeÊ|N
pIË|DP}rwoLOQË
FaP}IDG{}penBÉWUnMINWnM¾Ge{pqrP}DGHUMPXP}P½eÊwDOeNM{}rwrwDpepeHWDP P¿XNM¢DIHr|P {DGHUP
VMVM V f5f@UBÉWÌnQFeHPwr|¹§¨º|r}peIBP}xMBP|HqFu¬QpeKQrBP|BpsDGINM¾GH|nMULp P|F-FenM§QP¢IÊ|{DHP|F\yr«¢Ir|{rBxg\r|¬Mp
VMd\ P| KM¾ÆInMLGrpIr| KMpIDGUM~PwBrwUpeF\DP|K¨FuBpImDOÊBLGBDOWDHP|Pw¹UF-ºXr}BrwLOrBF-HXP|eLOr|DGÍU{PwMrWFP
QQO VS i+~r|r|IpIPwD¹P½ºXrByBpIx©KQnMÎ-LGFIDºXF rBrWFuKQPXpIUFuByULOÌH¦epIÏ
UF-BmË¢PXLGÐNtHJDP
QQ `c©ªDGwrwPwLOÑ̹HJº|nMr½LP|BF\yK¨¬Mr|DLBPXpIpIr|UwF ÑNMDGr
ttd\O P|VS KM¾ÆInMk^LGr}LGpInM{KtrWNWFuIBKtrwDOFurw{NWyJeInQr|peP|K¨DP}DGF pq^P|¹eÏ
rwUpeFuDPByBFsmDG{|pIJnMIK¨peDrwP F
tt ÒBpIr|KM{pIKMDGULGMrwPwFuBxUF\P|KMyLGDGpIHUP|KM¹JpIÏ
UÌFeF\NWMIxPw¹JFsÏ
DG{UF\JeBpIrWDP Fu|pInMKtrWF
M Md\O P|VS KM¾ÆInMÓMhELGr«rwpIpe §M{«DÆqPwPX¹DF\ºX~r}{}rwBrwpeyLODÌP}r|HJnMpIB§MLmPXDOIpIr|P|UpIDGFU§MFuRÔDÆq{{PXLGDr|UFuLGHJÑU{nQHJLGnQr|P|LGLGpeUPwÌHJF\F\nQMP}LGP|DGPXpeKQeÌP|Ê|F ps{IDODp+HPwMFu^¬Mrwr|pe{§QDÆr|qPXN
DnQF-HP¢LOÌePXÊwpI{UFDGHUP|F
M M `chEpIrw§MLOÌDÆqHJPXnMDLF\P|{}FuBrwDLOP¢ÌHJIÊ|nM{LPXDGpIHUUP|F\FuU¬M{Õe{Uper|rwLGNWÑUntHnMHJLGLGUPwPXFupIKtUFrwLODP¢Ir|{DHP|F
Md\ P| KM¾ÆInMhELGrpI§MDÆqPXDF\-¬MHDODG§QMperwDFuMP|mF §QP|FeUªÖMMP|BrwpeÌFsmP|HDOIPwBr|pIUF
QQO VS f-dor|HJDNtBHJrWFuDOe^rWFu§t|P|UFeUpIF-P|DGBF\nMFspIrwrw§MFupImmw{«HJDP|BHr DOrWF §tP|Fe
Qd\ P| KM¾ÆInMÓMLGrrwpI ¹UP½QP|hFuÒBDGDNwMIP|¹UpqºXP|r HU¹JÏ
peUÌFuBnQ|H¹DGº|Mr r §QPwFs
BBO VS ÔrXFsIIP|§MNQDOHLGDGDP|MDGP|F-BBympIpIUUMBr×ntÒ¹ºX{Õr ||nQP
Bd\ P| KM¾ÆInMCELGrDGP|Ù |pqPX{«h5P|F\UFsBIyPwBK¨r«rXeFsUÊwNQLODHJBDP|rFUHJRpIBDGFsDIPXP||LOpqDGNMPX{«r PwF\Mm©P¢IDO{«PXpÌØMBDPXwpIP|{PwFoMxÓMpIrwFsuyBUÔr|nMpI§QPXDOÒ
−
−
−
QUÍMICA BIOINORGÂNICA I
P:43140 A:2006/2007 D:1929 C:102 R:10
Página 1 de 2
!#"%$&'$#( $#( !)+*, !)- .
/103254036786 9;:<650346 =2>0@?50@AB6
ÙQÙQO VS ÓM~rwpepI{½{}nMrBLBP|DGF\NQ¿|y{}UFsDHeP}pInBMeP}nQpI»¼PwrwF pe{«P|¹UºXr}BxFsÊwLODBrWFoDGÊ|NQDGHrwF
TQTQd\O P|VS KM¾ÆInMKM+LGrpIDr|BT KMpIr|pIDGwUÑMfNMPwDGLOBr wUnMF\NQ|F-UPwpIFsP|K¨DGFuUHJBerWrwFuF-QLGP}{ÉWnMNW¾G{IrwDGF\HUPpeUBKMrwpIFuUFeULONWUI{}PXUeDGNWË|erwrwF FupIKQpeÌFsUNwqP¢IDOËwrwF
TQTQ k^k^pIpInMnMKtKtrrVMSwRR{}{}IIP|P|DGDGF-F-P|P|LGLGHUHUPXPXLGLGDODONMNMrWr½F eUpepIrwFerwF
TQTQ k^k^pIpInMnMKtKtrrSÌSU
TQTQ¡ Ù k^k^pIpInMnMKtKtrrS×SÌ TQTQOTSÌv k^k^pInMpInMKtK¨rrcS¢
SUÙMRÔR rwrwFuF\¬QWP|P|LOFerwU|F\ÑUNMNMr|§QrWpeF ÌF
d\SÌvMP|GKMS ¾ÆInMLGrÇiSÌr|v{NQH[ELGPXnMe¾OnM{pqP DHPBxHrWrwpIMNQPw¹ºXr½b¦RBUFsepInBenQpIP}yDFsrw{}UpeDP
SÌSÌvMvM¡ V baiFeÚMr|{{pIpIDrFs{Byr HJr
r|pqBNtP|¹º|rZyÌFaIpenBInMpqP|F
d\SwS|P|GKMS ¾ÆInMLGrÇË
SwDS BNtHJ[EDPnMJ¾O{ÒBKtDHUPpeDG{BxNWHIrWP|rwLªpIMMP}NQUPwFs¹eºXpIr½nBebsnQb¦pIRQP}©DOWLGUP|HJ¹UeºXpIr Ê|NMDHP
SwSwS|S|¡ V ~~rwpIr|peDpIP|DGP}FuBByxÌHUFaPXI{penQKtHJr«enMBpqyP½LGDGwLGUPXH¦NtIBpeÊwr NMDHP
SwSwS|S|¡ CE»¼DÆU»¼UDÆIperÛUNWBeyUF-ÜWePXDG¬MKtN rWF+~ByLGHJLGr
p r|pqBUNQP|¹UºXrQR|Ur|{JIpeDPZrBHJIPXÑÌBpIDGHUPMØMÉWnQP|MpIPwMPxKMLPXNtP½mIJIpIP|ÑUBpIDGHUP
−
Ý ´a®EÞe´a·Â ÁMÃßEÃ
`c
¬QDGpeUDGFIË|FeULOUpUp-ØBC½k} Ó\©GGÖQÖQf\~ePXá
pIDGpUNQØBFC½ØQ fZ â5OÖ b¶GNMØtr|©pIP|wNMP|XNM»¼DrwHmpIdo¬MdEU {ZDGOFsÖ epIb¶à NMrwØMpeÔWPXÌPXNMpqDHyFsrwdoNª¬MØMVX{v|v|DFaQI peàwØ¡hÒ
»¼r|pqÛ]NMDGË|pqFeDÆaàpeÌFeFUØãSUTwTX
0
0
0
æä å ³B·-ç+·èç+±@éµ Ã Þs´ ÃÔêìë ·
ÒMP|{}^íQNtPXLîÓMpIUÉWnMÐNtHJDP½BxP|nMLP|F\eUÊ|pIDGHr KMpq¢IDGHUP|F
−
QUÍMICA BIOINORGÂNICA I
P:43140 A:2006/2007 D:1929 C:102 R:10
Página 2 de 2