Curriculum vitae
Maria de Fátima Costa Guedes da Silva
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
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Index
2. EDUCATION ............................................................................................................................................... 3
3. SCIENTIFIC CARRER ................................................................................................................................. 3
4. POSITIONS ................................................................................................................................................. 4
5. TEACHING COMMITMENTS ....................................................................................................................... 5
AT UNIVERSIDADE LUSÓFONA DE HUMANIDADES E TECNOLOGIAS (ULHT, LISBON) ...................... 5
AT INSTITUTO SUPERIOR TÉCNICO (IST, LISBON)................................................................................ 5
6. MAIN RESEARCH AREAS AND METHODS.................................................................................................. 5
GENERAL AREAS ...................................................................................................................................... 5
SPECIFIC AREAS ....................................................................................................................................... 5
TECHNIQUES ............................................................................................................................................. 6
7. PROJECTS .................................................................................................................................................. 6
8. RESERARCH TRAINING SUPERVISION ....................................................................................................... 7
9. PUBLICATIONS .......................................................................................................................................... 9
I – CONTRIBUTIONS IN BOOKS OR IN REVIEWS ..................................................................................... 9
II – RESEARCH PAPERS.......................................................................................................................... 10
III  RESEARCH PAPERS IN A NATIONAL (REFEREED) JOURNAL ...................................................... 27
IV – PATENTS ......................................................................................................................................... 28
INVITED LESSONS ................................................................................................................................... 30
COMMUNICATIONS (ORAL AND POSTER) AT CONGRESSES. ................................................................ 31
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Abridge CV
Name : Maria de Fátima Costa Guedes da Silva.
Nationality – Portuguese
Date and Place of Birth - May 12th, 1958, Porto.
Education - Chemistry (1982, FCL); Masters in Chemistry (1989, IST); D. Phil. in Chemical Engineering (1993,
IST).
http://cqe.ist.utl.pt/personal_pages/pages/fatima_guedes.php
Present positions :
i) Associate Professor (Universidade Lusófona de Humanidades e Tecnologias -ULHT, since 1995).
ii) Researcher at the Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais,
1049-001 Lisbon, Portugal
Contacts:
E-mail : [email protected]
Tel.: +351.218.419.207 (office); +351.218.419.235 (lab.); +351.218.417.657 (X-ray lab.)
Mobile: +351.936 408 681
Teaching commitments:
Organic Chemistry (ULHT, since 1996); Analytical Chemistry (ULHT, since 1996); Structural Analysis (ULHT,
1996-2006); Chemical Analysis (ULHT, 2005-2006); Inorganic Chemistry I and II (ULHT, 2009); General
Chemistry (ULHT, 2011).
Area of scientific activity
Bioinorganic, Inorganic and Analytical Chemistries; Coordination and Organometallic Chemistries. Molecular
electrochemistry. X-ray Diffraction analysis.
Main research interests
• Activation, by transition metal centres, of small molecules with biological, environmental,
pharmacological or industrial significance (alkanes, nitriles, cyanamides, oximes, oxadiazolines,
carboxamides, amidines, alkynes, phosphaalkynes, isonitriles, olefins, nitric oxide, dinitrogen, diazo
compounds, azides, cyanates, dihydrogen, etc.);
• Mechanistic investigation of the mechanisms of fast reactions (e.g. protonation or electron transfer
processes), mainly by digital simulation of cyclic voltammetry;
• conventional and non-conventional electrochemical methods, the latter including fast cyclic voltammetry
and digital simulation;
• Single crystal X-ray diffraction analysis.
Official appointments, membership of professional bodies, commissions, etc.:
Member of the Portuguese Electrochemical Society (since 1987). Member of the Iberoamerican Society of
Electrochemistry (since its foundation, 1992). Editor of the Journal Portugaliae Electrochimica Acta (1996-2002).
Member of the Directive board of the Portuguese Electrochemical Society (1996-2002). Member of the Organizing
or Cientific Committees of the following symposia: NATO Advanced Research Workshop on "Molecular
Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds" (Sintra, Portugal, 1992) (Director: A.
Pombeiro, Co-director: J. McCleverty); 9º, 10º and 11º Meetings of the Portuguese Electrochemical Society; XV
Meeting of the Iberoamerican Society of Electrochemistry, SIBAE (Évora, 2002); 12º Meetings of the Portuguese
Electrochemical Society /Symposium on Molecular Electrochemistry (Academia das Ciências de Lisbon) (2003);
XXV Int. Conf. Organometallic Chemistry (ICOMC2012, held in Lisbon in 2012; chairman: A. Pombeiro).
Recent collaborations in research projects: “Metal-based Synthons with Pharmacological Significance” (Project
POCTI/QUI/43415/2001, sponsored by the POCTI programme, FCT). “Early-Late Multinuclear Metal Systems on
Design and Development of New Materials” (NATO Collaborative Linkage Grant PST. CLG. 979289). “Transition
Metal Chemistry and Catalysis in Aqueous Media” [Project MRTN-CT-2003-503864, Human Resources and
Mobility (HRM) Marie Curie Research Training Network (RTN)]. “Chemical Synthesis and Catalysis” (Project
CONC-REEQ/543/2001, National Programme for Re-Equipping Science). “Catalytic Carboxylation of Alkanes”
(Project POCI/QUI/58821/2004, sponsored by the POCI 2010 Programme, FCT).
Reserarch training supervision: 3 Ph.D. (two awarded); 3 foreign Post-doc. fellows.
Publications: 2 Chapters and 8 other contributions in books; ca. 168 research papers in International Journals; 19
research papers in a national Journal; ca. 10 patents; 5 invited lectures in international Meetings; ca. 157 oral or
poster communications in international congresses.
Citation Report
2,337 citations (142 publications found); average citations per publication = 14,46;
h-index = 26 (ISI Web of Knowledge, June 5th, 2012)
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Maria de Fátima Costa Guedes da Silva
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1. IDENTIFICATION
Name : Maria de Fátima Costa Guedes da Silva.
Date and Place of Birth: 12th May, 1958.
Nationality: Portuguese.
Present positions
i) Associate Professor (Universidade Lusófona de Humanidades e Tecnologias -ULHT, since
1995).
ii) Researcher at the Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av.
Rovisco Pais, 1049-001 Lisbon, Portugal
Official addresses:
Teaching: Universidade Lusófona de Humanidades e Tecnologias, Av. Campo Grande 376,
1749-024 Lisbon
Research: Centro de Química Estrutural, Complexo I, Instituto Superior Técnico,
Av. Rovisco Pais, 1049-001 Lisbon
Contacts:
Teleph: +351-210417657 (X-ray lab)/ +351-218 419 225 (lab) or 207 (Office).
E-mail: [email protected]
URL: http://cqe.ist.utl.pt/personal_pages/pages/fatima_guedes.php
2. EDUCATION
Degree : Chemistry, University of Lisbon, 1982.
Master : "Chemistry of the catalytic processes", IST, TU Lisbon, l989. Supervisor Prof. Dr. Armando J.L.
Pombeiro.
PhD: Chemical Engeneering, IST, TU Lisbon, 1993. Supervisor Prof. Dr. Armando J.L. Pombeiro.
3. SCIENTIFIC CARRER
After graduation the research began, free of charge, in the Electroplating field, at the Center for
Electrochemistry and Kinetics, University of Lisbon, under the guidance of Prof. Isabel Pereira. In 1986
she was admitted to the Master in Chemistry of Catalytic Processes (IST) and in 1987 she was awarded a
Master's scholarship by INIC. At this stage, the work was carried out under the supervision of Prof. Dr.
Armando Pombeiro at the Centro de Química Estrutural (IST). Having completed the Master she
continued her studies in the same place and with the same supervisor, under a PhD fellowship [initially
granted by INIC, later transferred to the JNICT (CIENCIA Program) ], jointly in Line I (Bioinorganic
Chemistry under the responsibility of Prof. Fraústo Dr. da Silva) and in Line V (Coordination Chemistry
and Molecular Electrochemistry, under the responsibility of Prof. Armando Pombeiro)].
During the PhD:
i) She prepared the first rhenium(I) complexes containing chelating diphosphines in cis position and
synthesized a series of mono-and di-nitrile compounds with that metal center, as well as, by protonation
reactions, some derived metheleneamide species.
ii) She devoted to the analysis of complex spectra of nuclear magnetic resonance by using the iterative
spin simulation program LAOCOON.
iii) In collaboration with Prof. Christian Amatore, École Normale Superieure, in Paris, she developed
non-conventional electrochemical techniques, particularly fast cyclic voltammetry and cyclic
voltammetry in steady-state conditions, and she built a potentiostat and her own ultramicroelectrodes of
gold and platinum (diameters up to 5 m).
iv) She began the study of mechanisms of fast reactions by techniques of digital simulation in cyclic
voltammetry and stopped flow spectrophotometry, in collaboration with Profs. Christian Amatore and
Richard A. Henderson (Univ. of Sussex), respectively.
In parallel to the research work leading to the PhD degree, but regardless of this, and given the interest in
studying the electrochemical behaviour of complexes with biological significance:
v) Collaborated with the group of Prof. Fraústo da Silva in the investigation of the electrochemical
behaviour of complexes of vanadium (IV), models of Amavadine.
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Maria de Fátima Costa Guedes da Silva
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vi) Collaborated in the study of the electrochemical properties of cobalt (II), nickel (II) and copper (II)
complexes with Schiff bases containing indole groups, which were prepared by the group of Prof. P. Gili,
University of La Laguna, Tenerife.
vii) Collaborated in the study of the electrochemical properties of palladium (II) and platinum (II)
complexes with Fischer type carbene ligands, in collaboration with the group of Prof. Rino. A. Michelin,
University of Padua.
viii) Collaborated in the study, by electrochemical techniques, of the effects of substituents on
cyclopentadienyl rings in ferrocene compounds synthesized by Dr. Rudolf Herrmann, University of
Munich, which allowed the determination of p (Hammett) and *(Taft) parameters for 73 of these
substituents.
After the PhD (1993), the research has been developed in different scientific general areas:
a) Molecular electrochemistry:
• Developed simulation techniques for digital cyclic voltammetry which has allowed the study of
various mechanisms of anodically induced fast reactions, particularly in systems of biological
significance or application in organic synthesis.
• Established a new type of mechanism of electrocatalises and demonstrated the occurrence of a
Michaelis Menten type electrocatalytic process for the oxidation of thiols mediated by a complex
of vanadium, an Amavadin model (collaboration with the group of Prof. Fraústo da Silva and
Prof. C. Amatore).
• Established the mechanism of electron-transfer induced cis/trans isomerization i) in a
monocarbonyl diphosphinic Re(I) complex which, follows a rare electrocatalytic electron transfer
chain process with a null global flow of current; ii) in mono- and di -nitrile Re(I) complexes with
a chelating phosphines; iii) in mixed thiol-isonitrile molybdenum (II) complexes.
• Established the mechanisms of electron-transfer induced deprotonations of hydride complexes of
iron (II), mono- and di-nuclear with CNH or bridged dinitrile ligands; worked on the mechanim
of the electron induced conversion of CNH2/CNH/CN on a diphosphine complex of rhenium (I).
• Investigated the electrochemical behaviour of several other types of complexes, sometimes within
established collaborations with other groups: ruthenium (II) and osmium (II) with
dimethylsulphoxide and hydrazinium ligands; rhodium (I) with diketonates type ligands; platinum
(0, II and IV) with cinnamonitrile, ciclofosfazene and carbene ligands; tungsten with alcenilcarbyne ligands; etc. ..
b) Coordination chemistry and activation of small molecules
Introduced in the research group (1993) the synthesis of platinum complexes, an area that came to be
developed later. She has supervised the synthesis and reactivity, characterization and reactivity tin
complexes, of platinum and other transition metals with cyanamides, oximes, nitriles, cyanide or other
nitrogenous substrates, with possible pharmacological significance.
c) X-ray diffraction analyses
Since 1997 has been dedicated to the structural determination, by X-ray diffraction analyses, of various
metal complexes and organic compounds.
4. POSITIONS
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Member of the organizing and scientific commission of the 25th International Conference on
Organometallic Chemistry (ICOMC) (Lisbon, 2012).
Editor of the Journal of the Portuguese Electrochemical Society, Portugaliae Electrochimica Acta
(1996-2002).
Member of the Portuguese Electrochemical Society (since 1987).
Member of the Iberoamerican Electrochemical Society (since its foundation, in 1992).
Member of the Directive Board of the Portuguese Electrochemical Society (1996-2002).
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
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Member of the organizing and scientific commissions of the following meetings: NATO Advanced
Research Workshop on "Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic
Compounds" (Sintra Portugal, 1992); 9º, 10º and 11º Meetings of the Portuguese Electrochemical
Society; XV Meeting of the Iberoamerican Society of Electrochemistry, SIBAE (Évora, 2002); 12º
Meeting of the Portuguese Electrochemical Society /Symposium on Molecular Electrochemistry
(Science Academy of Lisbon) (2003).
5. TEACHING COMMITMENTS
AT UNIVERSIDADE LUSÓFONA DE HUMANIDADES E TECNOLOGIAS (ULHT, LISBON)
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“Analytical Chemistry I”, 1996-2006 and “Analytical Chemistry”, since 2006.
“Chemical Analysis”, 2005/06 and 2006/07.
“Analytical Chemistry II” (Spectroscopic Methods), 1995-2006.
“Chemistry III” (Organic Chemistry), since 1996.
“Chemistry I” (General Chemistry), 1998/99 and 2007-08.
“Microbial Technology”, 1995-96.
AT INSTITUTO SUPERIOR TÉCNICO (IST, LISBON)
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"Coordination Compounds in Pharmacology” [2 years research course within the Specific
Programme for the Development of the Portuguese Industry (PEDIP programme), I.S.T., 199193] .
Ultramicroelectrodes in "Electrochemical Methods in Synthesis”, 1991-92 (M. Sc. course on
Chemical Engineering/Applied Chemistry, I.S.T.).
6. MAIN RESEARCH AREAS AND METHODS
GENERAL AREAS
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Bioinorganic, Inorganic, Analytic, Coordination, Organometallic and Organic Chemistries.
Molecular Electrochemistry.
SPECIFIC AREAS
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Activation of small molecules with biological, industrial or environmental interest or related ones
(such as alkanes, alkynes, phosphaalkynes, isocyanides, dinitrogen, nitriles, cyanamides, nitric
oxide, oximes, olefins, azides, cyanates, etc.) by transition metal centers.
Crystal engineering of coordination compounds, self-assembly of polynuclear and supramolecular
structures, transition metal and organometallic chemistries.
Molecular Electrochemistry of coordination and organic compounds, namely towards
applications in electrosynthesis, electrocatalysis and in mechanistic studies, as well as in the
establishment of potential-structure relationships, and in the induction of chemical reactivity by
electron-transfer.
Mechanisms of fast chemical or electrochemical reactions.
Conventional molecular electrochemistry (e.g. cyclic voltammetry, controlled potential
electrolysis).
Unconventional molecular electrochemistry (use of ultramicroelectrodes in fast voltammetry, the
development and use of digital simulation methods in cyclic voltammetry and their application to
mechanistic studies of electrode processes involving fast reactions induced by electron-transfer,
in electrocatalysis, etc.).
stopped-flow spectrophotometry.
mass spectrometry (including fast atom bombardment, FAB-MS) and its coupling to gaschromatography (GC-MS) .
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
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The application of digital simulation to the analysis of NMR spectra as well as NMR
spectroscopy of various less-common nuclei.
TECHNIQUES
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High vacuum and inert atmosphere synthetical methods, and analysis of the reactional systems
and products obtained.
Multinuclear magnetic resonance.
Mass Spectrometry [fast atom bombardment (FAB) or electron impact (EI), and mass
spectrometry coupled to gas chromatography (GC-MS).
Stopped flow spectrophotometry (study of fast reaction kinetics).
Infrared and ultraviolet / visible spectroscopies
Chromatography (capillary columns).
Cyclic voltammetry and controlled potential electrolysis.
Digital simulation of cyclic voltammetry (application to establish mechanisms of electrode
processes).
Construction and use of ultramicroelectrodes (application of electrochemical techniques in
unconventional, in particular fast scan cyclic voltammetry).
Structural analysis by single crystal X-ray diffraction
7. PROJECTS
Under the responsability of A.J.L. Pombeiro:
 "Coordination Chemistry of Dinitrogen and Related Molecules" [project sponsored by INIC
(1985-1992) or JNICT (1993-95)] .
 "Electrochemistry of Transition Metal Complexes” [project sponsored by INIC (1985-1992) or
JNICT (1993-95)] .
 ”Activation of Small Molecules", FCT / JNICT (1996-99).
 "Molecular Electrochemistry of Coordination Compounds", FCT / JNICT (1996-99).
 “Coordination Chemistry and Molecular Electrochemistry”, Group V (Centro de Química
Estrutural), FCT (2000-07).
 “Coordination Chemistry and Molecular Electrochemistry, Synthesis and Catalysis”, Group V
(Centro de Química Estrutural), FCT (since 2008).
 "Investigation of the Mechanisms of Proton Transfer Reactions, in Coordination Compounds, by
Stopped Flow Spectrophotometry" [project sponsored by the ICCTI (JNICT)/The British Council
protocol]. Co-responsibility: Dr. R. Henderson (Nitrogen Fixation Laboratory, Norwich (199097).
 "Molecular Electrochemistry of Coordination Compounds - Application of Ultramicroelectrodes"
(Project PMCT/C/CEN/339/90, sponsored by JNICT) (1990-94).
 "Synthesis and Mechanistic Studies in Bioinorganic Chemistry" [sponsored by the CIENCIA
(Science) Program, Sub-program III - Global Support to the Scientific and Technological System,
Infrastructures for Research and Development, Measure M] (1990-97)
 "Chemistry and Electrochemistry of Low-Valent Palladium and Platinum Complexes with
Unsaturated C-N Ligands" (project sponsored jointly by INIC, JNICT and the CNR, Italy).
(1991-92).
 "Mechanisms of the Activation of Metal-Ligand Bonds by Electrochemistry with
Ultramicroelectrodes. Application to the Study of Model Reactions for the Activation of Small
Molecules" (project sponsored jointly by INIC, JNICT and CNRS, France). (1992-96).
 "Activation and Electrochemistry of Unsaturated Small Molecules of Biological or Industrial
Significance  Nitric Oxide and Cyanamide" (Project STRDA/CEN/450/92, sponsored by the
STRIDE Program, Measure A) (1992-95).
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
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"Activation of Unsaturated Small Molecules by Palladium or Platinum Metal Centres, a Chemical
and Electrochemical Investigation" (project sponsored jointly by JNICT and the CNR, Italy).
(1993-94).
“Development of Mimetic Systems of Fundamental Biological Processes with Environmental and
Economical Relevance" (Project PRAXIS/2/2.1/QUI/03/94, sponsored by the PRAXIS XXI
Programme for Scientific and Technological Research) (1994-99).
"Multiple Metal-Carbon Bond Species in Selective Processes" (Project ERBCHRXCT940501,
Human Capital and Mobility EC Network) (1994-97).
"Chemistry and Redox Properties of Palladium or Platinum Complexes with Multiple Bonded C,
N-Donor Ligands" (sponsored jointly by JNICT and the CNR, Italy). (1995-96).
"Chemical and Electrochemical Investigation of Some Transition Metal-Promoted Reactions of
Alkynes, Diazoalkanes, Cyanamide and Derived Species" [sponsored jointly by ICCTI (JNICT)
and the CNR, Italy]. (1997-98).
“The Chemistry of Platinum Group Metals with N-Donor Ligands: Structure-Reactivity and
Structure-Biological Activity Relationships”. (since 1998).
"Oxidation of Saturated Hydrocarbons" (Project PRAXIS/POCTI /2/2.1/QUI/193/94, sponsored
by the PRAXIS XXI and the POCTI Programmes) (1998-2002).
“Coordination and Reactivity of Organonitriles, Cyanamides and Derived Species” (sponsored
jointly by ICCTI and the CNR, Italy). (1999-2001).
“Metal-based Synthons with Pharmacological Significance” (Project POCTI/QUI/43415/2001,
sponsored by the POCTI programme, FCT) (2002-05).
“Early-Late Multinuclear Metal Systems on Design and Development of New Materials” (NATO
Collaborative Linkage Grant PST. CLG. 979289). (2003-06)
“Transition Metal Chemistry and Catalysis in Aqueous Media” [Project MRTN-CT-2003503864, Human Resources and Mobility (HRM) Marie Curie Research Training Network (RTN)]
(2000-07).
“Single-Pot Carboxylation of Alkanes under Mild Conditions”, (Project PTDC/QUIQUI/102150/2008) (since 2010).
“GC-MS”, [Programme PO 002 (Inovation and Scientific and Technological Research), MO 003
(Development of a Modern Network of R&D Institutions), Project 6811 (Consolidation of
Scientific Re-equipment of S&T Institutions), sponsored by FCT, 2010-present].
Under the responsability of A. Charmier:
 “Synthesis of New Heterocycles with Biological Activity: Reactions, by the Microwave
Activation, of Cycloaddition of several dipoles to Transition Metals Coordinated Organonitriles”
(POCI/QUI/59558/2004)
8. RESERARCH TRAINING SUPERVISION
3 Ph.D. (two awarded); 3 foreign Post-doc. Fellows.
Doctorates:
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Srinivasan Sowmianarayan Parimala, (Madras University, India) “Activation of Nitriles by
Electron-Rich Metal Centres“ (SFRH/BPD/20339/2004)
Zhen Ma (Chinese academy of sciences, Fuzhou, Fujian, China) “Synthesis, Electrochemical and
Luminescent Behaviours of Polyaza-Complexes” (SFRH/BPD/24691/2005)
Malgorzata Gajewska (Poland) “Syntheses and characterisation of organotin and related
complexes with potential pharmacological interest” (SFRH/BPD/32522/2006)
PhD Theses (Co-supervision)
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Maria de Fátima Costa Guedes da Silva
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Cristina Maria Pires Ferreira, “Platinum and Rhenium Compounds with Nitrogen Ligands and
their Reactivity” (IST, 2000) .
Natércia da Conceição Tomé Martins “Mechanistic Studies on the Electrocatalytic Reduction of
Organohalides and on the Oxidation of Alcohols, Thiols and Phenols" (IST, 2004)
Sónia Maria Pena Rodrigues Meireles da Cunha “Activação de Cianamidas e Diazoto por Centros
Fosfínicos de Molibdénio e Tungsténio” IST, 2003, provisional thesis (deyed in June 2004).
Master Theses (Co-supervision)
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Isabel Luísa Ferreira Machado, "Electrochemistry of Complexes with Unsaturated N-Ligands"
(IST, 1994)
Maria Estela Silva Dória, "Palladium and Platinum Complexes: Reactions with Diazo
Compounds and Electrochemical Behaviour of Cyanamide Compounds" (IST, 1995)
Other (Co-supervision)
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Elsa Mariana P.R. Parrot Branco, "Chemistry of Platinum and Palladium Compounds with
Nitrogen-Ligands, specifically Cyanamide", PEDIP programme "Coordination Compounds in
Pharmacology" (1991-93), (2 years)
Tong Yu-Ying, “Chemistry and Electrochemistry of Complexes of Gold or other Metals with
Sulphur- or Nitrogen-ligands”, PEDIP programme "Coordination Compounds in Pharmacology"
(1991-93)
Katarzyna Szajnowska (Wroclaw University, Poland), Erasmus programme, (1999) (2 months).
Filipa Delgado Siopa, 2004 (6,5 meses) (POCTI/QUI/43415/2001).
Tetyana Anasimova (St. Petersburg State University), PhD student (supervision: Prof. AJL
Pombeiro; Co-supervision: Dr. K. Luzyanin), supervisor in the course, “Advanced Experimental
Techniques and Methodologies” of the Phd Program in Chemical Engineering of IST
Curriculum Vitae
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9. PUBLICATIONS
2 chapters and 8 and other contributions in books (refereed).
119 research publications in refereed international journals
19 research publications in refereed national journal.
9 patents.
5 invited lessons in international meetings.
129 communications (oral or poster) in international meetings.
I – CONTRIBUTIONS IN BOOKS OR IN REVIEWS
I.1
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I.5
Tânia J. Castilho, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Roberta Bertani, Mirto
Mozzon, Rino A. Michelin, "Electrochemical Behaviour of Aminooxy-, Dioxy- and
Diaminocarbene Complexes of Palladium(II) and Platinum(II)", em "Molecular Electrochemistry
of Inorganic, Bioinorganic and Organometallic Compounds", A. J. L. Pombeiro and J.
McCleverty (Eds.), NATO ASI Series, Kluwer Academic Publishers, Dordrecht, Holanda, C385
(1992) 345-350. ISBN 0-7923-2077-8
João J.R. Fraústo da Silva, M. Fátima C. Guedes da Silva, J. Armando L. da Silva, Armando J.L.
Pombeiro, "Redox Properties of the Amavadine Models [V(HIDA)2]2- and [V(HIDPA) 2]2- and
their Electroinduced Reactivity towards Activated Thiols and Phenols", em "Molecular
Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds", A. J. L. Pombeiro
and J. McCleverty (Eds.), NATO ASI Series, Kluwer Academic Publishers, Dordrecht, Holanda,
C385 (1992) 411-415. ISBN 0-7923-2077-8
M. Fátima C. Guedes da Silva, João J. R. Fraústo da Silva, Armando J.L. Pombeiro, Christian
Amatore, Jean-Nöel Verpeaux, "Mechanism of the Electroactivation of the Metal-Hydride Bond
in [ReClH(NCR)(Ph2PCH2CH2PPh2)2][BF4]", em "Molecular Electrochemistry of Inorganic,
Bioinorganic and Organometallic Compounds", A. J. L. Pombeiro and J. McCleverty (Eds.),
NATO ASI Series, Kluwer Academic Publishers, Dordrecht, Holanda, C385 (1992) 483-487.
ISBN 0-7923-2077-8
M. Fátima C. Guedes da Silva, M. Fernanda N.N. Carvalho, M. Amélia N.D.A. Lemos, Armando
J.L. Pombeiro, “Binding and Reactivity of Cyanide, Isocyanide and Aminocarbyne, CNH x (x = 02), at a Single Transition Metal Centre”, em “Progress in Coordination and Organometallic
Chemistry”, G. Ondrejovic e A. Sirota (eds), “Monograph Series of the International Conferences
on Coordination Chemistry”, Vol. 3, Slovak Technical University Press, Bratislava, (1997) 143146. ISBN 978-80-227-3085-3 - ISSN 1335-308X
C.M.M. Matoso, J.J.R. Fraústo da Silva, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro,
“A Possible Role for Amavadine in some Amanita Fungi: A Unique Case in Biology”, in
"Vanadium Compunds- Chemistry, Biochemistry and Therapeutic Applications", Alan S Tracey e
Debbie C. Crans (eds.), ACS Symposium Series 711, American Chemical Society, (1998) Ch.18,
241-247. ISBN 0-8412-3589-9.
I.6
A.J.L. Pombeiro, M. Fátima C. Guedes da Silva “Electrochemical Behaviour of Phosphazenes
and their Complexes”, Cap. 14 in “Phosphazenes: A Worldwide Insight”, M.Gleria and R. De
Jaeger Eds., Nova Science Publishers, Hauppauge, NY, 2004, p. 343-364. ISBN-10:
159033423X- ISBN-13: 978-1590334232
I.7
A.J.L. Pombeiro, M. Fátima C. Guedes da Silva “Bond and Structure Activation by anodic
Electron-Transfer: Metal-Hydrogen Bond Cleavage and cis/trans Isomerization in Coordination
Compounds”, Part 2 - Molecular Activation, Cap. 5 in “Trends in Inorganic Molecular
Electrochemistry”, A.J.L. Pombeiro, C. Amatore (Eds.), Marcel Dekker / Fontis Media, New
York / Lausanne, 2004, Cap. 5, pp. 153-186.
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
1.8
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VY Kukushkin, YA Izotova, D Tudela, MFC Guedes da Silva, AJL Pombeiro,
“PLATINUM(II) COMPLEXES OF PROPANONE OXIME”, JR Shapley (Ed.) INORGANIC
SYNTHESES, VOL 34, Pages: 81-85 Published: 2004
Accession Number: WOS:000284266500018
A.J. L. Pombeiro, M. Fátima C. Guedes da Silva, Robert H. Crabtree “Technetium & Rhenium –
Inorganic and Coordination Chemistry” in “Encyclopedia of Inorganic Chemistry”, R. Bruce
King (Ed), 2nd Ed., Wiley, Chichester, 2005, Vol. IX, 5499-5516.
II – RESEARCH PAPERS
1984
II.1
M. Isabel S. Pereira, M. Fátima C. Guedes da Silva, Fernanda M. A. da Costa, "The
Electrodeposition of SnS Layers on Sn(Hg)", J. Electroanal. Chem., 172 (1984) 367-372.
http://dx.doi.org/10.1016/0022-0728(84)80198-9
1989
II.2
II.3
II.4
Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva, David L. Hughes, Raymond L. Richards,
"Preparation and Properties of the Nitrile Complexes trans-[ReCl(NCR)(dppe)2] (R=alkyl or
aryl)", Polyhedron, 8 (1989) 1872-1873.
http://dx.doi.org/10.1016/S0277-5387(00)80679-8
Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva, David L. Hughes, Raymond L. Richards,
"Syntheses
of
the
Cyanamide-Derived
bis(cyanoimido)
Complexes
trans[M(NCN)2(Ph2PCH2CH2PPh2)2] (M = Mo or W) and Crystal Structure of the Molybdenum
Compound", J. Organomet. Chem., 371 (1989) C45-C47.
http://dx.doi.org/10.1016/0022-328X(89)85239-8
Armando J.L. Pombeiro, Sílvia S.P.R. Almeida, M. Fátima C. Guedes da Silva, John C. Jeffery,
Raymond L. Richards, "Reaction of 1-Alkynes with trans-[ReCl(N2)(Ph2PCH2CH2PPh2)2]:
Preparation of the Vinylidene Compounds trans-[ReCl(=C=CHR)(Ph2PCH2CH2PPh2)2]
(R=Alkyl or Aryl) and X-ray Structure of trans-[ReCl(=C=CHPh)(Ph2PCH2CH2PPh2)2]", J.
Chem. Soc.,Dalton Trans., (1989) 2381-2387.
http://dx.doi.org/10.1039/DT9890002381
1991
II.5
II.6
M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Adrian Hills, David L. Hughes,
Raymond L. Richards, "Synthesis and Crystal Structure of the Complex Double Salt
[Re(NCC6H4Me-4)2(Ph2PCH2CH2PPh2)2][ReF2(Ph2PCH2CH2PPh2)2][BF4]2",
J.
Organomet.Chem., 403 (1991) C1-C3.
http://dx.doi.org/10.1016/0022-328X(91)83108-G
M. Emília N.P.R.A. Silva, Armando J.L. Pombeiro, João J.R. Fraústo da Silva, Rudolf Herrman,
Norbert Deus, Tânia J. Castilho, M. Fátima C. Guedes da Silva, "Redox Potencial and Substituent
Effects at Ferrocene Derivatives. Estimates of Hammett p and Taft polar  Substituent
Constants", J. Organometal. Chem., 421 (1991) 75-90.
http://dx.doi.org/10.1016/0022-328X(91)86433-Q
1992
II.7
II.8
M. Fátima C. Guedes da Silva, M. Teresa Duarte, Adelino M. Galvão, João J. R. Fraústo da Silva,
Armando J.L. Pombeiro, "The cis-{Re(Ph2PCH2CH2PPh2)2}+ Metal Centre. Synthesis and
Molecular
Structure
of
the
Dinitrile
Complex
cis-[Re(NCC6H4Me4)2(Ph2PCH2CH2PPh2)2][BF4]", J. Organometal. Chem., 433 (1992) C14-C17.
http://dx.doi.org/10.1016/0022-328X(92)80161-P
Christian Amatore, João J. R. Fraústo da Silva, M. Fátima C. Guedes da Silva, Armando J.L.
Pombeiro, Jean-Nöel Verpeaux, "Electrochemically-Induced Dehydrogenation of the Hydride
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
11 / 47
Complexes [ReClH(NCR)(Ph2PCH2CH2PPh2)2][BF4]. A Mechanistic Study.", J. Chem. Soc.,
Chem. Commun., (1992) 1289-1291.
http://dx.doi.org/10.1039/C39920001289
1993
II.9
II.10
II.11
II.12
Rino A. Michelin, Roberta Bertani, Mirto Mozzon, Gabiella Bombieri, Franco Benetollo, M.
Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Hydride to Carbene Migration at
Platinum(II). Synthesis and X-ray Structure of cis-{(PPh3)2Pt[C(H)SCH2CH2S]}BF4",
Organometallics, 12 (1993) 2372-2376.
http://dx.doi.org/10.1021/om00030a056
M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, Roberta
Bertani, Rino A. Michelin, Mirto Mozzon, Franco Benetollo, Gabriella Bombieri, "Reactivity of
[Pt(CH2=CH2)(PPh3)2] Towards Ethyldiazoacetate. Synthesis and Molecular Structure of the
Diethyl Fumarate Complex [Pt{trans-CH(CO2Et)=CH(CO2Et)} (PPh3)2] and Preparation of the
nalogous Diethylmaleate Compound", Inorg. Chim. Acta, 214 (1993) 85-95.
http://dx.doi.org/10.1016/S0020-1693(00)87529-5
Talib Al Salih, M. Teresa Duarte, João J.R. Fraústo da Silva, Adelino M. Galvão, M. Fátima C.
Guedes da Silva, Peter B. Hitchcock, David, L. Hughes, Christopher J. Pickett, Armando J.L.
Pombeiro, Raymond L. Richards, "Structural and Electronic Comparison of 15- to 17-Electron
Dichloro Complexes of Molybdenum and Rhenium: Electrochemical Behaviour and X-ray
Crystal Structures of trans-[ReCl2(dppe)2]A (A = Cl or BF4; dppe = Ph2PCH2CH2PPh2), trans[ReCl2(dppe)2] and trans-[MoCl2(dppe)2] [NBun4]2 [BF4]3", J. Chem. Soc., Dalton Trans., (1993),
3015-3023.
http://dx.doi.org/10.1039/DT9930003015
João J.R. Fraústo da Silva, M. Fátima C. Guedes da Silva, Richard A. Henderson, Armando J.L.
Pombeiro, Raymond L. Richards, "Protonation of the Nitrile Ligand versus Protonation of
Rhenium at cis- or trans-[ReCl(NCR)(Ph2PCH2CH2PPh2)2] (R = Cl, F, Me or MeO). A
Mechanistic Study", J. Organomet. Chem., 461 (1993) 141-145.
http://dx.doi.org/10.1016/0022-328X(93)83285-4
1994
II.13
II.14
II.15
M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, Christian
Amatore, Jean-Nöel Verpeaux, "Rates and Mechanism of Oxidative Two-Electron Transfer
Induced cis- to trans-Isomerization for the Nitrile Complex [ReCl(NC6H4Me4)(Ph2PCH2CH2PPh2)2]”, Organometallics, 13 (1994) 3943-3951.
http://dx.doi.org/10.1021/om00022a033
M. Amélia N.D.A. Lemos, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "ElectronTransfer Activation of the Aminocarbyne and the Hydrogen-Isocyanide Complexes
[ReCl(CNHn)(Ph2PCH2CH2PPh2)2] [BF4]n-1 (n = 2 or 1). Interconversion of Coordinated CNH2
and CNH", Inorg. Chim. Acta, 226 (1994) 9-16.
http://dx.doi.org/10.1016/0020-1693(94)04064-8
M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, "Synthesis
and Redox Properties of cis-[ReCl(NCR)(Ph2PCH2CH2PPh2)2] (R = Alkyl or Aryl), ChloroNitrile Complexes with a cis-Phosphinic Rhenium(I) Centre", J. Chem. Soc., Dalton Trans.,
(1994) 3299-3304.
http://dx.doi.org/10.1039/DT9940003299
1995
II.16
M. Fátima C. Guedes da Silva, Elsa M.P.R.P. Branco, Yu Wang, João J.R. Fraústo da Silva,
Armando J.L. Pombeiro, Roberta Bertani, Rino A. Michelin, Mirto Mozzon, Franco Benetollo,
Gabriella Bombieri, "Syntheses and Properties of Cyanamide and Cyanoguanidine Complexes of
Platinum(II). X-Ray Structure of trans-[Pt(CF3)(NCNEt2)(PPh3)2][BF4]", J. Organomet. Chem.,
490 (1995) 89-99.
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
II.17
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http://dx.doi.org/10.1016/0022-328X(95)05203-2
Umberto Belluco, Roberta Bertani, Rino A. Michelin, Mirto Mozzon, M. Fátima C. Guedes da
Silva, João J.R. Fraústo da Silva, A.J.L. Pombeiro, Wang Yu, "Reactions and Electrochemical
Behaviour of Dithiocarbene Complexes of Platinum(II)", Inorg. Chim. Acta, 235 (1995) 397-405.
http://dx.doi.org/10.1016/0020-1693(95)90082-H
Roberta Bertani, Rino A. Michelin, Mirto Mozzon, Piero Traldi, Roberta Seraglia, M. Fátima C.
Guedes da Silva, Armando J.L. Pombeiro, "Highly Reactive Platinum(0) Carbene Intermediates
in the Reactions of Diazo Compounds. A Fast Atom Bombardment Mass Spectrometric Study",
Organometallics, 14 (1995) 551-554.
http://dx.doi.org/10.1021/om00001a075
1996
II.19
II.20
II.21
II.22
II.23
II.24
Luísa M.D.R.S. Martins, M. Fátima C. Guedes da Silva, Indalécio Marques, João J.R. Fraústo da
Silva, M. Cândida N. Vaz, Armando J.L. Pombeiro, "FAB-MS Spectra of Nitrile or Cyanamide
Complexes with the {M(Ph2PCH2CH2PPh2)2}n+ (M = Fe or Re) Metal Sites. Application to
Reactions Induced in FAB Conditions", Rapid Commun. Mass Spect., 10 (1996) 447-454.
http://dx.doi.org/CCC 09514198/96/040447-08
P. Gili, M.G. Martin Reyes, P. Martin Zarza, Isabel L.F. Machado, M. Fátima C. Guedes da Silva,
M. Amélia N.D.A. Lemos, A.J.L. Pombeiro, "Synthesis, Spectroscopic, Magnetic and
Electrochemical Properties of Cu(II) and Fe(III) Complexes with the New Ligand N,N'-[1,1'Dithiobis(phenyl)] bis(5'-Methoxysalicylaldimine)", Inorg. Chim. Acta., 244 (1996) 25-36.
http://dx.doi.org/10.1016/0020-1693(95)04756-5
M. Fátima C. Guedes da Silva, João J. Fraústo da Silva, Armando J.L. Pombeiro, Maria A.
Pellinghelli, Antonio Tiripicchio, " Deprotonation Reactions of the Aminocarbyne Complex
trans-[ReCl(CNH2)(dppe)2][BF4] (dppe = Ph2PCH2CH2PPh2). Synthesis and Properties of the
Cyano-Complexes trans-[Re(CN)(L)(dppe)2] (L = NCR, N2, CO or C=CHPh) and Crystal
Structure of trans-[Re(CN)(NCMe)(dppe)2].PriOH", J. Chem. Soc., Dalton Trans., (1996) 27632772.
http://dx.doi.org/10.1039/DT9960002763
M. Fátima C. Guedes da Silva, J. Armando L. da Silva, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, Christian Amatore, Jean-Nöel Verpeaux, "Evidence for a Michaelis-Menten Type
Mechanism in the Electrocatalytic Oxidation of Mercaptopropionic Acid by an Amavadine
Model", J. Am. Chem. Soc., 118 (1996) 7568-7573
http://dx.doi.org/10.1021/ja9607042
M. Gleria, R. Bertani, G. Facchin, F. Noé, Rino A. Michelin, Mirto Mozzon, Armando J.L.
Pombeiro, M. Fátima C. Guedes da Silva, Isabel L.F. Machado, “Organometallic and
Coordination Chemistry on Phosphazenes. III. Synthesis, Characterization, and Electrochemical
Behavior of Transition Metal- Cinnamonitrile Cyclophosphazene Derivatives”, Journal of
Inorganic and Organometallic Polymers, 6 (1996) 145-170.
http://dx.doi.org/10.1007/BF01057745
M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, "Dinitrile
Complexes with a Rare cis-Diphosphine Rhenium(I) Centre: Syntheses, Properties and cis- to
trans- Isomerization", J. Organomet. Chem., 526 (1996) 237-250.
http://dx.doi.org/10.1016/S0022-328X(96)06566-7
1997
II.25
P. Gili, M.G. Martin Reyes, P. Martin Zarza, M. Fátima C. Guedes da Silva, Y.-Y. Tong,
Armando J.L. Pombeiro, "Complexes of Mn(II) and Mn(III) with the Schiff base N-[2-(3Ethylindole)]pyridoxaldimine. Electrochemical Study of these complexes and related Ni(II) and
Cu(II) and Fe(III) Complexes", Inorg. Chim. Acta., 255 (1997) 279-288.
http://dx.doi.org/10.1016/S0020-1693(96)05374-1
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
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Peter B. Hitchcock, David L. Hughes, Katayoun Marjani, Armando J.L. Pombeiro, Raymond L.
Richards, M. Fátima C. Guedes da Silva, “Thiolate-isocyanide Complexes of Molybdenum(II)
and Tungsten (II): Crystal Structures of cis-[Mo(SC6H2Pri3 2,4,6)2(CNMe)2], cis-[Mo(SC6H2Pri32,4,6)2(CNBut)2] and cis-[W(SC6H2Pri3-2,4,6)2 (CNMe)4], and Anodically-induced Isomerisation
Studies”, J. Chem. Soc., Dalton Trans., (1997) 3725-3731.
http://dx.doi.org/10.1039/a703860g
II.27
M. Fátima C. Guedes da Silva, Cristina M.P. Ferreira, Elsa M.P.R.P. Branco, João J.R. Fraústo da
Silva, Armando J.L. Pombeiro, Rino A. Michelin, Umberto Belluco, Roberta Bertani, Mirto
Mozzon, Gabriella Bombieri, Franco Benetollo, Vadim Yu. Kukushkin, “Bifunctional Activation
of Cyanoguanidine. Synthesis and Molecular Structure of the Azametallacycle cis[(PPh3)2Pt{NHC(OMe)=NC(NH2)=NH}][BPh4]”, Inorg. Chim. Acta, 265 (1997) 267-270.
http://dx.doi.org/10.1016/S0020-1693(97)05636-3
1998
II.28
Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Vadim Yu. Kukushkin, João J.R. Fraústo
da Silva, Armando J.L. Pombeiro, “The First Direct Observation of the N-O- Bond Cleavage in
the Oxidative Addition of an Oxime to a Metal Centre. Synthesis and Crystal Structure of the
Methyleneamide Complex trans-Re(OH)(N=CMe2)(Ph2PCH2CH2PPh2)2HSO4” J. Chem. Soc.,
Dalton Trans., (1998) 325-326.
II.29
M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, Christian
Amatore, Jean-Noel Verpeaux, “Electron-Transfer-Induced Geometrical Isomerization of the
Dinitrile Complexes cis-[Re(NCR)2(dppe)2][BF4] (R = Aryl, Alkyl): Rates, Mechanisms and
Ligand Effects”, Inorg. Chem., 37 (1998) 2344-3350.
http://dx.doi.org/10.1021/ic971257+
M. Fátima C. Guedes da Silva, Youlia A. Izotova, Armando J.L. Pombeiro, Vadim Yu.
Kukushkin, “Manifestation of Redox Duality of 2-propanone oxime: Pt(II)-assisted reduction
versus Pt(IV)-mediated oxidation of Me2C=NOH species” Inorg. Chim. Acta, 277 (1998) 83-88.
http://dx.doi.org/10.1016/S0020-1693(97)06126-4
M. Fátima C. Guedes da Silva, Cristina M.P. Ferreira, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, “Electron-Transfer Chain Catalysis for the cis-to-trans Isomeric Conversion of cis[ReCl(CO)(dppe)2]” J. Chem. Soc., Dalton Trans., (1998) 4139-4145.
http://dx.doi.org/10.1039/a805343j
http://dx.doi.org/10.1039/a707213i
II.30
II.31
1999
II.32
Sílvia S.P.R. Almeida, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, “Reactions of a Cyanosilane with an Iron(II) Centre. Synthesis and Crystal Structure of
the Isocyanotriphenylborate complex trans-[FeH(CNBPh3)(dppe)2] and Anodic Deprotonation of
the Hydrogen Isocyanide (CNH) analogue”, J. Chem. Soc., Dalton Trans., (1999) 467-472.
http://dx.doi.org/10.1039/a807707j
2000
II.33
II.34
M. Fátima C. Guedes da Silva, M. Amélia N.D.A. Lemos, João J.R. Fraústo da Silva, Armando
J.L. Pombeiro, Maria A. Pellinghelli, Antonio Tiripicchio, “Aminocarbyne and Isocyanide
Complexes of rhenium. Crystal Structures of trans-[ReCl(CNR) (Ph2PCH2CH2PPh2)2] (R = H or
SiMe3)” J. Chem. Soc., Dalton Trans., (2000) 373-380.
http://dx.doi.org/10.1039/a908174g
Lei Zhang, M. Pilar Gamasa, José Gimeno, Rodrigo J. Carbajo, Fernando López-Ortiz, M. Fátima
C. Guedes da Silva, Armando J.L. Pombeiro, “Mono and Dinuclear Alkenyl-Carbyne Complexes
Bridged by Cyanide and Diisocyanide Ligands: Synthesis, Electrochemical- and 183W-NMR
studies” Eur. J. Inorg. Chem., (2000) 341-350.
http://dx.doi.org/10.1002/(SICI)1099-0682(200002)2000
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
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M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Silvano Geremia, Ennio Zangrando,
Mario Calligaris, Andrey V. Zinchenko, Vadim Yu. Kukushkin, "Unusual Pathways for the
Reaction between [MCl2(Me2SO)4] (M = Os, Ru) and Hydrazine dihydrochloride: deoxygenation
of sulfoxides vs. coordination of hydrazinium" J. Chem. Soc. Dalton Trans., (2000) 1363-1371.
http://dx.doi.org/10.1039/a908170d
Dmitrii A. Garnovskii, M. Fátima C. Guedes da Silva, T.B. Pakhomova, G. Wagner, M. Teresa
Duarte, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, Vadim Yu. Kukushkin,
“Iminoacylation. 6. Coupling of Chloro- and Amidoximes Ar(R)C=NOH(R = Cl, NH2) with
Acetonitrile Ligands Coordinated to Platinum(IV)” Inorg. Chim. Acta., 300-302 (2000) 499-504.
http://dx.doi.org/10.1016/S0020-1693(99)00556-3
Amélia Rauter, Maria Ferreira, C. Borges, Teresa Duarte, Fátima Piedade, M. Fátima C. Guedes
da Silva, Helena Santos, "Construction of a Branched Chain at C-3 of a Hexopyranoside.
Synthesis of Miharamycin Sugar Moiety Analogs" Carbohydrate Research, 325 (2000) 1-15.
http://dx.doi.org/10.1016/S0008-6215(99)00307-9
Lei Zhang, M. Pilar Gamasa, José Gimeno, M. Fátima C. Guedes da Silva, Armando J.L.
Pombeiro, C. Graiff, M.Lanfranchi, Antonio Tiripicchio, “Synthesis, Characterization and
Electrochemical Studies of Neutral Alkenyl-Carbyne Tunsten Complexes Bearing Chelating
Bidentate and Tridentate Phosphines”, Eur. J. Inorg. Chem., (2000) 1707-1715.
http://dx.doi.org/10.1002/1099-0682(200008)2000
2001
II.39
II.40
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II.43
II.44
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M. Fátima C. Guedes da Silva, Anna M. Trzerciak, Józef J. Ziólkowski, Armando J.L. Pombeiro,
“Redox Potential, Ligand and Structural Effects in Rhodium(I) Complexes”, J. Organometal.
Chem., 620 (2001) 174-181.
http://dx.doi.org/10.1016/S0022-328X(00)00816-0
Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva, “Coordination Chemistry of CNH2, the
Simplest Aminocarbyne”, J. Organomet. Chem, 617-618 (2001) 65-69.
http://dx.doi.org/10.1016/S0022-328X(00)00641-0
M. Fátima C.Guedes da Silva, Luísa M.D.R.S. Martins, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, “Redox potential-(electronic) structure relationships in 18- and 17-electron mononitrile
(or monocarbonyl) diphosphine complexes of Re and Fe”, Collect. Czech. Chem. Commun., 66
(2001) 139-154.
http://dx.doi.org/10.1135/cccc20010139
P. Sobota, K. Przybylak, J. Utko, L.B. Jerzykiewicz, A.J.L. Pombeiro, M. Fátima C. Guedes da
Silva, K. Szczegot “Synthesis, Structure and Reactivity of Chiral Titanium Compounds:
Procatalysts for Olefin Polymerization”, Chem. Eur.J., 7 (2001) 951-958.
http://dx.doi.org/10.1002/1521-3765(20010302)7
C.M.P. Ferreira, M. Fátima C. Guedes da Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, V.Yu.
Kukushkin, R.A. Michelin “Azametallacycles from Ag(I)- or Cu(II)-Promoted Coupling
Reactions of Dialkylcyanamides with Oximes at Pt(II)”, Inorg. Chem., 40 (2001) 1134-1142.
http://dx.doi.org/10.1021/ic000553a
Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva, M. Amélia N.D.A. Lemos “ElectronTransfer Induced Isomerizations of Coordination Compounds”, Coord. Chem. Rev., 219-221
(2001) 53-80.
http://dx.doi.org/10.1016/S0010-8545(01)00299-5
Lei Zhang, M. Fátima C. Guedes da Silva, Maxim L. Kuznetsov, M. Pilar Gamasa, José Gimeno,
João J.R. Fraústo da Silva, Armando J.L. Pombeiro “Synthesis and Electrochemical and
Theoretical
Studies
of
Fischer-type
Alkenyl-Carbyne
Tungsten
Complexes
[(dppe)(CO)2(RNC)W(CCH=CCH2CH2(CH2)nCH2}][BF4] (R = alkyl, aryl)”, Organomettalics,
20 (2001) 2782-2793.
http://dx.doi.org/10.1021/om001095g
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
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Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva, Rino A. Michelin “Aminocarbyne
Complexes Derived from Isocyanides Activated Toward Electrophilic Addition”, Coord. Chem.
Rev., 218 (2001) 43-74.
http://dx.doi.org/10.1016/S0010-8545(01)00357-5
Rino A. Michelin, Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva “Aminocarbene
Complexes Derived from Nucleophilic Addition to Isocyanides”, Coord. Chem. Rev., 218 (2001)
75-112.
http://dx.doi.org/10.1016/S0010-8545(01)00358-7
M.N. Kopylovich, V.Yu. Kukushkin, M. Fátima C. Guedes da Silva, M. Haukka, J.J.R. Fraústo
da Silva, A.J.L. Pombeiro “Conversion of Alkanenitriles to Amidines and Carboxylic Acids
Mediated by a Cobalt(II)-Ketoxime System”, J. Chem. Soc., Perkin Trans. I (2001) 1569-1573.
http://dx.doi.org/10.1039/b101337h
Nadejha A. Bokach, Stanislav I Selivanov, Vadim Yu. Kukushkin, Matti Haukka, M. Fátima C.
Guedes da Silva, Armando J.L. Pombeiro, “The First Observation and Structural Characterization
of (Formamide)Platinum(IV) Complexes”, Eur. J. Inorg. Chem., (2001) 2805-2809.
http://dx.doi.org/10.1002/1099-0682(200111)2001
2002
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U. Belluco, F. Benetollo, R. Bertani, G. Bombieri, R.A. Michelin, M. Mozzon, A.J.L. Pombeiro,
M. Fátima C. Guedes da Silva, “Stereochemical Investigation of the Addition of Primary and
Secondary Aliphatic Amines to the Nitrile Complexes cis- and trans-[PtCl2(NCMe)2]. X-ray
Structures of the Amidine Complexes trans-[Pt(NH2Pri)2{Z-N(H)=C(NHPri)Me}]Cl2.4H2O and
trans-[PtCl2(NCMe){E-N(H)=C(NMeBut)Me}], Inorg. Chim. Acta, 330 (2002) 229-239.
http://dx.doi.org/10.1016/S0020-1693(01)00803-9
Umberto Belluco, Franco Benetollo, Roberta Bertani, Gabriella Bombieri, Rino A. Michelin,
Mirto Mozzon, Oliviero Tonon, Armando J. L. Pombeiro, M. Fátima C. Guedes da Silva
“Addition reactions of primary and secondary aliphatic amines to the benzonitrile ligands in cisand trans-[PtCl2(NCPh)2] complexes. X-ray structure of the amidine complex trans-[PtCl2{ZN(H)=C(NHBut)Ph}2]”
Inorg.
Chim.
Acta,
334, (2002) 437-447.
http://dx.doi.org/10.1016/S0020-1693(02)00866-6
S.M. P. R. M. Cunha, M. Fátima C. Guedes da Silva, A. J. L. Pombeiro, “Activation of
Cyanamide by a Molybdenum(0) Diphosphinic Centre. Formation of Cyanoimide and its
Reactivity with Electrophiles”, J. Chem. Soc., Dalton Trans., (2002) 1791-1799.
http://dx.doi.org/10.1039/b108165a
M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, “Activation
of Organonitriles Toward -Electrophilic Attack. Synthesis and Characterisation of
Methyleneamide (Azavinylidene) Complexes of Rhenium”, Inorg. Chem., 41 (2002) 219-228.
http://dx.doi.org/10.1021/ic010841m
C.M.P. Ferreira, M. Fátima C. Guedes da Silva, Teresa Duarte, J.J.R. Fraústo da Silva, A.J.L.
Pombeiro, “Cationic Phenyl and Chloro-Platinum(II) Complexes with Cyanamides and
Cyanoguanidine. X-ray Structure of trans-[Pt(Ph)(NCNMe2)(PPh3)2][BPh4]”, Inorg. Chim. Acta,
334 (2002) 395-402.
http://dx.doi.org/10.1016/S0020-1693(02)00746-6
A.I.F. Venâncio, M.L. Kuznetsov, M. Fátima C. Guedes da Silva, L.M.D.R.S. Martins, J.J.R.
Fraústo da Silva, A.J.L. Pombeiro, “Metal-Hydride Bond Activation and Metal-Metal Interaction
in Dinuclear Iron Complexes with Linking Dinitriles: a Synthetic, Electrochemical and
Theoretical Study”, Inorg. Chem., 41 (2002) 6456-6467.
http://dx.doi.org/10.1021/ic025835k
2003
II.56
S.M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, “Mixed DinitrogenOrganocyanamide Complexes of Molybdenum(0) and Their Protic Conversion into Hidrazine and
Amidoazavinylidene Derivatives”, Inorg. Chem., 42 (2003) 2157-2164.
http://dx.doi.org/10.1021/ic026176e
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D.A. Garnovskii, M. Fátima C. Guedes da Silva, M.N. Kopylovich, A.D. Garnovskii, J.J.R.
Fraústo da Silva, A.J.L. Pombeiro, “Electrochemical Synthesis of Adducts of 2-Aminopyridine
or Methanol in Metal Chelates of a N,N,N-Tridentate Schiff Base Ligand. X-ray Crystal
Structures of the Ni(II) and Zn(II) Derivatives”, Polyhedron, 22(10) (2003) 1335-1340.
http://dx.doi.org/10.1016/S0277-5387(03)00104-9
C.M.P. Ferreira, M. Fátima C. Guedes da Silva, R.A. Michelin, V.Yu. Kukushkin, J.J.R. Fraústo
da Silva, A.J.L. Pombeiro, “2-Amino-2-oxazoline and Trialkylisourea Pt(II) Complexes Derived
from Organocyanamides”, Dalton Trans., (2003) 3751-3756.
http://dx.doi.org/10.1039/b306690h
S.S.P.R. Almeida, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, “Electrochemical Behaviour
of trans-[FeH(CN)(dppe)2] Adducts”, Collect. Czech. Chem. Commun., 68 (2003) 1663-1676.
http://dx.doi.org/10.1135/cccc20031663
S.S.P.R. Almeida, M. Fátima C. Guedes da Silva, L.B. Jerzykiewicz, P. Sobota, A.J.L. Pombeiro,
“Cyanide as a versatile Lewis Base Ligand at a Dinitrogen-binding Iron(II) centre: Mono- and
Heteronuclear
Adducts”,
Inorg.
Chim.
Acta,
356
(2003)
259-266.
http://dx.doi.org/10.1016/S0020-1693(03)00249-4
2004
II.61
II.62
II.63
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Q. Li, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, “Diorganotin(IV) Derivatives of
Substituted Benzohydroxamic Acids with High Antitumor Acivity”, Chem. Eur. J., 10 (2004)
1456-1462.
http://dx.doi.org/10.1002/chem.200305266
A.M. Trzeciak, B. Borak, Z. Ciunik, J.J. Ziólkowski, M. Fátima C. Guedes da Silva, A.J.L.
Pombeiro, “Structure, Electrochemistry and Hydroformylation Catalytic Activity of the
bis(pyrazolylborato)rhodium(I) Complexes [RhBp(CO)P] [P = P(NC4H4)3, PPh3, PCy3,
P(C6H4OMe-4)3”,
Eur.
J.
Inorg.
Chem.,
(2004)
1411-1419.
http://dx.doi.org/10.1002/ejic.200300517
E. Reisner, V.B. Arion, M. Fátima C. Guedes da Silva, R. Lichtenecker, A. Eichinger, B.K.
Keppler, V. Yu. Kukushkin, A.J.L. Pombeiro, “Tuning of Redox Potentials for the Design of
Ruthenium Anticancer Drugs — an Electrochemical Study of [trans-RuCl4L(DMSO)]- and
[trans-RuCl4L2]- Complexes, where L = Imidazole, 1,2,4-Triazole, Indazole”, Inorg. Chem., 43
(2004) 7083-7093.
http://dx.doi.org/10.1021/ic049479c
Q. Li, M. Fátima C. Guedes da Silva, Z. Jinghua, A.J.L. Pombeiro, “Diorganotin(IV) Derivatives
of Arylhydroxamic Acids. Synthesis, Properties and Antitumor Activity”, J. Organometal.
Chem., 689 (2004) 4584-4591.
http://dx.doi.org/10.1016/j.jorganchem.2004.08.025
2005
II.65
II.66
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E.C.B. Alegria, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, “Syntheses
and Properties of Re(III) Complexes Derived from Hydrotris(1- pyrazolyl)methanes: Molecular
Structure of [ReCl2(HCpz3)(PPh3)][BF4]”, J. Organometal. Chem., 690(8), (2005) 1947-1958.
http://dx.doi.org/10.1016/j.jorganchem.2004.11.005
A.M. Kirillov, M.N. Kopylovich, M.V. Kirillova, M. Haukka, M. Fátima C. Guedes da Silva,
A.J.L. Pombeiro, “Multinuclear Copper Triethanolamine Complexes as Selective Catalysts for the
Peroxidative Oxidation of Alkanes under Mild Conditions”, Angew. Chem., Int. Ed. 44 (2005)
4345–4349 and Angew. Chem., 2005, 117, 1119-1123.
http://dx.doi.org/10.1002/anie.200500585
A.M. Kirillov, M. Haukka, M. Fátima C. Guedes da Silva, Armando J. L. Pombeiro “Preparation
and Crystal Structures of Benzoylhydrazido- and -diazenidorhenium Complexes with N,OLigands and Their Catalytic Activity Towards Peroxidative Oxidation of Cycloalkane” Eur. J.
Inorg. Chem. (2005) 2071–2080.
http://dx.doi.org/10.1002/ejic.200400991
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A.I.F. Venâncio, M. Fátima C. Guedes da Silva, L.M.D.R.S. Martins, João J.R. Fraústo da Silva,
Armando J.L. Pombeiro “Allenylidene Iron(II) Complexes and Their Deprotonation, Nucleophilic
Addition Reactions, and Cathodic Protonation toward Alkynyl Derivatives: A Chemical and
Electrochemical Study“ Organometallics, 24 (2005) 4654-4665.
http://dx.doi.org/10.1021/om050408a
2006
II.69
II.70
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A.M. Kirillov, M.N. Kopylovich, M.V. Kirillova, E.Yu. Karabach, M. Haukka, M. Fátima
C.Guedes da Silva, Armando J. L. Pombeiro “Mild Peroxidative Oxidation of Cyclohexane
Catalyzed by Mono-, Di-, Tri-, Tetra- and Polynuclear Copper Triethanolamine Complexes”
Advanced Synthesis & Catalysis, Volume 348, 1-2 (2006) 159 – 174.
http://dx.doi.org/10.1002/adsc.200505216
N.A. Bokach, M.Haukka, P.Hirva, M. Fátima C. Guedes da Silva, V.Yu. Kukushkin,
ArmandoJ.L. Pombeiro “Photoinduced synthesis and electrochemical properties of new
ruthenium(mono)bipyridine dialkylcyanamide and propiononitrile complexes” J. Organomet.
Chem. 691 (2006) 2368–2377.
http://dx.doi.org/10.1016/j.jorganchem.2005.12.064
Y.Yu. Karabach, A.M. Kirillov, M. Fátima C. Guedes da Silva, M.N. Kopylovich, A.J.L.
Pombeiro “An Aqua-soluble Copper(II)-sodium 2D Coordination on Polymer with Intercalated
Infinite Chains of Decameric Water Clusters”, Crystal Growth & Design, 6(10), (2006) 22002203.
http://dx.doi.org/10.1021/cg060310e
A.M. Kirillov, M. Haukka, M. Fátima C. Guedes da Silva, J.J.R. Fraústo da Silva,
A.J.L.Pombeiro “A Picolinate-N2 Complex of Rhenium, the first Dinitrogen Complex Bearing a
Carboxylate or a N,O-Ligand”, J. Organomet. Chem. 691 (2006) 4153–4158.
http://dx.doi.org/10.1016/j.jorganchem.2006.06.015
2007
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A.M. Kirillov, M. Haukka, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “Synthesis,
Characterization and Redox Behaviour of Mono- and Dicarbonyl Phosphane Rhenium(I)
Complexes Bearing N-, N,N- and N,O-Type Ligands”, Eur. J. Inorg. Chem. (2007) 1556-1565.
http://dx.doi.org/10.1002/ejic.200601026
M.V. Kirillova, M. Fátima C. Guedes da Silva, A.M. Kirillov, J.J.R. Fraústo da Silva, A.J.L.
Pombeiro “3D Hydrogen Bonded Heteroneclear CoII, NiII, CuII and ZnII Aqua Complexes Derived
from Dipicolonic Acid”, Inorg. Chim Acta. 360 (2007) 506–512.
http://dx.doi.org/10.1016/j.ica.2006.07.087
J. Lasri, M.A.Januário Charmier, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, "Direct
synthesis of (imine)platinum(II) complexes by iminoacylation of ketoximes with activated
organonitrile ligands", Dalton Trans., (2007) 5062-5067.
http://dx.doi.org/10.1039/b611341a
A.M. Kirillov, P. Smolénski, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, “The First Copper
Complexes Bearing the 1,3,5-Triaza-phosphaadamantane (PTA) Ligand” Eur. J. Inorg. Chem.
(2007) 2686–2692.
http://dx.doi.org/10.1002/ejic.200601152
J. Lasri, M.A.Januário Charmier, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, “Mixed
Unsymmetric Oxadiazoline and/or Imine Platinum(II) Complexes”, Dalton Trans., (2007) 32593266.
http://dx.doi.org/10.1039/b704329e
M.T.A.R.S. da Costa, M.F.C. Guedes da Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro,
“Reactions of Bis(phenyldiazenido)rhenium Complex [ReBr2(NNPh)2(PPh3)2]Br with Carbon
Monoxide and Alk-1-ynes”, Collect Czech. Chem. Commun., 72 (2007) 599-608.
http://dx.doi.org/10.1135/cccc20070599
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S. Mukhopadhyay, J. Lasri, M.A.J. Charmier, M.F.C. Guedes da Silva, A.J.L. Pombeiro,
“Microwave Synthesis of Mono- and Bis-Tetrazolato Complexes via 1, 3-Dipolar Cycloaddition
of Organonitriles with Platinum(II)-bound Azides”, Dalton Trans., (2007) 5297-5304.
http://dx.doi.org/10.1039/b709959b
S. Bolaño, J. Bravo, J.A. Castro-Fojo, M.M. Rodríguez-Rocha, M.F.C. Guedes da Silva, A.J.L.
Pombeiro, L. Gonsalvi, M. Peruzzini, “Synthesis, Reactivity, X-ray Crystal Structures and
Electrochemical Behaviour of Water-Soluble [Tris(pyrazolyl)borato] ruthenium(II) Complexes of
1,3,5-triaza-7-phosphaadamantane (PTA)”, Eur. J. Inorg. Chem., 35 (2007) 5523-5532.
(highlighted as one of the most accessed articles in December 2007).
http://dx.doi.org/10.1002/ejic.200700672
S. Mukhopadhyay, J. Lasri, M.F.C. Guedes da Silva, M.A.J. Charmier, A.J.L. Pombeiro, “transBis[5(4-fluorophenyl)tetrazolato]bis(triphenylphosphine)platinum(II)”, Acta Crys. E63, (2007)
m2656.
http://dx.doi.org/10.1107/S1600536807047617
Alexander M. Kirillov, Piotr Smolenski, M. Fátima C. Guedes da Silva and Armando J. L.
Pombeiro, “1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo-[3.3.1.1]decane 7-oxide triiodide”
Acta Crys. E64 (2007) o496–o497.
http://dx.doi.org/10.1107/S1600536808001426
T.F.S Silva, L.M.D.R. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Bis[tris(1pyrazolyl)methane-kappa N-3,N ',N '']copper(II) dichloride methanol disolvate” Acta Cryst., E63
(2007) M1979-U1707
http://dx.doi.org/10.1107/S1600536807024671
2008
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A.M. Kirillov, Y.Y. Karabach, M. Haukka, M.F.C. Guedes da Silva, J. Sanchiz, M.N.
Kopylovich, A.J.L. Pombeiro, “Self-assembled Copper(II) Coordination Polymers Derived from
Aminopolyalcohols and Benzenepolycarboxylates: Structural and Magnetic Properties”, Inorg.
Chem., 47 (2008) 162-175.
http://dx.doi.org/10.1021/ic701669x
M.V. Kirillova, A.M. Kirillov, M.F.C. Guedes da Silva, M.N. Kopylovich, J.J.R. Fraústo da
Silva, A.J.L. Pombeiro, “3D Hydrogen Bonded Metal-Organic Frameworks Constructed from
[M(H2O)6][M’(dipicolinate)2].mH2O (M/M’ = Zn/Ni or Ni/Ni). Identification of Intercalated
Acyclic (H2O)6/(H2O)10 Clusters”, Inorg. Chim. Acta, 361 (2008) 1728-1737.
http://dx.doi.org/10.1016/j.ica.2006.12.016
M.V. Kirillova, M.L. Kuznetsov, J.A.L. Silva, M.Fátima C. Guedes da Silva, J.J.R. Fraústo da
Silva, A. J.L. Pombeiro, “Amavadin and Other Vanadium Complexes as Remarkable Efficient
Catalysts for the Single-Pot Conversion of Ethane into Propionic and Acetic Acids”, Chem. Eur.
J., 14 (2008) 1828-1842.
http://dx.doi.org/10.1002/chem.200700980
Piotr Smolenski, Alexander M. Kirillov, M. Fátima C. Guedes da Silva and Armando J. L.
Pombeiro,
“1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo-[3.3.1.13,7]decane
Tetrafluoroborate”, Acta Cryst. (2008) E64, o556.
http://dx.doi.org/10.1107/S1600536808003401
Alexander M. Kirillov, Piotr Smolenski, M. Fátima C. Guedes da Silva, Maximilian N.
Kopylovich and Armando J. L. Pombeiro “Three-dimensional hydrogen-bonded supramolecular
assembly in tetrakis(1,3,5-triaza-7-phosphaadamantane)copper(I) chloride hexahydrate” Acta
Cryst. E64 (2008) m603–m604.
http://dx.doi.org/10.1107/S1600536808008179
Ricardo R. Fernandes, Alexander M. Kirillov, M. Fátima C. Guedes da Silva, Zhen Ma, José A.
L. da Silva, João J. R. Fraústo da Silva, Armando J. L. Pombeiro “An Infinite Two-Dimensional
Hybrid Water-Chloride Network, Self-Assembled in a Hydrophobic Terpyridine Iron(II) Matrix”
Crys. Grow. & Design 8 (2008) 782–785.
http://dx.doi.org/10.1021/cg7010315
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Paolo Sgarbossa, M. Fátima C. Guedes da Silva, Alessandro Scarso, Rino A. Michelin, Armando
J.L. Pombeiro “Lewis acidity of platinum(II)-based Baeyer–Villiger catalysts: Na electrochemical
approach” Inorg. Chim. Acta, 2008, 361, 3247- 3253.
http://dx.doi.org/10.1016/j.ica.2007.10.050
P. Smolenski, C. Dinoi, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Synthesis of the Watersoluble
[Rh(Tpms)(CO)(PTA)] Compound, the First Transition Metal Complex Bearing the 1,3,5-triaza7-phosphaadamantane (PTA) and the Tris(1-pyrazolyl)methane sulfonate (Tpms) Ligands”, J.
Organometal. Chem., 693 (2008) 2338-2344.
http://dx.doi.org/10.1016/j.jorganchem.2008.04.008
J. Lasri , M.F.C. Guedes da Silva, M.A. Charmier, A.J.L. Pombeiro “Optically Active Mixed
Unsymmetric Imine Platinum(II) Complexes. Utilization of the Liberated Imines to Further
Syntheses of Mixed Imine-Diazadiene Complexes and of E-cyanoalkanes”, Eur. J. Inorg. Chem.,
(2008) 3668-3677.
http://dx.doi.org/10.1002/ejic.200800343
J. Lasri, M.N. Kopylovich, M.F.C. Guedes da Silva, M.A. Charmier, A.J.L. Pombeiro , “MetalFree and PdII-Promoted [2+3] Cycloadditions of a Cyclic Nitrone to Phthalonitriles: Syntheses of
Oxadiazolines as well as Phthalamide-PdII and Dihydropyrrolyl-iminoisoindolinone-PdII
Complexes with High Catalytic Activity in Suzuki-Miyaura Cross-Coupling Reactions”, Chem.
Eur. J., 14(30), (2008) 9312-9322.
http://dx.doi.org/10.1002/chem.200800510
Marina V. Kirillova, Alexander M. Kirillov, M. Fátima C. Guedes da Silva, Armando J.L.
Pombeiro “Self-assembled Two-dimensional Water-soluble Dipicolinate-Cu/Na Coordination
Polymer: Structural Features and Catalytic Activity for the Mild Peroxidative Oxidation of
Cycloalkanes in Acid-free Medium”, Eur. J. Inorg. Chem., (2008) 3423–3427.
http://dx.doi.org/10.1002/ejic.200800355
P. Smoleński, S. Mukhopadhyay, M.F.C. Guedes da Silva, M.A.J. Charmier, A.J.L. Pombeiro ,
“New Water-soluble Azido- and Derived Tetrazolato-platinum(II) Complexes with 1,3,5-Triaza7-phosphaadamantane (PTA). Easy Metal-mediated Synthesis and Isolation, from Aqueous
Medium, of 5-Substituted Tetrazoles”, Dalton Trans., (2008) 6546 - 6555.
http://dx.doi.org/10.1039/b808156e
S. Mukhopadhyay, J. Lasri, M.F.C. Guedes da Silva, M.A.J. Charmier, A.J.L. Pombeiro
“Activation of C-CN bond of Propionitrile: an Alternative Route to the Syntheses of 5substituted-1H-Tetrazoles and Dicyano-Platinum(II) Species”, Polyhedron, 27(13), (2008) 28832888.
http://dx.doi.org/10.1016/j.poly.2008.06.031
S. Mukhopadhyay, B.G. Mukhopadhyay, M.F.C. Guedes da Silva, J. Lasri, M. A. J. Charmier,
A.J.L. Pombeiro, “PtII-Promoted [2+3] Cycloaddition of Azide to Cyanopyridines: Convenient
Tool toward Heterometallic Structures” , Inorg. Chem., 47 (2008) 11334-11341.
http://dx.doi.org/10.1021/ic8014223
R. Wanke, P. Smolenski, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro, “Cu(I)
Complexes Bearing the New Sterically Demanding and Coordination Flexible Tris(3-phenyl-1pyrazolyl)methanesulfonate Ligand and the Water-Soluble Phosphine 1,3,5-Triaza-7phosphaadamantane or Related Ligands”, Inorg.Chem., 47 (2008) 10158-10168.
http://dx.doi.org/10.1021/ic801254b
2009
II.98
Ł. Jaremko, A.M. Kirillov, P. Smoleński, T. Lis, M.F.C. Guedes da Silva, A.J.L. Pombeiro ,
“Synthesis, Characterization and Molecular Structures of the Hybrid Organic-Inorganic Salts of
N-alkyl-1,3,5-triaza-7-phosphaadamantane
(alkyl
=
methyl,
ethyl)
and
Tetra(isothiocyanato)cobalt(II)
“,
Inorg.
Chim. Acta,
362 (2009)
1645-1649.
http://dx.doi.org/10.1016/j.ica.2008.07.016
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Konstantin V. Luzyanin, M. Fátima C. Guedes da Silva, Vadim Yu. Kukushkin, Armando
J.L.Pombeiro, “First example of an imine addition to coordinated isonitrile” Inorganica Chimica
Acta, 362 (3), (2009) 833-838.
http://dx.doi.org/10.1016/j.ica.2008.02.026
J. Lasri, M.F.C. Guedes da Silva, M.N. Kopylovich, S. Mukhopadhyay, M.A.J. Charmier, A.J.L.
Pombeiro, “PdII-Promoted [2+3] Cycloadditions of Pyrrolin N-oxide to Organonitriles.
Application of (4-1,2,4-oxadiazoline)-PdII Complexes in the Suzuki-Miyaura Reaction”, Dalton
Trans., (2009) 2210-2216.
http://dx.doi.org/10.1039/b813996b
M.N. Kopylovich, J. Lasri, M.F.C. Guedes da Silva, A.J.L. Pombeiro , “Single-pot Template
Transformations of Cyanopyridines on a PdII Centre: Syntheses of Ketoimine and 2,4-Dipyridyl1,3,5-Triazapentadiene Palladium(II) Complexes and Their Catalytic Activity for Microwave
assisted Suzuki-Miyaura and Heck Cross-Coupling Reactions in Solid Phase”, Dalton Trans.,
(2009) 3074-3084. Highlighted as a “hot article”.
http://dx.doi.org/10.1039/b820680e
P. Smolenski, L. Benisvy, M.F.C. Guedes da Silva, A.J.L. Pombeiro, “Syntheses and Crystal
Structures of the First Zinc Complex with 1,3,5-Triaza-7-phosphaadamantane (PTA),
[ZnCl2(PTA)2], and of the Hybrid Organic-Inorganic Salts of N-Methyl-1,3,5-triaza-7phosphaadamantane with Tetrahalozinc [PTA-Me]2[ZnI2X2] (X = I, Cl)” Eur. J. Inorg. Chem.
(2009) 1181–1186.
http://dx.doi.org/10.1002/ejic.200801023
Zhen Ma, Yanpeng Xing, Mei Yang, Miao Hua, Baoqing Liu, M. Fátima C. Guedes da Silva,
A.J.L. Pombeiro, “The double-helicate terpyridine silver(I) compound [Ag2L2](SO3CF3)2 (L = 4’phenyl-terpyridine) as a building block for di- and mononuclear complexes”, Inorg. Chim. Acta,
(2009) 2921-2926.
http://dx.doi.org/10.1016/j.ica.2009.01.018
A.M.Kirillov, P. Smolenski, L. Benisvy, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Unprecedent
Metal-Free C(sp3)-C(sp3) Bond Cleavage: Switching from N-Alkyl- to N-Methyl- 1,3,5-triaza-7phosphaadamantane” Organometallics 28 (2009) 1683-1687.
http://dx.doi.org/10.1021/om801026a
K.V. Luzyanin, A.G. Tshovrebov, M.F.C. Guedes da Silva, M. Haukka, A.J.L. Pombeiro,V.Yu.
Kukushkin “Metal-mediated [2+3] Cycloaddition of Nitrones to Palladium-bound Isonitriles”
Chem. Eur. J., 15 (24), (2009) 5969 – 5978.
http://dx.doi.org/10.1002/chem.200802623
N.C.T. Martins, M.F.C. Guedes da Silva, R.Wanke, Armando J.L. Pombeiro, “Electrocatalytic
Reduction of Organohalides Mediated by the Dihalo-Molybdenum Phosphinic Complexes trans[MoX2(Ph2PCH2CH2PPh2)2] (X = I, Br) – A Mechanistic Study by Cyclic Voltammetry Digital
Simulation”, Dalton Trans.,(2009) 4772–4777.
http://dx.doi.org/10.1039/b811393a
M. Gajewska, K.V. Luzyanin, M.F.C. Guedes da Silva, Q. Li, Jingrong Cui, A.J.L. Pombeiro,
“Cyclic Trinuclear Diorganotin(IV)-Complexes – the First Tin Compounds Bearing
Oximehydroxamate Ligands: Synthesis, Structural Characterization and High in vitro
Cytotoxicity” Eur.J.Inorg.Chem., (2009) 3765-3769.
http://dx.doi.org/10.1002/ejic.200900388
B.G. Mukhopadhyay, S. Mukhopadhyay, M.F.C. Guedes da Silva, M.A.J. Charmier, A.J. L.
Pombeiro, “Synthesis of mono- and bis-tetrazolato complexes of Ni(II), Pt(II) and Cu(II) via 1,3dipolar
cycloadditions
of
2-cyanopyridines
with
metal
ligated
azides
in
N,N,Oaminoiminophenolato complexes”, Dalton Trans., (2009) 4778–4785.
http://dx.doi.org/10.1039/b902007a
S.M.P.R.M. Cunha, M.F.C. Guedes da Silva, J.J. R. Fraústo da Silva, A.J.L. Pombeiro,
“Cyanoimide-Bridged, Bi- and Trinuclear, Heterometallic Complexes with na NCN–Mo–NCN
Phosphinic Core” Eur. J. Inorg. Chem., (2009) 3966-3971.
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http://dx.doi.org/10.1002/ejic.200900398
II.110 A.M. Kirillov, P. Smoleński, Z. Ma, M.F.C. Guedes da Silva, M. Haukka, A.J.L. Pombeiro
“Copper(I) Iodide Complexes derived from N-alkyl-1,3,5-Triaza-7-phosphaadamantanes:
Synthesis, Crystal Structures, Photoluminescence and Identification of the Unprecedented
{Cu3I5}2– Cluster”, Organometallics, 28 (2009) 6425-6431.
http://dx.doi:10.1021/om900591q
II.111 L. Benisvy, R. Wanke, M.F.C. Guedes da Silva, A.J.L. Pombeiro, “Towards the Functionalisation
of the Methine Carbon of a Sterically Hindered Tris(pyrazolyl)methane: Is a Radical Pathway
Envisageable? Synthesis and structure of Tetrakis(3,5-dimethylpyrazolyl)methane”, Tetrahedron,
2009, Volume 65( 45), (2009) 9218-9223.
http://dx.doi.org/10.1016/j.tet.2009.09.006
II.112 T.F.S. Silva, G.S. Mishra, M.F. Guedes da Silva, R. Wanke, L.M.D.R.S. Martins, A.J.L.
Pombeiro, “CuII Complexes Bearing the 2,2,2-tris(1-pyrazolyl)ethanol or 2,2,2-tris(1pyrazolyl)ethyl methanesulfonate Scorpionates. X-Ray Structural Characterization and
Application in the Mild Catalytic Peroxidative Oxidation of Cyclohexane”, Dalton Trans., (2009)
9207–9215.
http://dx.doi.org/10.1039/b911990f
II.113 K.V. Luzyanin, A.G. Tskhovrebov, M.C.Maia, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro,
V.Yu. Kukushkin, "Novel Metal-Mediated (M = Pt, Pd) Coupling between Isonitriles and
Benzophenone Hydrazone as a Route to Aminocarbene Complexes Exhibiting High Catalytic
Activity (M = Pd) in the Suzuki–Miyaura Reaction" Organometallics, 28(22), (2009) 6559–6566.
http://dx.DOI.org/10.1021/om900682v
II.114 J. Lasri, M. F.C. Guedes da Silva, M.N. Kopylovich, B.Ghosh Mukhopadhyay, A.J. L. Pombeiro
“Platinum(II)-Promoted [2+3] Cycloaddition of Azide with 4-Cyanobenzaldehyde, a Schiff Base
Derivative or Dicyanobenzenes To Give Formyl-, Amino(imino)- or Cyano-Functionalized
Tetrazolato Complexes” Eur. J. Inorg. Chem. (2009) 5541-5549.
http://dx.DOI.org/10.1002/ejic.200900858
2010
II.114 A.M. Kirillov, E.C.B.A. Alegria, M. F.C. Guedes da Silva, L.M.D.R.S. Martins, C. Sousa, A.J.L.
Pombeiro. “Synthesis, characterization and redox behaviour of benzoyldiazenido-3 and
oxorhenium complexes bearing N,N- and S,S-type ligands” Inorg. Chim. Acta, 363 (2010) 12691274.
http://dx.doi.org/10.1016/j.ica.2009.08.030
II.115 T.F.S. Silva, K.V. Luzyanin, M.V. Kirillova, M. Fátima Guedes da Silva, L.M. D. R. S. Martins,
A.J. L. Pombeiro “Novel Scorpionate and Pyrazole Dioxovanadium Complexes, Catalysts for
Carboxylation and Peroxidative Oxidation of Alkanes” Advanced Synthesis & Catalysis,
Volume 352, 1 (2010) 171-187.
http://dx.doi.org/10.1002/adsc.200900660
II.116 K.T. Mahmudov, M.N. Kopylovich, M.F.C. Guedes da Silva, P.J. Figiel, Y. Yu. Karabach, A.J L.
Pombeiro, “New copper(II) dimer with 3-(2-hydroxy-4-nitro-phenylhydrazo)pentane-2,4-dione
and its catalytic activity in cyclohexane and benzyl alcohol oxidations”, J. Mol. Cat. A:Chem.,
Volume 318, 1-2, (2010) 44-50.
http://dx.doi.org/10.1016/j.molcata.2009.11.006
II.117 Z. Ma, Y. Cao, Q. Li , M. F.C. Guedes da Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro,
“Synthesis, Characterization, Solid-state Photo-luminescence and Anti-tumor Activity of Zinc(II)
4’-phenyl-terpyridine Compounds”, J. Inorg. Biochem., 104(7), (2010) 704-11.
http://dx.doi.org/10.1016/j.jinorgbio.2010.03.002
II.118 C. Dinoi, M.F.C. Guedes da Silva, .E.C.B.A. Alegria, P. Smoleński, L.M.D.R.S. Martins, R. Poli,
A.J L. Pombeiro*, “Molybdenum Complexes Bearing the Tris(1-pyrazolyl)methanesulfonate
Ligand: Synthesis, Characterization and Electrochemical Behaviour”, Eur. J. Inorg. Chem., 16
(2010) 2415-2424.
http://dx.doi.org/10.1002/ejic.201000018
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II.119 P. J. Figiel, M.N. Kopylovich, J. Lasri, M.F.C. Guedes da Silva, J.J.R. Fraústo da Silva, A.J.L.
Pombeiro, “ Solvent-free Microwave-assisted Peroxidative Oxidation of Secondary Alcohols to
the Corresponding Ketones Catalyzed by Copper(II) 2,4-alkoxy-1,3,5-triazapentadienato
Complexes”, Chem. Commun., 46 (2010) 2766-2768.
http://dx.doi.org/10.1039/b922738e
II.120 R. Wanke, M.F.C. Guedes da Silva, S. Lancianesi,T.F.S. Silva, L.M.D.R.S. Martins, C. Pettinari,
A.J.L. Pombeiro “Synthesis and Coordination Chemistry of a New N4-Polydentate Class of
Pyridyl-Functionalized Scorpionate Ligands: Complexes of FeII, ZnII, NiII, VIV, PdII and Use for
Heterobimetallic Systems” Inorg.Chem., 49 (2010) 7941-7952.
http://dx.doi.org/10.1021/ic100966u
II.121 P.J. Figiel, A. M. Kirillov, M. F. C. Guedes da Silva, J. Lasri, A. J. L. Pombeiro “Self-assembled
dicopper(II) diethanolaminate cores for mild aerobic and peroxidative oxidation of alcohols”
Dalton Trans., 39 (2010) 9879–9888.
http://dx.doi.org/10.1039/c0dt00472c
II.122 A.M. Kirillov, J.A. S. Coelho, M.V. Kirillova, M. F. C. Guedes da Silva, D.S. Nesterov, K.R.
Gruenwald, M. Haukka, A.J.L. Pombeiro “Bringing an “Old” Biological Buffer to Coordination
Chemistry: New 1D and 3D Coordination Polymers with [Cu4(Hbes)4] Cores for Mild
Hydrocarboxylation of Alkanes” Inorg. Chem. 49 (2010) 6390–6392.
http://dx.doi.org/10.1021/ic1007999
II.123 Y. Y. Karabach, M. F.C. Guedes da Silva, M. N. Kopylovich, B. Gil-Hernandez, J. Sanchiz, A.
M. Kirillov, A. J. L. Pombeiro “Self-Assembled 3D Heterometallic CuII/FeII Coordination
Polymers with Octahedral Net Skeletons: Structural Features, Molecular Magnetism, Thermal and
Oxidation Catalytic Properties” Inorg. Chem., 2010, 49, 11096-11105
http://dx.doi.org/10.1021/ic101668f
II.124 A. Lis, M.F.C. Guedes da Silva, A. M. Kirillov, P. Smolenski, A. J. L. Pombeiro “Design of
Silver(I)-PTA Coordination Polymers through Controlled N,P-Coordination of 1,3,5-Triaza-7phosphaadamantane (PTA) with Arylcarboxylates” Crystal Growth & Design, 2010, 10, 52445253.
http://dx.doi.org/10.1021/cg101058x
2011
II.125 M.N. Kopylovich, J. Lasri, M.F.C. Guedes da Silva, A.J. L. Pombeiro, “PdII-Promoted Single-Pot
Template Transformations of Benzonitriles, Cyanoguanidine and Sodium Dicyanamide with the
Formation of Symmetrical and Asymmetrical (1,3,5-Triazapentadienate)palladium(II) Complexes
Eur. J. Inorg. Chem. 2011, 377–383 .
http://dx.doi.org/10.1002/ejic.201000898
II.126 T.F.S. Silva, M.F.C. Guedes da Silva, G.S. Mishra, L.M.D.R.S. Martins, A.J.L. Pombeiro,
“Synthesis and structural characterization of iron complexes with 2,2,2-tris(1-pyrazolyl)ethanol
ligands: Application in the peroxidative oxidation of cyclohexane under mild conditions”
J.Organomet. Chem. 2011, 696, 1310-1318.
http://dx.doi.org/10.1016/j.jorganchem.2010.12.036
II.127 M.N. Kopylovich, T.C..O. MacLeod, K.T. Mahmudov, M.F.C. Guedes da Silva, A.J.L. Pombeiro
“Zinc(II) ortho-Hydroxyphenylhydrazo-β-diketonate Complexes and their Catalytic Ability
towards Diastereoselective Nitroaldol (Henry) Reaction” Dalton Trans., 2011, 40, 5352-5361.
http://dx.doi.org/10.1039/C0DT01457E
II.128 M.N. Kopylovich, K.T. Mahmudov, M.F.C. Guedes da Silva, P.J. Figiel, Y.Yu. Karabach, M.L.
Kuznetsov, K.V. Luzyanin, A.J. L. Pombeiro, “Ortho-hydroxyphenylhydrazo-β-diketones:
tautomery, coordination ability and catalytic activity of their copper(II) complexes toward
oxidation of cyclohexane and benzylic alcohols”, Inorganic Chemistry, 2011, 50¸918-931.
http://dx.doi.org/10.1021/ic101516k
II.129 M.N. Kopylovich, K.T. Mahmudov, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, M.L.
Kuznetsov, T.F.S. Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro “Trends in properties of para-
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substituted 3-(phenylhydrazo)pentane-2,4-diones” J. Phys. Org. Chem. 2010, Published online in
Wiley Online Library: 2010; 24, 2010, 764 – 773. http://dx.doi.org/10.1002/poc.1824
K.T. Mahmudov, M.N. Kopylovich, K.V. Luzyanin, A. Mizar, M.F.C. Guedes da Silva, V.
André, A.J.L. Pombeiro, “Structural and thermal properties of three cyano-substituted
azoderivatives of β-diketones” J. Mol. Struct. 2011, Volume 992, Nº 1-3, 19 Abril 2011, 72-76.
http://dx.doi.org/10.1016/j.molstruc.2011.02.045
A.G. Tskhovrebov, K. V. Luzyanin, F. M. Dolgushin, M.Yu. Antipin, M. Fátima C. Guedes da
Silva, A. J. L. Pombeiro, V.Yu. Kukushkin “Novel Reactivity Mode of Metal Diaminocarbenes:
PdII-Mediated Coupling between ADCs and Isonitriles Leading to Binuclear Carbene Species”
Organometallics, 30, 2011, 3362–3370. Publication Date (Web): May 26, 2011.
http://dx.doi.org/10.1021/om20025744
L. Benisvy, R. Wanke, M.F.C. Guedes da Silva, A.J.L. Pombeiro “A Dianionic Dinickel(II)
Complex and Its Oxidised Phenoxyl Radical States” Eur. J. Inorg. Chem. 2011, 21912796 (online 18-05-2011). http://dx.doi.org/10.1002/ejic.201100232
R.R. Fernandes, J. Lasri, M. Fátima C. Guedes da Silva, J.A da Silva, J.J.R. Fraústo da Silva,
A.J. L. Pombeiro “Mild Alkane C H and O H Oxidations Catalysed by Mixed N,S Copper, Iron
and Vanadium Systems” Applied Catalysis A: General, Volume 402, Issues 1-2, 2011, 110-120.
http://dx.doi.org/10.1016/j.apcata.2011.05.035
R.R. Fernandes, J. Lasri, M.F.C. Guedes da Silva, A.M.F. Palavra, J.A.L. da Silva, J.J.R. Fraústo
da Silv, A.J. L. Pombeiro, “Oxadiazoline and ketoimine Pd(II) complexes as highly efficient
catalysts for Suzuki-Miyaura cross-coupling reactions in supercritical CO2” Adv. Synth. Catal.
2011, 353, 1153 – 1160
http://dx.doi.org/10.1002/adsc.201000909
R.R. Fernandes, J. Lasri, A.M. Kirillov, M. Fátima C. Guedes da Silva, J.A.L. da Silva, J.J.R.
Fraústo da Silva, A. Pombeiro “New Fe(II) and Cu(II) complexes bearing azathia macrocycles:
catalyst precursors for mild peroxidative oxidation of cyclohexane and 1-phenylethanol” Eur. J.
Inorg. Chem. (on-line 26 JUL 2011), 2011, 3781–3790.
http://dx.doi.org/10.1002/ejic.201100460
A. M. Kirillov, S. Wieczorek, A. Lis, M. F. C. Guedes da Silva, M. Florek,J. Król, Z.
Staroniewicz, P. Smoleński, A. J. L. Pombeiro, “1,3,5-triaza-7-phosphaadamantane-7-oxide
(PTA=O): new diamondoid building block for design of 3D metal-organic frameworks” Crystal
Growth & Design, 2011, 11, 2711–2716. http://dx.doi.org/cg200571y
Xianmei Shang, Xianggao Meng, Elisabete C.B.A. Alegria, Qingshan Li, M. Fátima C. Guedes da
Silva, Maxim L. Kuznetsov, Armando J.L. Pombeiro "Syntheses, molecular structures,
electrochemical behavior, theoretical study and antitumor activities of organotin(IV) complexes
containing 1-(4-chlorophenyl)-1-cyclopentanecarboxylato ligands" Inorg. Chem., 2011, 50, 81588167. Publication Date (Web): July 27, 2011.
http://dx.doi.org/ic200635g
R. Wanke, L. Benisvy, Maxim L. Kuznetsov, M. Fátima C. Guedes da Silva and Prof. Armando J.
L. Pombeiro “Persistent Hydrogen-Bonded and Non-Hydrogen-Bonded Phenoxyl Radicals”
Chemistry - A European Journal 17(42), 2011, 11882–11892.
http://dx.doi.org/10.1002/chem.201101509
J. Lasri, M. J. F. Rodríguez, M. Fátima C. Guedes da Silva, P. Smoleński, M. N. Kopylovich, J.J.
R. Fraústo da Silva, A.J.L. Pombeiro “Microwave Synthesis of Bis(tetrazolato)-PdII Complexes
with PPh3 and Water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA). The First Example of CCN Bond Cleavage of Propionitrile by a PdII Centre” J. Organomet.Chem., 2011, 696, 35133520.
http://dx.doi.org/10.1016/j.jorganchem.2011.07.047
R.R. Fernandes, J. Lasri, M. Fátima C. Guedes da Silva, J.A. L. da Silva, J.J.R. Fraústo da Silva,
A.J.L. Pombeiro “Bis- and tris-pyridyl amino and imino thioether Cu and Fe complexes. Thermal
and microwave-assisted peroxidative oxidations of 1-phenylethanol and cyclohexane in the
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presence of various N-based additives” Journal of Molecular Catalysis A: Chemical, 2011, 351,
100-111. Available online 1 October 2011. http://dx.doi.org/10.1016/j.molcata.2011.09.022
C. Pettinari, F. Marchetti, G. Lupidi, L. Quassinti, M. Bramucci, D. Petrelli, Luca A. Vitali, M.
Fátima C. Guedes da Silva, L. M. D. R. S. Martins, P. Smoleński, A. J. L. Pombeiro “Synthesis,
Antimicrobial and Antiproliferative Activity of Novel Silver(I) Tris(pyrazolyl) methanesulfonate
and 1,3,5-Triaza-7- phosphadamantane Complexes” Inorg. Chem. 2011, 50 (21), 11173–11183.
http://dx.doi.org/10.1021/ic201714c
Piotr Smoleński, Alexander M. Kirillov, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro
“Transformations of the Vaska-type complex trans-[RhCl(CO)(PTA)2] (PTA = 1,3,5-triaza-7phosphaadamantane) during stepwise addition of HCl: Synthesis, characterization and crystal
structure of trans-[RhCl2(PTA)(PTAH)]” Inorg. Chim. Acta, 2011, 378, 342-346.
http://dx.doi.org/10.1016/j.ica.2011.09.002
A. M. Kirillov, S. W. Wieczorek, M. Fátima C. Guedes da Silva, J. Sokolnicki, P. Smolenski, A.
J. L. Pombeiro “Crystal engineering with 1,3,5-triaza-7-phosphaadamantane (PTA): first PTAdriven 3D metal-organic frameworks. CrystEngComm, 2011, 13, 6329-6333.
http://dx.doi.org/10.1039/c1ce05612c
S. H. Mehdi, R. Hashim, R. M. Ghalib, M. Fátima C. Guedes da Silva, O. Sulaiman, S. Z.
Rahman d, V. Murugaiyah, M. M. Marimuth “Synthesis, characterization, antimicrobial and
enzymatic activity of 4b,9b-dihydroxy-7,8-dihydro-4bH-indeno[1,2-b]benzofuran-9,10(6H,9bH)dione” J. Mol. Struct., 2011, 1006, 318-323. Available online 21 September 2011
http://dx.doi.org/10.1016/j.molstruc.2011.09.026
F. Marchetti, C. Pettinari, R. Pettinari, A. Cerquetella, L.M. D. R. S. Martins, M. Fátima C.
Guedes da Silva, T.F.S. Silva, A.J. L. Pombeiro “Ru(II) arene complexes bearing
tris(pyrazolyl)methanesulfonate capping ligands. Electrochemistry, spectroscopic and X-ray
structural characterization” Organomettalics, 2011, 30, 6180-6188 Publication Date (Web):
October 24, 2011.
http://dx.doi.org/10.1021/om200713v
M.N. Kopylovich, K.T. Mahmudov, M. Fátima C. Guedes da Silva, A. M. Kirillov, A. J. L.
Pombeiro “Unusual shift of a nitro group in a phenylhydrazo--diketone” Dalton Trans. 2011, 40,
12472-12478. First published on the web 13 Oct 2011.
http://dx.doi.org/10.1039/C1DT11209K
A.M. Kirillov, M.V. Kirillova, L.S. Shul’pina, P.J. Figiel, K.R. Gruenwald, M. Fátima C. Guedes
da Silva, M. Haukka, A..L. Pombeiro, G.B. Shul’pin, “Mild oxidative functionalization of alkanes
and alcohols catalyzed by new mono- and dicopper(II) aminopolyalcoholates” J. Mol. Catal. AChem., 2011, 350, 26-34.
http://dx.doi.org/10.1016/j.molcata.2011.08.028
R. R. Fernandes, J. Lasri, M. Fátima C. Guedes da Silva, J.A.L. da Silva, J.J.R. Fraústo da Silva,
A.J.L. Pombeiro, “Bis- and tris-pyridyl amino and imino thioether Cu and Fe complexes. Thermal
and microwave-assisted peroxidative oxidations of 1-phenylethanol and cyclohexane in the
presence of various N-based additives”, J. Mol. Cat.: A Chem., 2011, 351, 100-111.
http://dx.doi.org/10.1016/j.molcata.2011.09.022
2012
II.149 M.N. Kopylovich, Y.Yu. Karabach, M. Fátima C. Guedes da Silva, P.J. Figiel, J. Lasri, A.J.L.
Pombeiro “Alkoxy-1,3,5-Triazapentadien(e/ato) Copper(II) Complexes: Template Formation and
Applications for Preparation of Pyrimidines and as Catalysts for Oxidation of Alcohols to
Carbonyl Products” Chemistry – A European Journal, 2012, 18, 899-914.
http://dx.doi.org/10.1002/chem.201101688
II.150 J. Lasri, S. Gupta, M. Fátima C. Guedes da Silva, A. J. L. Pombeiro “Copper(II)-mediated in-situ
hydrolyses of pyrroline N-oxide and benzonitrile leading to a mixed ligand complex” Inorg.
Chem. Commun, 2012,18, 72-69.
http://dx.doi.org/10.1016/j.inoche.2012.01.012
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II.151 A. Mizar, M. Fátima C. Guedes da Silva, M.N. Kopylovich, S. Mukherjee, K.T. Mahmudov,
A.J.L. Pombeiro “Water-Soluble Copper(II) Complexes with a Sulfonic-Functionalized
Arylhydrazone of β-Diketone and Their Application in Peroxidative Allylic Oxidation of
Cyclohexene” Eur. J. Inorg. Chem. 2012, 2305–2313. http://dx.doi.org/10.1002/ejic.201101361
II.152 R.S. Chay, K.V. Luzyanin, V.Yu. Kukushkin, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro
“Novel Palladium–Aminocarbene Species Derived from Metal-Mediated Coupling of Isonitriles
and 1,3-Diiminoisoindoline: Synthesis and Catalytic Application in Suzuki–Miyaura CrossCoupling” Organometallics, 2012, 31 (6), 2379–2387
http://dx.doi.org/10.1021/om300020j
II.153 C. Di Nicola, F. Garau, M. Gazzano, M. Fátima C. Guedes da Silva, A. Lanza, M. Monari, F.
Nestola, L. Pandolfo, C. Pettinari, A.J.L. Pombeiro “New Coordination Polymers and Porous
Supramolecular Metal Organic Network Based on the Trinuclear Triangular SBU [Cu3(μ3-OH)(μpz)3]2+ and 4,4’-Bipyridine. 1” Cristal Growth & Design, 12, 2012, 2890−2901.
http://dx.doi.org/10.1021/cg300080a (listed as one of the 10 most read articles of CC&D in
2012).
II.154 B.G.M. Rocha, R. Wanke, M. Fátima C. Guedes da Silva, K.V. Luzyanin, L.M.D.R.S. Martins, P.
Smolénski, A.J.L. Pombeiro, “Reactivity of bulky tris(phenylpyrazolyl)methanesulfonate
copper(I) complexes towards small unsaturated molecules”, J. Organomet. Chem., 714, 2012, 4752. http://dx.doi.org/10.1016/j.jorganchem.2012.03.022
II.155 E.C.B.A. Alegria, M.Fátima C. Guedes da Silva, M.L. Kuznetov, S.M.P.R.M. Cunha, L.M.D.R.S.
Martins, A.J.L. Pombeiroa “Acylated Cyanoimido-Complexes trans-[Mo(NCN){NCNC(O)R}
(dppe)2]Cl and their Reactions with Electrophiles: Chemical, Electrochemical and Theoretical
Study” Dalton Trans., 2012, 41,13876-13890.
http://dx.doi.org/10.1039/C2DT30867C
II.156 M.N. Kopylovich, M.J. Gajewska, K.T. Mahmudov, M.V. Kirillova, P.J. Figiel, M. Fátima C.
Guedes da Silva,B.Gil-Hernández, J.Sanchiz, A.J.L. Pombeiro, "Copper(II) complexes of 3-(2hydroxy-4-carboxyphenyl-hydrazone)pentane-2,4-dione as effective catalysts for the acid-free
peroxidative alkane and aerobic benzyl alcohol oxidations" New Journal of Chemistry, 2012, 36,
1646-1654. http://dx.doi.org/10.1039/C2NJ40210F
II.157 K.T. Mahmudov, M. Fátima C. Guedes da Silva, M. Glucini, M. Renzi, K.C.P. Gabriel, M.N.
Kopylovich, M. Sutradhar, F. Marchetti, C. Pettinari, S. Zamponi, A.J.L. Pombeiro “Watersoluble heterometallic copper(II)-sodium complex comprising arylhydrazone of barbituric acid as
a
ligand”
Inorg.
Chem.
Commun.,
32,
2012,172-189.
http://dx.doi.org/10.1016/j.inoche.2012.06.008
II.158 M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “Redox Potential Parameterization in
Coordination Compounds with Polydentate Scorpionate and Benzene Ligands” Electrochimica
Acta, 2012, 82, 478-483. http://dx.doi.org/10.1016/j.electacta.2012.05.006
II.159 K.T. Mahmudov, M. Fátima C. Guedes da Silva, M. Glucini, M. Renzi, K.C.P. Gabriel, M.N.
Kopylovich, M. Sutradhar, F. Marchetti, C. Pettinari, S. Zamponi, A.J.L. Pombeiro*, “Watersoluble heterometallic copper(II)-sodium complex comprising arylhydrazone of barbituric acid as
a ligand”, Inorg. Chem. Commun., 2012, 22, 187-189.
http://dx.doi.org/10.1016/j.inoche.2012.06.008
II.160 T.C.O. Mac Leod, M.N. Kopylovich, M. Fátima C. Guedes da Silva, K.T. Mahmudov, A.J.L.
Pombeiro, “Copper(II) complexes of arylhydrazones of  -diketones immobilized on Zn-Al
layered double hydroxides as effective recyclable catalysts for peroxidative oxidation of alkanes”,
Appl.Cat. A: Gen., 2012, 439, 15-23. http://dx.doi.org/10.1016/j.apcata.2012.06.032
II.161 J. Lasri, G. Gajewski M. Fátima C. Guedes da Silva, M.L. Kuznetsov, R.R Fernandes, A.J.L.
Pombeiro, “Solvent-Dependent Reactivities of Acyclic Nitrones with β-Diketones: Catalyst-free
Syntheses of
Endiones and Enones”, Tetrahedron, 2012, 35, 7019-7027.
http://dx.doi.org/10.1016/j.tet.2012.06.086
II.162 A. Kirillov, M. Filipowicz, M. Fátima C. Guedes da Silva, J. Kłak, P. Smoleński, A.J.L.
Pombeiro, “Unprecedented Mixed-Valence Cu(I)/Cu(II) Complex Derived from N-Methyl-1,3,5-
Curriculum Vitae
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triaza-7-phosphaadamantane: Synthesis, Structural Features and Magnetic Properties”
Organometallics, 31 (22), 7921–7925. http://dx.doi.org/10.1021/om3005564
II.163 X. Shang, E.C.B.A. Alegria, M. F. C. Guedes da Silva, M. L. Kuznetsov, Q. Li, A. J.L.
Pombeiro,* "Redox-Active Cytotoxic Diorganotin(IV) Cycloalkylhydroxamate Complexes with
Different Ring Sizes: Reduction Behaviour and Theoretical Interpretation", J. Inorg. Biochem.,
2012, 117, 147-156.
http://dx.doi.org/10.1016/j.jinorgbio.2012.08.019
II.164 J. Lasri, M. Kuznetsov, M. F. C. Guedes da Silva, A. J. L. Pombeiro, "PtII-mediated imine–nitrile
coupling leading to symmetrical (1,3,5,7,9-pentaazanona-1,3,6,8-tetraenato)Pt(II) complexes
containing the incorporated 1,3-diiminoisoindoline moiety", Inorg. Chem., 2012, 51 1077410786. http://dx.doi.org/10.1021/ic301176b
II.165 T. F. S. Silva, L. M. D. R. S. Martins, M. F. C. Guedes da Silva, A. R. Fernandes, A. Silva, P. M.
Borralho, S. Santos, C.M. P. Rodrigues, A. J. L. Pombeiro, “Cobalt complexes bearing
scorpionate ligands: synthesis, characterization, cytotoxicity and DNA cleavage”, Dalton Trans.,
2012, 41, 12888-12897 (article featured online on Global Medical Discovery [ISSN 1929-8536])
http://dx.doi.org/10.1039/c2dt11577h
II.166 M. Sutradhar, M. Kirillova, M. F. C. Guedes da Silva, L. Martins, A.J.L. Pombeiro, “A
Hexanuclear Mixed-valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane
Oxidation Catalyst”, Inorg. Chem., 2012, 51 (21), 11229–11231.
http://dx.doi.org/10.1021/ic3017062
2013
II.167 M.N. Kopylovich, A. Mizar, M.F.C. Guedes da Silva, T.C.O. Mac Leod, K.T. Mahmudov, A.J. L.
Pombeiro, “Template Syntheses of Copper(II) Complexes from Arylhydrazones of Malononitrile
and their Catalytic Activity towards Alcohol Oxidations and Nitroaldol Reaction. Hydrogen Bond
Assisted Ligand Liberation and E/Z Isomerisation”, Chem.-Eur.J., 2013, 19, 588-600.
http://dx.doi.org/10.1002/chem.201203254
II.168 T.F.S. Silva, T.C.O. Mac Leod, L. M. D. R. S. Martins, M. F. C. Guedes da Silva, M. A.
Schiavon, A. J.L. Pombeiro, “Pyrazole or tris(pyrazolyl)ethanol oxo-vanadium(IV) complexes as
homogeneous or supported catalysts for oxidation of cyclohexane under mild conditions” J. Mol
Cat.:A Chem. 2013, 367, 52–60. http://dx.doi.org/10.1016/j.molcata.2012.10.024
II.169 M.N. Kopylovich, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, M.L. Kuznetsov, K.T.
Mahmudov, A.J.L. Pombeiro, “Synthesis, structure and electrochemical behaviour of Na, MgII,
MnII, ZnII, CdII and NiII complexes of 3-(2-carboxyphenylhydrazone)pentane-2,4-dione”
Polyhedron, 2013, 50, 374-382. http://dx.doi.org/10.1016/j.poly.2012.11.030
II.170 M. Fátima C. Guedes da Silva, A.J. L. Pombeiro “XXV International Conference on
Organometallic Chemistry”, Platinum Metals Rev., 2013, 57, (1), 17–31.
http://dx.doi.org/10.1595/147106713X659127
II.171 X. Shang, T.F.S. Silva, L.M.D.R.S. Martins, Q. Li, M.F.C. Guedes da Silva, M.L. Kuznetsov,
A.J.L. Pombeiro “Synthesis, characterization, electrochemical behavior and in vitro protein
tyrosine kinase inhibitory activity of the cymene-halogenobenzohydroxamato [Ru(η6cymene)(bha)Cl] complexes” J. Organomet. Chem. in press.
http://dx.doi.org/10.1016/j.jorganchem.2012.12.013
II.172 M. Sutradhar, M.F.C. Guedes da Silva, D.S. Nesterov, J. Jezierska, A.J.L. Pombeiro “1D
coordination polymer with octahedral and square-planar nickel(II) centres” Inorganic Chemistry
Communications, 2013, 29, 82-84. http://dx.doi.org/10.1016/j.inoche.2012.12.008
II.173 M. Sutradhar, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Synthesis and chemical reactivity of
an Fe(III) metallacrown-6 towards N-donor Lewis bases”, Inorg. Chem. Commun., 2013, 30, 42.45. http://dx.doi.org/10.1016/j.inoche.2013.01.017
Curriculum Vitae
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III  RESEARCH PAPERS IN A NATIONAL (REFEREED) JOURNAL
III.1
III.2
III.3
III.4
III.5
III.6
III.7
III.8
III.9
III.10
III.11
III.12
III.13
III.14
III.15
III.16
M. Isabel S. Pereira, M. Fátima C. Guedes da Silva, M. José B.V. Melo, Fernanda M. A. da
Costa, "Estudo Comparativo da Electrocristalização do SnS em Eléctrodos de Amálgama e
Estanho Sólido", Port. Electroch. Acta, 3 (1985) 21-34.
M. Fátima C. Guedes da Silva, Armando J. L. Pombeiro, "Redox Properties of the Nitrile
Complexes trans-[ReCl(NCR)(Ph2PCH2CH2PPh2)2]", Port. Electroch. Acta, 7 (1989) 95-100.
M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Anodic Deprotonation of
Methyleneamido to Nitrile Ligands at a Rhenium Centre", Port. Electroch. Acta, 9 (1991) 189194.
M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, "Anodically
Induced cis to trans Isomerization of the Nitile Complexes cis-[ReCl(NCR)(dppe)2]", Port.
Electroch. Acta, 11 (1993) 93-97.
Yu-Ying Tong, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, P. Martin-Zarga, G. Martin, P. Gili, "Redox Properties of some Tryptamine-Derived
Salicylaldimines and of their Tetra-Coordinate Cobalt(II), Nickel(II) or Copper(II) Complexes",
Port. Electroch. Acta, 11 (1993) 87-92.
Elsa M.P.R.P. Branco, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Roberta Bertani,
Rino A. Michelin, Mirto Mozzon, "Redox Properties of Hydride Complexes of Pt(II) with a
Metal-Carbon Single Bond", Port. Electroch. Acta, 11 (1993) 81-86.
M. Estela S. Dória, Elsa M.P.R. Branco, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro,
Rino A. Michelin, Roberta Bertani, Mirto Mozzon, "Redox Properties of Some CyanamideDerived Complexes of Palladium(II) or Platinum(II)", Port. Electroch. Acta, 13 (1995) 325-328.
M. Fátima C. Guedes da Silva, J. Armando L. da Silva, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, Christian Amatore, Jean-Nöel Verpeaux, "Searching for the Mechanism of the
Electrocatalytic Oxidation of Mercaptopropionic Acid by an Amavadine model", Port. Electroch.
Acta, 13 (1995) 315-318.
M. Fátima C. Guedes da Silva, "Activation of Complexes by Electron-Transfer Processes",
Portugaliæ Electrochimica Acta, 14 (1996) 41-43.
Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro,
“Electrochemical Behaviour of adducts of trans-Mo(NCN)2(dppe)2  with some transition metal
Lewis acids”, Port. Electroch. Acta, (1996) 177-181.
M. Fátima C. Guedes da Silva, Isabel L.F. Machado, Armando J.L. Pombeiro, R. Bertani, G.
Facchin, M. Gleria, R.A. Michelin, M. Mozzon, F. Noé, “Electrochemical Behavior of PtCinnamonitrile Cyclophosphazene Complexes”, Port. Electroch. Acta, 14 (1996) 183-187.
Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Piotr Sobota,
“Electrochemical Study of Some Vanadium Complexes”, Port. Electroch. Acta, (1996) 157-161.
Fernando S.C.L. Conde, Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Armando J.L.
Pombeiro, Rino A. Michelin, Christian Amatore, “ Electrochemical Behaviour of Platinum
Complexes with Ligating Unsaturated Carbon Species”, Port. Electroch. Acta, 15 (1997) 263268.
Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, “Comparative
Electrochemical Behaviour of Protonated Derivatives of trans-[Mo(NCEt)(NCN)(dppe)2]+” Port.
Electroch. Acta, 15 (1997) 269-273.
M. Fátima C. Guedes da Silva, Katayoun Marjami, Armando J.L. Pombeiro, Raymond L.
Richards, “Anodically-Induced Isomerization of cis-[Mo(SC6H2Pri3-2,4,6)2(CNBut)4]. A
Mechanistic Study” Port. Electroch. Acta, 15 (1997) 275-280.
Sónia M.P.R.M. da Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Redox
Properties of the Nitrogen-Cyanamide Complexes trans-[Mo(N2)(NCNR2) (dppe)2]” Port.
Electroch. Acta, 17 (1999), 221-224.
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III.17 Natércia C. T. Martins, M. Fátima C. Guedes da Silva , J.Armando L. da Silva, João J. R. Fraústo
da Silva, Carlos Paliteiro, Armando J.L. Pombeiro “Electrocatalytic Oxidation of Pyrogallol by an
Amavadin Model”, Port. Electroch. Acta, 19 (2001) 367-370.
III.18 Silvia S.P.R. Almeida, João J.R. Fraústo da Silva and Armando J.L. Pombeiro “Estimate of
Electrochemical Ligand Parameters in Iron(II) Adducts of [FeH(CN)(dppe) 2]”, Port. Electroch.
Acta, 19 (2001) 371-376.
III.19 E.C.B.A. Alegria, S.M.P.R.M. Cunha, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L.
Pombeiro, “Comparative Electrochemical Behaviour of the Complexes trans[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)Cl(dppe)2][BF4]”,
Portugaliae Electrochimica Acta, 2004, 22, 19-23.
IV – PATENTS
IV.1
IV.2
IV.3
IV.4
IV.5
IV.6
IV.7
IV.8
IV.9
Q.Li, A.J.L. Pombeiro, M. Fátima C. Guedes da Silva, H. Lingge, “Diorgano-tin Derivatives of
Aryl-hydroxamic Acids Having Anti-tumor Activity”, PT 102826 (priority date: 2002/08/07;
award date: 2004/08/23).
A.J.L. Pombeiro, A.M. Kirillov, M.N. Kopylovich, M.V. Kirillova, M. Haukka, M. Fátima C.
Guedes da Silva, “New Di-, Tri-, Tetra- and Poly-nuclear Copper Complexes, and Their Use as
Catalysts for the Peroxidative Oxidation of Cyclohexane”. PT 103225 (priority date:
2005/01/19; award date: 2006/03/20).
A.J.L. Pombeiro, J. Lasri, M. Kopylovich, M. Fátima C. Guedes da Silva, R.R. Fernandes,
M.A.C. Januário, “New Palladium Complexes with Bis(pyrrolidinyledene)phthalamides and Dihydropyrrolyliminoisoindolinones, and their Application as Catalysts in Suzuki-Miyaura
Coupling Reactions”, PT 104187 (priority date: 2008/09/25; award date: 2009/07/23).
A.J.L. Pombeiro, J. Lasri, M. Kopylovich, M. Fátima C. Guedes da Silva, S. Mukhopadhyay,
R.R. Fernandes, M.A.J. Charmier, “New Palladium Complexes with Bicyclic Ligands of
Hydropyrol-Oxadiazole Type, and Their Application as Catalysts in Microwave-assisted
Suzuki-Miyaura Coupling Reactions”, PT 104199 (priority date: 2008/09/30; award date:
2009/08/11).
A.J.L. Pombeiro, M. Gajewska, K.V. Luzyanin, M. Fátima C. Guedes da Silva, Q. Li, “New
Cyclic Trinuclear Tin Complexes with Antitumor Activity bearing the Oxime-Hydroxamate
Type Ligand N,2-di-hydroxi-5-(1-hidroxyiminoethyl)benzamide”, PT 104676 (priority date:
2009/07/20; award date: 2010/02/08).
A.J.L. Pombeiro, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, G.S. Mishra, T.F.S. Silva,
R. Wanke, “Copper(II) Complexes with Hydrophilic C-functionalized Scorpionate Ligands and
Their Application as Catalysts for thye Peroxidative Oxidation of Cyclohexane under
Environmentally Tolerable Conditions, in Particular in Aqueous Medium”, PT 104713 (priority
date: 2009/08/09; award date: 2010/09/13).
A.M. Kirillov, P. Smoleński, Z. Ma, M. Fátima C. Guedes da Silva, M. Haukka, A.J.L. Pombeiro,
“Copper Complexes Bearing Iodo and Aminophosphine Ligands, Their Preparative Method and
Use as Photoluminescent Materials, PT 104799 (priority date: 2009/10/20; award date:
2010/10/26).
A. J.L. Pombeiro, P.J. Figiel, M. Kopylovich, J. Lasri, M. Fátima C. Guedes da Silva, J. J.R.
Fraústo da Silva, L. M.D.R.S. Martins, T. F.S. Silva, “Copper(II) Complex with 2,4-ethoxy1,3,5-triazapentadienide Ligands and its Application, and of the 2,4-methoxy Analogue, as
Catalysts for the Peroxidative Oxidation, Assisted by Microwaves and without Addition of
Solvent, of Secondary Alcohols to Ketones”, PT 104884 (priority date: 2009/12/15; award date:
2011/10/26).
A.J.L. Pombeiro, L.M.D.R.S. Martins, T.F.S. Silva, M. Fátima C. Guedes da Silva, K. V.
Luzyanin, M. V. Kirillova, “Oxocomplexes of Vanadium(IV-V) with Scorpionate or Pyrazol
Ligands and Their Application as Catalysts for the Peroxidative Oxidation of Cycloalkanes and
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
IV.10
29 / 47
the Carboxylation of Gaseous Alkanes”, PT 104887 (priority date: 2009/12/15; award date:
2011/09/06).
A.J.L. Pombeiro, R.R. Fernandes, J. Lasri, A.M.F. Palavra, M. Fátima C. Guedes da Silva,
J.A.L. Silva, J.J.R. Fraústo da Silva, “Palladium (II) Complexes with Oxadiazoline and
Ketoimine Ligands as Catalysts of Suzuki-Miyaura Reactions in Supercritical Carbon Dioxide
Medium”, PT 105634 (priority date: 2011/04/19; award date: 2011/04/19).
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
30 / 47
INVITED LESSONS
1
2
3
4
5
.
M. Fátima C. Guedes da Silva, "Activation of Complexes by Electron-Transfer Processes", VIII
Encontro da Sociedade Portuguesa de Electroquímica, Covilhã, 1996, 1. (invited lecture).
M. Fátima C. Guedes da Silva “Reacções Induzidas por Transferência Electrónica” SIBAE 2002,
XV Congresso da Sociedade Ibero-Americana de Electroquímica, Évora, Portugal, 2002, 5030KN (invited keynote lecture).
M. Fátima C. Guedes da Silva, "Mechanisms of Selected Electron-Transfer Induced Processes in
Coordination Chemistry", X Iberic Meeting of Electrochemistry, XIV Congresso da Sociedade
Portuguesa de Electroquímica, 2007, Coimbra, Portugal, PL3, p5 (invited lecture).
M. Fátima C. Guedes da Silva, “Chemical and Structural Studies of Complexes with N- and OLigands”, International Conference on Organometallic and Coordination Chemistry, Nizhny
Novgorod, Rússia, Setembro, 2008, S9 (invited keynote lecture).
M. Fátima C. Guedes da Silva, “Metal Coordination Structures and Hydrogen Bond Effects”
International workshop on Materials for Catalysis and Energy, National Taiwan University of S
& T, Taipei, Taiwan, February, 2009 (invited lecture).
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
31 / 47
COMMUNICATIONS (ORAL AND POSTER) AT CONGRESSES.
1983
1
2
M. Isabel S. Pereira, M. Fátima C. Guedes da Silva, Fernanda M.A. da Costa, "Electrodeposição
do Sulfureto de Estanho(II) em Amálgama de Estanho", IV Reunião Internacional de
Electroquímica, Braga, 1983, C31.4.
M. Isabel S. Pereira, M. Fátima C. Guedes da Silva, Fernanda M.A. da Costa, "Electrochemical
Phase Formation on Tin Amalgam in Sulphide Solutions", 34th ISE Meeting, Erlangen,
Alemanha, 1983.
1988
3
Talib Al-Salih, C.J. Pickett, M. Emília R. Silva, M. Fátima C. Guedes da Silva, Armando J.L.
Pombeiro, "Carbon-Halogen Bond Cleavage at Electrochemically Generated Molybdenum(I)
Sites", XXVI International Conference on Coordination Chemistry, Porto, 1988, MS-1, P8.
1989
4
5
6
M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Redox Properties of the Nitrile
Complexes trans-[ReCl(NCR)(Ph2PCH2CH2PPh2)2]", IV Encontro da Sociedade Portuguesa de
Electroquímica, Estoril, Portugal, 1989, A6.
M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Redox Potential-Structure Relationships
at Nitrile Complexes with the Metal Centre {Re(Ph2PCH2CH2PPh2)2}+", Journées
d'Electrochimie, Montpellier, França, 1989, A 3-21.
Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva, David Hughes, Raymond L. Richards,
"Preparation and Properties of the Nitrile Complexes trans-[ReCl(NCR)(dppe)2] (R=alkyl or
aryl)", International Conference on the Chemistry of the Early Transition Metals, The Royal
Society of Chemistry, University of Sussex, 1989 (ver I.3).
1990
7
8
João J.R. Fraústo da Silva, Armando J.L. Pombeiro, J. Armando L. Silva, M. Fátima C.Guedes da
Silva, "Electrochemical Behaviour of the 'Amavadine' Model [V(HIDA) 2]2- in Non-Aqueous
Media", Italian-Portuguese-Spanish Meeting in Inorganic Chemistry, Gandia, Espanha, 1990,
B20, 240.
Roberta Bertani, Tânia J. Castilho, Rino Michelin, Mirto Mozzon, Armando J.L. Pombeiro, M.
Fátima C. Guedes da Silva, "Redox Properties of Carbene Complexes of Palladium(II) and
Platinum(II)" J. Heyrovsky Centennial Congress on Polarography, Praga, 1990.
1991
9
10
11
12
M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Adrian Hills, David L. Hughes,
Raymond L. Richards, "Syntheses and Molecular Structure of the Dinitrile-and DifluoroRhenium Complex trans-[Re(NCC6H4Me-4)2(dppe)2][ReF2(dppe)2][BF4]2", 12º Encontro da
Sociedade Portuguesa de Química, Coimbra, 1991, 362
M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Anodic Deprotonation of Methyleneamido to Nitrile Ligands at a Rhenium Centre", V Encontro da Sociedade Portuguesa de
Electroquímica e I Reunião Ibérica de Electroquímica, Aveiro, 1991, 108 (presented by
M.F.C.G.S.).
M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Electrochemically-Induced
Dehydrogenation of the Hydride-Nitrile Complexes [ReClH(NCR)(dppe)2][BF4]", Journnées
d'Electrochimie, Brest, França, 1991, Ca4.3.
M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Raymond L.Richards, "Synthesis of the
Hydride-Nitrile-Complexes [ReClH(NCR)(dppe)2][BF4]", International Conference on Inorganic
Chemistry, Univ. Sussex, Brighton, 1991.
1992
13
M. Teresa Duarte, João J.R. Fraústo da Silva, Adelino M. Galvão, M. Fátima C. Guedes da Silva,
Armando J.L. Pombeiro, "Synthesis and Crystal Structure of trans-[ReCl2(dppe)2][BF4]", 13º
Encontro da Sociedade Portuguesa de Química, Lisbon, 1992, PI10.
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
14
15
16
17
18
19
20
21
22
23
32 / 47
M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Rino A. Michelin, Mirto Mozzon,
"Conversion of Ethyldiazoacetate into Diethylfumarate at a Pt Centre; Synthesis of [Pt(2EtO2CCH=CHCO2Et)(PPh3)2]", Italian-Portuguese-Spanish Meeting, Algarve, 1992, OM44
(presented by M.F.C.G.S.).
Tânia J. Castilho, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Roberta Bertani, Mirto
Mozzon, Rino A. Michelin "Electrochemical Behaviour of Aminooxy-, Dioxy- and
Diaminocarbene Complexes of Palladium(II) and Platinum(II)", NATO ARW, Sintra, 1992, P14.
João J.R. Fraústo da Silva, M. Fátima C. Guedes da Silva, José Armando L. da Silva, Armando J.
L. Pombeiro, "Redox Properties of the Amavadine Models [V(HIDA)2]2- and [V(HIDPA)2]2- and
their Electroinduced Reactivity towards Activated-Thiols and -Phenols", NATO ARW,
Sintra, 1992, P19.
M. Fátima C. Guedes da Silva, João J. R. Fraústo da Silva, Armando J.L. Pombeiro, Christian
Amatore, Jean-Nöel Verpeaux, "Mechanism of the Electroactivation of the Metal-Hydride Bond
in [ReClH(NCR)(Ph2PCH2CH2PPh2)2][BF4]", NATO ARW, Sintra, 1992, P24.
M. Fátima C. G. Silva, M. Teresa Duarte, Adelino M. Galvão, João J. R. Fraústo da Silva,
Armando J.L. Pombeiro, "Synthesis and Structural Characterization of cis-[Re(NCC6H4 Me4)2(Ph2PCH2CH2PPh2)2][BF4]", I.C.C.C., Lausanne, 1992, P550.
João J.R. Fraústo da Silva, M. Fátima C. Guedes da Silva, J. Armando L. da Silva, Armando J.L.
Pombeiro, "Redox Properties of Amavadine Models [V(HIDA)2]2- and [V(HIDPA)2]2-, Mediators
for the Electrocatalytic Oxidation of some Thiols and Phenols", EUROBIC I, Newcastle, 1992,
P84.
Rino A. Michelin, Mirto Mozzon, Roberta Bertani, Armando J.L. Pombeiro, M. Fátima C.
Guedes da Silva, "Chemical and Electrochemical Behaviour of Hydrido-Carbene Complexes of
Pt(II)", I Congresso Gruppo Interdivisionaly Chimica Organometallica, CO.G.I.C.O.'92,
Camerino, 1992, 20.
Elsa M.P.R.P. Branco, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Roberta Bertani,
Rino Michelin, Mirto Mozzon, "Redox Properties of Hydride Complexes of Pt(II) with a MetalCarbon Single Bond", VI Encontro da Sociedade Portuguesa de Electroquímica, Vila Real, 1992,
44.
Yu-Ying Tong, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, P. Martin-Zarga, G. Martin, P. Gili, "Redox Properties of some Tryptamine-Derived
Salicylaldimines and of their Tetra-Coordinate Cobalt(II), Nickel(II) or Copper(II) Complexes",
VI Encontro da Sociedade Portuguesa de Electroquímica, Vila Real, 1992, 46 (presented by
Y.Y.T.).
M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, "Anodically
Induced cis to trans Isomerization of the Nitrile Complexes [ReCl(NCR)(dppe)2]", VI Encontro
da Sociedade Portuguesa de Electroquímica, Vila Real, 1992, 48 (presented by M.F.C.G.S.).
1993
24
25
26
27
M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, Christian
Amatore, J.-N. Verpeaux, "Electrochemical Mechanistic Study of the Isomerization of the Nitrile
Complex [ReCl(NCC6H4F-4)(dppe)2]", 12th Summer School on Coordination Chemistry,
Karpacz, Polónia, 1993, P20, 72.
M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, "Synthesis
and Characterization of the cis Isomers of the Nitrile Complexes [ReCl(NCR)(dppe)2]", LatinAmerican Inorganic Chemistry Meeting, Santiago de Compostela, 1993, LAICM1220P, 115.
Elsa M.P.R.P. Branco, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, Rino Michelin, Roberta Bertani, Mirto Mozzon, Paola Berin, "Cyanamide Complexes
of Palladium and Platinum", Latin-American Inorganic Chemistry Meeting, Santiago de
Compostela, 1993, LAICM1218P, 104.
Roberta Bertani, Rino A. Michelin, Mirto Mozzon, Roberta Seraglia, M. Fátima C. Guedes da
Silva, Armando J.L. Pombeiro, "Highly Reactive Platinum(0) Intermediates; a Fast Atom
Bombardment-Mass Spectrometry Study", XXI Congresso Nazionale di Chimica Inorganica,
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
33 / 47
Villasimius, Cagliari, 29 Septembre-01 Octobre (1993) 419; 1st Journal of Organometallic
Conference on Applied Organometallic Chemistry, Munchen, Germany, Nov. 4-5, (1993) 7;
Sintesi e Metodologie Speciali in Chimica Inorganica (Applicazioni a Composti e Materiali
Innovativi), Bressanone, Itália, 1993, p.58.
1994
28
29
30
31
Roberta Bertani, Rino A. Michelin, Mirto Mozzon, Roberta Seraglia, M. Fátima C. Guedes da
Silva, Armando J.L. Pombeiro, "Highly Reactive Platinum(0) Carbene Intermediates in the
Reactions of Diazo Compounds. A Fast Atom Bombardment Mass Spectrometric Study", XVI Int.
Conf. Organomet. Chem., Univ. Sussex, 1994, P.42.
Franco Benetollo, Roberta Bertani, Gabriela Bombieri, Elsa M.P.R.P. Branco, M. Estela S. Dória,
M. Fátima C. Guedes da Silva, Rino A. Michelin, Mirto Mozzon, Armando J.L. Pombeiro, Yu
Wang, "Synthesis and Properties of Cyanamide and Cyanoguanidine Complexes of Platinum(II).
X-Ray Structure of trans-[Pt(CF3)(NCNEt2)(PPh3)2][BF4]." XVI Int. Conf. Organomet. Chem.,
Univ. Sussex, 1994, P.211.
Roberta Bertani, Giacomo Facchin, M. Gleria, M. Fátima C. Guedes da Silva, Isabel L.F.
Machado, Rino Michelin, Armando J.L. Pombeiro, "Redox Properties of Platinum Complexes
with Cinnamonitrile Substituted Phosphazenes", 45th Annual Meeting of the International Society
of Electrochemistry, Porto, 1994, IV-6.
M. Fátima C. Guedes da Silva, M. Amélia N.D.A. Lemos, Armando J.L. Pombeiro, "ElectronTransfer Activation of the Aminocarbyne Complex trans-[ReCl(CNH2)(dppe)2] [BF4]", 45th
Annual Meeting of the International Society of Electrochemistry, Porto, 1994, IV-31.
1995
32
33
34
35
36
37
Adelino M. Galvão, Elena Levi, Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva, J.
Armando da Silva, João J.R. Fraústo da Silva, "Modelos da Amavadina - Estudos com o
Complexo de Crómio(III) com HIDA", 2ª Conferência de Química Inorgânica, Sociedade
Portuguesa de Química, Monte Real, 1995, CP 22, 91.
M. Fátima C. Guedes da Silva, José Armando L. Silva, João J. R. Fraústo da Silva, Armando J.L.
Pombeiro, "Oxidação Electrocatalítica de Tióis por Complexos de Vanádio, modelos da
Amavadina", 2º Encontro da Divisão de Catálise, Sociedade Portuguesa de Química, Lisbon,
1995, 47-48.
M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, M. Angela
Pellinghelli, Antonio Tiripicchio, "Binding of Isocyanides to an Electron-Rich Rhenium(I)
Centre. X-Ray Molecular Structures of the Complexes trans-[ReCl(CNR)(dppe)2] (R = H or
SiMe3)", 24th IUPAC Conference on Solution Chemistry, Lisbon, 1995, PH04, 192.
M. Estela S. Dória, Elsa M.P.R.P. Branco, Maria de Fátima C. Guedes da Silva, Armando J.L.
Pombeiro, Rino A. Michelin, Roberta Bertani, Mirto Mozzon, "Redox Properties of Some
Cyanamide-Derived Complexes of Palladium(II) and Platinum(II)", VII Encontro da Sociedade
Portuguesa de Electroquímica, III Encontro Ibérico de Electroquímica, Algarve, 1995, B7, 67.
M. Fátima C. Guedes da Silva, J. Armando L. da Silva, João J. R. Fraústo da Silva, Armando J.L.
Pombeiro, Christian Amatore, Jean-Nöel Verpeaux, "Searching for the Mechanism of the
Electrocatalytic Oxidation of Mercaptopropionic Acid by an Amavadin Model", VII Encontro da
Sociedade Portuguesa de Electroquímica, III Encontro Ibérico de Electroquímica, Algarve, 1995,
B4, 59.
M. Fátima C. Guedes da Silva, Luísa M.D.R.S. Martins, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, "FAB-MS Spectra of Nitrile or Cyanamide Complexes with the
{M(Ph2PCH2CH2PPh2)2}n+ (M = Fe or Re) Metal Sites. Applications to the Reactions Induced in
FAB Conditions", 2º Encontro de Espectrometria de Massa, Lisbon, 1995, P15, 85.
1996
38
M. Fátima C. Guedes da Silva, João J. Fraústo da Silva, Armando J.L. Pombeiro, Maria A.
Pellinghelli, Antonio Tiripicchio, " Deprotonation Reactions of the Aminocarbyne Complex
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
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40
41
42
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trans-[ReCl(CNH2)(dppe)2][BF4] (dppe = Ph2PCH2CH2PPh2) to Form Cyano-Complexes with
Small
Unsaturated
Ligands.
XRay
Molecular
Structure
of
transth
[Re(CN)(NCMe)(dppe)2].C3H8O", 13 Summer School on Coordination Chemistry, Wroclaw Polónia, 1996, P30. 88.
M. Fátima C. Guedes da Silva, Cristina M.P. Ferreira, Elsa M.P.R.P. Branco, Armando J.L.
Pombeiro, Rino Michelin, Gabriella Bombieri, Franco Benetollo, " Synthesis and Molecular
Structure of the Cyanoguanidine-Derived Azametallacycle Complex cis-[(PPh3)2Pt{NHC(OMe)=NC(NH2)=NH}][BPh4]" 13th Summer School on Coordination Chemistry, Wroclaw,
Polónia, 1996, P22, 80.
Cristina M.P. Ferreira, Annette Limberg, M. Fátima C. Guedes da Silva, Mohamed F. Meidine,
Armando J. L. Pombeiro, Piotr Sobota, “Electrochemical Study of Some Vanadium Complexes”,
VIII Encontro da Sociedade Portuguesa de Electroquímica, Covilhã, 25-28 Setembro 1996, 26.
Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Electrochemical
Behaviour of Adducts of trans-Mo(NCN)2(dppe)2 with Some Transition Metal Lewis Acids”,
VIII Encontro da Sociedade Portuguesa de Electroquímica, Covilhã, 1996, 33.
M. Fátima C. Guedes da Silva, Isabel L.F. Machado, Armando J.L. Pombeiro, M. Gleria, R.
Bertani, G. Facchin, F. Noé, R.A. Michelin, M. Mozzon, “Electrochemical behavior of PtCinnamonitrile Cyclophosphazene Complexes”, VIII Encontro da Sociedade Portuguesa de
Electroquímica, Covilhã, 1996, B9, 34.
1997
43
44
45
46
47
48
49
50
M. Fátima C. Guedes da Silva, M. Fernanda N.N. Carvalho, M Amélia N.D.A. Lemos, Armando
J.L. Pombeiro, “Binding and Reactivity of Cyanide, Isocyanide and Aminocarbyne, CNH x (x = 0
- 2), at a Single Transition Metal Centre”, 16th Conference on Coordination Chemistry,
Smolenice, Eslovaquia, 1997, p. 61.
Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Indalécio Marques, João J.R. Fraústo da
Silva, M. Cândida Vaz, Armando J.L. Pombeiro, “Fast-Atom Bombardment (FAB) Mass Spectra
of the CyanoimidoComplexe trans-Mo(NCN)2(Ph2CH2CH2PPh2)2 and some derivatives”, 3º
Encontro Nacional de Espectrometria de Massa, Lisbon, 1997, p.56-57.
Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Indalécio Marques, João J.R. Fraústo da
Silva, M. Cândida Vaz, Armando J.L. Pombeiro, “Fast-Atom Bombardment (FAB) Mass Spectra
of Some Platinum Complexes. Unusually Intense Molecular Ion Peaks in Azametallacycle
Complexes”, 3º Encontro Nacional de Espectrometria de Massa, Lisbon, 1997, p.59-60.
Rino A. Michelin, Mirto Mozzon, Roberta Bertani, Cristina M.P. Ferreira, M. Fátima C. Guedes
da Silva, Armando J.L. Pombeiro, “N-Heterocycles and Azametallacycles from reactions of
Nitriles and Cyanoguanidine Promoted by Platinum(II)”, XXV Congresso di Chimica Inorganica,
Alessandria, 1997, C12.
Lei Zhang, M.P. Gamasa, J. Gimeno, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro,
“Synthesis and Electrochemical Studies of Cyanide and Diisocyanide Bridged Fischer Type
Dinuclear Bis(Alkenyl-Carbyne) Tungsten Complexes”, International School of Organometallic
Chemistry, Camerino, 1997, p.115-116.
M. Fátima C. Guedes da Silva, Karayoun Marjani, Armando J.L. Pombeiro, R.L. Richards,
“Anodically-Induced Isomerisation of cis-Mo(SC6H2Pri3-2,4,6)2(CNBut)4  A Mechanistic
Study.” IX Encontro da Sociedade Portuguesa de Electroquímica, Braga, 1997, p. 51-52.
Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, “Comparative
Electrochemical Study of Protonated Derivatives of trans-Mo(NCN)2(Ph2CH2CH2PPh2)2 and
trans-Mo(NCNEt)(NCN)(Ph2CH2CH2PPh2)2+ ”, IX Encontro da Sociedade Portuguesa de
Electroquímica, Braga, 1997, p. 49-50.
Fernando S.C.L. Conde, Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Armando J.L.
Pombeiro, Rino A. Michelin, Christian Amatore, “Electrochemical Behaviour of Platinum(II)
Complexes with Ligating Unsaturated Carbon Species”, IX Encontro da Sociedade Portuguesa de
Electroquímica, Braga, 1997, p. 47-48.
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
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52
53
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Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Vadim Yu. Kukuskin, Armando J.L.
Pombeiro, “Oxidative addition of Oxime to a Metal Centre, a Novel Route for Methyleneamide
Ligands.
Synthesis
and
Crystal
Structures
of
transnd
Re(OH)(N=CMe2)(Ph2PCH2CH2PPh2)2HSO4.” 2 International Conference on Progress in
Inorganic and Organometallic Chemistry, Polanica Zdrój-Poland, 1997, p. 73.
Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, “Electrophilic Additions to Cyanoimide (NCN) Ligands, Crystal Structure of transMo(NCNEt)(NCN)(Ph2CH2CH2PPh2)2BF4.” 2nd International Conference on Progress in
Inorganic and Organometallic Chemistry, Polanica Zdrój-Poland, 1997, p. 72.
Cristina M.M. Matoso, J. Armando L. Silva, J.J.R. Fraústo da Silva, M. Fátima C. Guedes da
Silva, Armando J.L. Pombeiro, “A Possible Role for Amavadine in some Amanita Fungi – A
Unique Case in Biology”, The Fifth Chemical Congress of North America, Cancún, Quintana
Roo, México, 1997, 02-845.
Cristina M.M. Matoso, João J.R. Fraústo da Silva, M. Fátima C. Guedes da Silva, J. Armando L.
Silva, Nádia S.S. Viaro, “Reacções dos N-Amino e N-Hidroxi Derivados do Ácido
iminodicarboxílico e seus complexos”, XI Encontro Galego-Português de Química, Férrol, 1997,
1.02-75.
1998
55
56
57
Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, V.Yu. Kukushkin, Armando J.L.
Pombeiro, “Methyleneamide Complexes of Re Derived from Oximes”, XXXIII International
Conference on Coordination Chemistry, Florence, Itália, 1998, p. 468.
M. Fátima C. Guedes da Silva, C.M.P. Ferreira, Armando J.L. Pombeiro, “Isomeric Conversion
of cis-ReCl(CO)(Ph2CH2CH2PPh2)2 via an Electron-Transfer Chain Catalytic Mechanism”, Post
ICCC Satellite Meeting. Electrochemistry: Long- and Short-Lived Intermediates in Coordination
and Organometallic Compounds, Siena, Itália, 1998, p. 48-49.
Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, “Mechanistic
Study of the Cathodically Induced Dehydrogenation of Hydrogen Cyanamide at transMo(NCNH)(NCN) (Ph2CH2CH2PPh2)2+”, Post ICCC Satellite Meeting. Electrochemistry:
Long- and Short-Lived Intermediates in Coordination and Organometallic Compounds, Siena,
Itália, 1998, p. 46-47.
1999
58
59
60
61
62
Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Vadim Yu. Kukushkin, Rino A. Michelin,
Armando J.L. Pombeiro, “Síntese e Caracterização de Complexos Neutros de Pt(II) com
Ligandos do Tipo Imino Éter e Oxazolina. Estrutura Molecular do Complexo cis[PtCl2{N=C(OCH2CH2)NEt2}2]. “IV Conferência de Química Inorgânica, Peniche, Portugal, O4,
1999, p. 29-30.
Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, “Síntese, Caracterização e Reactividade dos primeiros Complexos Mistos de Diazoto e
Cianamidas trans-[Mo(N2)(NCNR2) (Ph2PCH2CH2PPh2)2]. Estrutura Molecular de Cianamidas
trans-[Mo(N2)(NCNEt2) (Ph2PCH2CH2PPh2)2]. “IV Conferência de Química Inorgânica,
Peniche, Portugal, 1999, P2, p. 61-62.
M. Fátima C. Guedes da Silva, Sílvia S.P.R. Almeida, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, “Anodic Deprotonation of the Hydrogen Isocyanide Complex trans[FeH(CNH)(dppe)2].” V Encontro Ibérico de Electroquímica, X Encontro da Sociedade
Portuguesa de Electroquímica”, Évora, Portugal, 1999, p. 79-80.
Sónia, M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, “Redox
Properties
of
the
Dinitrogen-Cyanamide
Complexes
trans-[Mo(N2)(NCNR2)
(Ph2PCH2CH2PPh2)2] and some derivatives.” V Encontro Ibérico de Electroquímica, X Encontro
da Sociedade Portuguesa de Electroquímica”, Évora, Portugal, 1999, p. 91-92.
M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, A.V. Zinchenko, Vadim Yu. Kukushkin,
“Electrochemical Study of Ruthenium and Osmium Complexes with S-Coordinated Me2S and
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
63
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65
66
67
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Me2SO Ligands.” V Encontro Ibérico de Electroquímica, X Encontro da Sociedade Portuguesa
de Electroquímica”, Évora, Portugal, 1999, p. 109-110.
Natércia C.T. Martins, M. Fátima C. Guedes da Silva, Sónia M.P.R.M. Cunha, Carlos Paliteiro,
Christopher J. Pickett, Armando J.L. Pombeiro, "Mechanistic Investigation of the Electrocatalytic
Reduction of Organoiodides by trans-[MoI2(dppe)2]", 14th Summer School on Coordination
Chemistry, Polanica-Zdrój, Polónia, 1999, P82, p. 144.
Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, Vadim Yu Kukushkin, "Azametallacylces from Coupling Reactions of
Dialkylcyanamides with Oximes Promoted by Pt(II)", 14th Summer School on Coordination
Chemistry, Polanica-Zdrój, Polónia, 1999, P85, p. 147.
Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.
Pombeiro, "Reactions of Cyanoimide (NCN) at a Mo Centre", 14th Summer School on
Coordination Chemistry, Polanica-Zdrój, Polónia, 1999, P86, p. 148.
M. Fátima C. Guedes da Silva, Lei Zhang, João J.R. Fraústo da Silva, Armando J.L. Pombeiro,
"Anodically-Induced C-H and N-H Bond Cleavage at Isocyanide, Alkenylcarbyne or Hydrazibe
Complexes", Organometallics and Catalysis, 14-16 Julho, 1999, University of Rennes, França, p.
34.
Lei Zhang, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Mo or W Complexes with
4e- or 2e-donor Alkenylalkyne Ligands", Organometallics and Catalysis, 14-16 Julho, 1999,
University of Rennes, França, p. 61.
2000
68
69
70
71
Natércia C.T. Martins, M. Fátima C. Guedes da Silva, Sónia M.P.R. Cunha, C. Paliteiro, C.J.
Pickett, Armando J.L. Pombeiro, “Study of the Kinetics of the Electrocatalytic Reduction of
Organic Halides by trans-[MoX2(dppe)2] (X = I, Br)”, 34th Internat. Conference on Coordination
Chemistry, 2000, Edinburg, P0065.
M. Fátima C. Guedes da Silva, Anna M. Trzeciak, Józef Ziólkowski, Armando J.L. Pombeiro,
"Electrochemical Parameterisation of Square Planar Rhodium(I/II) Redox Couples", MetalContaining Molecules: 1st Chianti Electrochemistry Meeting, Siena, Itália, 2000,57.
Ana I.F. Venâncio, Luisa M.D.R.S. Martins, M. Fátima C. Guedes da Silva, João J.R. Fraústo da
Silva, Armando J.L. Pombeiro, "Electrochemical Behaviour of Dinitrile Iron(II)-Hydride
Complexes", Metal-Containing Molecules: 1st Chianti Electrochemistry Meeting, Siena, Itália,
2000, 71.
M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro,
“Azavinylidene Complexes of Rhenium”, 3rd Internat. Conference on Progress in Inorganic and
Organometallic Chemistry (PIOC), 2000, Polanica Zdrój, Polónia, P56, p. 100.
2001
72
73
74
75
Sílvia S.P.R. Almeida, J.J.R. Fraústo da Silva, Armando J.L. Pombeiro, “Estimate of
Electrochemical Ligand Parameters in Iron(II) Adducts of [FeH(CN)(dppe) 2]”, VI Encontro
Ibérico de Electroquímica/XI Encontro da Sociedade Portuguesa de Electroquímica, Porto,
Portugal, 2001, P-B1,
Natércia C. T. Martins, M. Fátima C. Guedes da Silva , J. Armando L. da Silva, João J. R. Fraústo
da Silva, Carlos Paliteiro, Armando J.L. Pombeiro, “Electrocatalytic Oxidation of Pyrogallol by
an Amavadin Model”, VI Encontro Ibérico de Electroquímica/XI Encontro da Sociedade
Portuguesa de Electroquímica, Porto, Portugal, 2001, P-B3.
Natércia C.T. Martins, P.J. Figiel, M. Fátima C. Guedes da Silva, Józef Ziólkowski, Armando
J.L. Pombeiro, “Searching for the mechanism of the Electrocatalytic Oxidation of Cyclohexanol
by N-Hydroxyphthalimide”, 6th FIGIPS (France, Itália, Greece, Israel, Portugal and Espanha)
Meeting in Inorganic Chemistry (European Mediterranean Conference in Inorganic Chemistry),
Barcelona, Espanha, 2001, PA.058, p. 170.
Maximilian N. Kopylovich, Vadim Yu. Kukushkin, M. Fátima C. Guedes da Silva, Matti Haukka,
João J.R. Fraústo da Silva, Armando J.L. Pombeiro “Conversion of Alkyl Nitriles to Amidines
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
76
77
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and Carboxylic Acids Catalyzed by a Cobalt(II)-Ketoxime System” 4th International School on
Molecular Catalysis, Poznań Dymaczewo, Polónia, 2001, IIA-P5, p.79.
M. Fátima C. Guedes da Silva, J.J.R. Fraústo da Silva, Armando J.L. Pombeiro “Activation of
Organonitriles Towards B-Electrophilic Addition”, 3rd International School of Organometallic
Chemistry, Univ. Camerino, Itália, 2001, p.81.
Qingshan Li, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro “Diorgano- and DichloroTin(IV) Complexes of ArylHydroxamic Acids, Their Antitumor Activity in vitro and Molecular
Structures”, 3rd International School of Organometallic Chemistry, Univ. Camerino, Itália, 2001,
p.136.
2002
78
79
80
Natércia C.T. Martins, P.J. Figiel, M. Fátima C. Guedes da Silva, Józef Ziólkowski, Armando
J.L. Pombeiro “Digital Simulation of the Electrocatalytic Oxidation of Secondary Alcohols by NHydroxyphthalimide”, 2nd Chianti Electrochemistry Meeting, Siena, Itália, Julho 2002, p.69.
Sílvia S.P.R Almeida, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, “Comportamento
Electroquímico de Alguns Aductos de trans-[FeH(CN)(dppe)2]”, SIBAE 2002, XV Congresso da
Sociedade Ibero-Americana de Electroquímica, Évora, Portugal, 2002, 5255P.
Natércia C.T. Martins, P.J. Figiel, M. Fátima C. Guedes da Silva, Józef Ziólkowski, Armando
J.L. Pombeiro “Mechanistic Investigation of the Electrocatalytic Oxidation of Alcohols by NHydroxyphthalimide”, 53rd Annual Meeting of the International Society of Electrochemistry,
Alemanha, 2002, p.355.
2003
81
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E.C.B. Alegria, L.M.D.R.S. Martins, T.F.S. Silva, M. Fátima C. Guedes da Silva, A.J.L.
Pombeiro*, “Unexpected Complex Double Salt with Poly(pyrazolyl)borate Iron(III). Crystal
Structure of [Fe(HB(pz)3][FeCl4] {HB(pz)3 = hidrotris(1-pyrazolyl)borate}”, FIGIPS Meeting in
Inorganic Chemistry, Lisboa, 2003, P148.
S.S.P.R. Almeida, M. Fátima C. Guedes da Silva, L.B. Jerzykiewicz, P. Sobota, A.J.L. Pombeiro,
“Synthesis and Characterization of some Heteronuclear Complexes of Iron(II)”, FIGIPS Meeting
in Inorganic Chemistry, Lisboa, Portugal, 2003, P151.
A.I.F. Venâncio, M. Fátima C. Guedes da Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro,
“Reactions of the Allenylidene Complex trans-[FeBr(=C=C=CPh2)(dppe)2][BPh4] with
Nucleophilic Agents”, FIGIPS Meeting in Inorganic Chemistry, Lisboa, Portugal, 2003, P403.
E.C.B. Alegria, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, S.M.P.R.M. Cunha, J.J.R.
Fraústo da Silva, A.J.L. Pombeiro, “Reactions of Cyanamide at a N2 – Binding Molybdenum
Center. Formation of Cyanoimide Species”, SMWC - II Santa Maria Workshop on Chemistry,
Devoted to Bioinorganic Chemistry, Havana, Cuba, 2003, P1.
A.J.L. Pombeiro, M. Fátima C. Guedes da Silva “Bond and Structure Activation by Anodic
Electron-Transfer: Metal-Hydrogen Bond Cleavage and cis/trans Isomerization in Coordination
Compounds”, New Trends in Molecular Electrochemistry and XII Meeting of The Portuguese
Electrochemical Society, Academia das Ciências de Lisboa, Portugal, 2003, PL9, 10.
E.C.B. Alegria, S.M.P.R.M. Cunha, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L.
Pombeiro, “Electrochemical Behaviour of the Cyanoimide-Type Complexes trans[Mo(NCN){NCNC(O)R}(dppe)2]Cl and trans--[Mo(NCN)Cl(dppe)2][BF4]”, New Trends in
Molecular Electrochemistry and XII Meeting of The Portuguese Electrochemical Society,
Academia das Ciências de Lisboa, Portugal, 2003, P.ME11, 88.
N.A. Bokach, M. Haukka, V.Yu. Kukushkin, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro,
“Electrochemical Investigation of Rithenium-Bipyridine-Cyanamide Complexes” New Trends in
Molecular Electrochemistry and XII Meeting of The Portuguese Electrochemical Society,
Academia das Ciências de Lisboa, Portugal, 2003, P.ME13, 90.
2004
88
L.M.D.R.S. Martins, T.F.S. Silva, S.M.P.R.M. Cunha, E.C.B. Alegria, M. Fátima C. Guedes da
Silva, A.J.L. Pombeiro “Reactions of Cyanamide and Derived Cyanoimide at a Molybdenum
Curriculum Vitae
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Diphosphinic Centre”, Inorganic Reactions Mechanisms Meeting 2003, Athens, Greece, 2004,
P44.
E.C.B. Alegria, S.M.P.R.M. Cunha, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L.
Pombeiro “Isomerização Geométrica Induzida por Transferência Electrónica de Complexos trans
de Molibdénio e Cianoimida”, XV Congresso da Sociedade Ibero-Americana de Electroquímica,
SIBAE 2004, 2004, C027.
E.C.B. Alegria, L.M.D.R.S. Martins, M.F.C.G. da Silva, A.J.L. Pombeiro, “Cleavage of a C(sp 3)N Bond in Hydrotris(pyrazolyl)methane Promoted by a Re- Benzoylhydrazido Complex”, III
Euchem Conference on Nitrogen Ligands in Organometallic Chemistry and Homogeneous
Catalysis, Camerino, Itália, 2004, P2.
E. Reisner, V.B. Arion, M. Fátima C. Guedes da Silva, M.A. Jakupec, B.K. Keppler, V. Yu.
Kukushkin, A.J.L. Pombeiro, “Electrochemical Aspects for the Design of Ruthenium Anticancer
Drugs – Redox Behaviour, Digital Simulations and Correlations with in vitro Antiproliferative
Activity”, 3rd Chianti Electrochemistry Meeting on Metal-containing Molecules, Certosa di
Pontignano, Siena, Itália, 2004, p. 35.
L.M.D.R.S. Martins, E. Alegria, S.M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, A.J.L.
Pombeiro, “Alkylation of Cyanoimido at a N2-binding Molybdenum Centre”, XXXVIth
International Conference on Coordination Chemistry, Mérida, Mexico, 2004, P1.106, p. 468.
2005
93
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A.M. Kirillov, M. Haukka, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “Rhenium Benzoyl
hydrazido and Diazenido Complexes with N,O-Ligands and their application in the Catalytic
Peroxidative Oxidation of Cycloalkanes” 20th International Conference on Coordination and
Bioinorganic Chemistry, Smolenice, Slovakia, 2005, p.56.
Y.Yu. Karabach, A.M. Kirillov, M.N. Kopylovich, M. Fátima C. Guedes da Silva, M. Haukka,
A.J.L. Pombeiro “New Self-Assembled Copper 1D and 2D-Coordination Polymers as Catalysts
for Biphasic Peroxidative Oxidation of Cyclohexane under mild Conditions”, Current and Future
Trends in Polymeric Meterials, Prague, República Checa, 2005, PC23.
K.V. Luzyanin, M.F. C. Guedes da Silva, V. Yu. Kukushikin, A.J.L. Pombeiro “PlatinumMediated Coupling of Some HON-Nucleophiles and Nitriles: Synthetic and Electrochemical
Studies”, VIII Iberic Meeting of Electrochemistry/XII Meeting of the Portuguese Electrochemical
Society, Covilhã, Portugal, 2005, PB.2, pp97-98.
2006
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A.M. Kirilov, M.N. Kopylovich, M.V. Kirillova, Y. Yu. Karabach, M. Haukka, M. Fátima C.
Guedes da Silva and A.J.L. Pombeiro, “New Water-soluble Multinuclear Copper Triethanolamine
Complexes as Efficient Catalysts for Mild Peroxidative Oxidation of Alkanes in Aqueous
Biphasic Liquid Medium”, Green Chemistry: a Solution for the World (Andalusia meets Europe
II, 2nd Workshop of COST D29/0009/03 Working Group and AQUACHEM Midterm Review
Meeting and Workshop), Almeria, Espanha, 2006, C-3, pp. 7-8.
Y. Yu. Karabach, M. Fátima C. Guedes da Silva, M. Haukka, A.M. Kirillov, M.N. Kopylovich,
A.J.L. Pombeiro, “New 1D and 2D Water-soluble Cu(II) Polymers Derived from Pyromellitic
Acid”, Green Chemistry: a Solution for the World (Andalusia meets Europe II, 2nd Workshop of
COST D29/0009/03 Working Group and AQUACHEM Midterm Review Meeting and
Workshop), Almeria, Espanha, 2006, C-30, p. 44.
M.V. Kirillova, M. Fátima C. Guedes da Silva, A.M. Kirillov, J.J.R. Fraústo da Silva, A.J.L.
Pombeiro, “Self-assembly Synthesis and Characterization of New Heterodinuclear Aqua
Complexes of the type [M(H2O)5M’(dipic)2] (M,M’ = Co2+, Ni2+, Cu2+, Zn2+) Derived from
Dipicolinic Acid in Water Solution”, Green Chemistry: a Solution for the World (Andalusia
meets Europe II, 2nd Workshop of COST D29/0009/03 Working Group and AQUACHEM
Midterm Review Meeting and Workshop), Almeria, Espanha, 2006, P-2, p. 50.
M.F.C.Guedes da Silva, Maximilian Kuznetsov, A.J.L. Pombeiro “Azavinylidene Complexes of
Rhenium: Electrochemical Behaviour and Theoretical Study”, 4th Chianti Meeting on Inorganic
Electrochemistry, Siena, Itália, Julho 2006, p. 63.
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A.M. Kirillov, M. Haukka, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “New Mono- nad
Dicarbonyl Phosphine Rhenium(I) Complexes Bearing Aromatic N-, N, N- and N,O_Heterocyclic
Ligands” XXII International Conference on Organometallic Chemistry, Zaragoza, Espanha, 2006,
P199, p. 387.
Y. Yu. Karabach, A.M. Kirillov, M. Fátima C. Guedes da Silva, M.N. Kopylovich, A.J.L.
Pombeiro “Catalytic Activity of na Aqua-Soluble Copper(II)-Sodium Two-Dimensional
Coordination Polymer in the Peroxidqative Oxidation of Cyclohexane” Experiment & Theory in
Transition Metal Chemistry: a Meeting Point, Bellaterra, Espanha, 2006, p.45.
S.M. Sbovota, A.J.L. Pombeiro, M. Fátima C. Guedes da Silova, R.A. Michelin “Water Soluble
Organonitrile Platinum(II) Complexes” Experiment & Theory in Transition Metal Chemistry: a
Meeting Point, Bellaterra, Espanha, 2006, p.47.
M. Fátima C. Guedes da Silva, M.Kuznetsov, A.J.L. Pombeiro “Azavinylidine Complexes of
Rhenium: Electrochemical Behaviour and Theoretical Study, 4th Chianti Meeting on Inorganic
Electrochemistry, Siena, Itália, 2006, p.63.
2007
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A.M. Kirillov, M.N. Kopylovich, M.V. Kirillova, M. Haukka, M.F.C. Guedes da Silva, A.J.L.
Pombeiro, “Mild Peroxidative Oxidation of Alkanes Catalyzed by Multinuclear Cooper(II)
Triethanolaminate Complexes”, 3rd International Conference on Green and Sustainable
Chemistry (GSC-3 Symposium), Delft, The Netherlands, 2007, P108, p. 108.
M.N. Kopylovich, Ya. Yu. Karabach, A.M. Kirillov, M. Haukka, M.F.C.G. da Silva, A.J.L.
Pombeiro, “From Solution to Solid Phase: Synthesis of New Copper(II) Containing
Coordination Polymers with Diverse Architectures”. XVI International Conference on Chemical
Thermodynamics in Russia (RCCT 2007) / X International Conference on the Problems of
Solvation and Complex Formation in Solutions, Suzdal, Russia, 2007, 5/S – 560-561.
Y. Yu. Karabach, A.M. Kirilllov, M. Haukka, M.F.C. Guedes da Silva, M.N. Kopylovich,
A.J.L. Pombeiro, “New Copper(II) Containing Coordination Polymers with Diverse
Architectures”, 9th FIGIPAS Meeting in Inorganic Chemistry, Vienna, Austria, 2007, PO-76.
Y. Yu. Karabach, A.M. Kirilllov, M.F.C. Guedes da Silva, M. Haukka, M.N. Kopylovich,
A.J.L. Pombeiro “Synthesis and Characterization of Copper(II)-AminopolyalcoholBenzenepolycarboxylate Coordination Polymers” AQUACHEM – Transition Metal Chemistry
and Catalysis in Aqueous Media; 3rd Annual Meeting, Debrecen, Hungary, 2007, P3.
A.M. Kirilllov, P. Smolenski, M.F.C. Guedes da Silva, M. Haukka, M.N. Kopylovich, A.J.L.
Pombeiro “The First Copper Complexes Bearing the 1,3,5-triaza-7-phosphaadamantane (tpa)
Ligand” AQUACHEM – Transition Metal Chemistry and Catalysis in Aqueous Media; 3rd
Annual Meeting, Debrecen, Hungary, 2007, P4.
2008
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J. Lasri, M.A.J. Charmier, M.F.C. Guedes da Silva, A.J.L. Pombeiro, “Mixed Unsymmetrical
Oxadiazoline and/or Imino Platinum(II) Complexes”, IXth Netherlands’ Catalysis and Chemistry
Conference, Noordwijkerhout, The Netherlands, 2008, P71, p.223.
A. Furtado, C. Travassos, A.M. Kirillov, M.F.C. Guedes da Silva, L.M.D.R.S. Martins,
E.C.B.A. Alegria, A.J.L. Pombeiro, “Benzoyldiazenido-Re(III) or Oxo-Re(V) Complexes
Bearing N,N- and N,O-type Ligands”, XXI Portuguese Chemical Society National Meeting,
Porto, 2008, CP 210, p.274.
A.J.L.Pombeiro, M.V.Kirillova, A.M.Kirillov, M.L.Kuznetsov, J.A.L.Silva, A. Palavra,
M.F.C.Guedes da Silva, J.J.R. Fraústo da Silva, “Highly Efficient Single-pot Carboxylation of
Alkanes to Carboxylic Acids Catalysed by Group 5-7 Metal Catalysts” XXIII International
Conference on Organometallic Chemistry (ICOMC), Rennes, France, 2008, OC29.
R.R. Fernandes, A.M. Kirillov, M.F.C. Guedes da Silva, Z. Ma, J.A.L. Silva, J.J.R. Fraústo da
Silva, A.J.L. Pombeiro, “Infinite Two-Dimensional Hybrid Water-Chloride Netwrok SelfAssembled in a Hydrophobic Terpyridine Iron(II) Matrix”, XXIII International Conference on
Organometallic Chemistry (ICOMC), Rennes, France, 2008, P352.
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N.C.T. Martins, M.F.C. Guedes da Silva, P.J. Figiel, A.J.L. Pombeiro, “Electrocatalytic
Oxidation of Alcohols and Thiols by N-hydroxypthalimide”, 5th Chianti Meeting on Inorganic
Electrochemistry, Siena, Italy, 2008, p. 54 (presented by M.F.C.G.S.).
A.J.L. Pombeiro, T.F.S. Silva, G.S. Mishra, M.V. Kirillova, E.C.B. Alegria, L.M.D.R.S.
Martins, A.M. Kirillov, M.F.C. Guedes da Silva, M.L. Kuznetsov, A. Palavra, J.A.L. Silva,
J.J.R. Fraústo da Silva, “Vanadium Catalysts for the Functionalization of Alkanes under Mild
Conditions”, 6th International Vanadium Symposium, Lisbon, Portugal, 2008, O50 (presented by
A.J.L.P..).
C. DiNicola, F. Garau, M.F.C. Guedes da Silva, J. Ngourne, L. Pandolfo, C. Pettinari, A.J.L.
Pombeiro, “New Porous Coordination Polymers Based on the Triangular [Cu3(3-OH)(-pz)3]2+
Core and Pyridine Containing Ligands” 4th EuCheMS Conference on Nitrogen-Ligands in
Coordination Chemistry, Bioinorganic Chemistry & Homogeneous Catalysis, GarmischPartenkirchen, Germany, 2008, SL8, p.52.
M. Gajewska, M.F.C. Guedes da Silva, A.J.L. Pombeiro, “Synthesis and Characterization of
Dibutyltin(IV) Complexes with O-donor Ligands Derivatives”, 9th European Biological
Inorganic Chemistry Conference (EUROBIC), Wroclaw, Poland, 2008, P58, p.177.
P. Smolenski, M.F.C. Guedes da Silva, F.P. Pruchnik, A.J.L. Pombeiro, “New Rhodium Watersoluble Complexes with 1,3,5-Triaza-7-phosphaadamantane”, 9th European Biological
Inorganic Chemistry Conference (EUROBIC), Wroclaw, Poland, 2008, P183, p.302.
S. Mukhopadhyay, M.A.J. Charmier, M.F.C. Guedes da Silva, A.J.L. Pombeiro, “Platinum(II)
Mediated [2+3] Cycloaddition of Azide and Nitrile: a Conveniente Tool towards Heterometallic
Supramolecular Chemistry”, 1st International Conference on Metal-Organic Frameworks and
Open Framework Compounds (MOF08), Angsburg, Germany, 2008, P21, p.102.
A.M. Kirillov, Y.Yu. Karabach, M.V. Kirillova, K. Gruenwald, M. Haukka, M.F.C. Guedes da
Silva, M.N. Kopylovich, A.J.L. Pombeiro, “Crystal Engineering of Multicopper Compounds
with N,O- and N,P-ligands via Self-assembly in Aqueous Medium: Synthesis, Structural
Features and Catalysis”, 1st Portuguese Young Chemistry Meeting (PYChem), Lisbon, Portugal,
2008, OC-16, p.26.
R.R. Carvalho, B. Martins, Y.Yu. Karabach, M.F.C. Guedes da Silva, A.M. Kirillov, A.J.L.
Pombeiro, “A 1D Copper Coordination Polymer Derived from N-ethyldiethanolamine and
Terephthalic Acid: Synthesis, Structure and Catalytic Properties”, 1st Portuguese Young
Chemistry Meeting (PYChem), Lisbon, Portugal, 2008, P-49, p.103.
P.J. Figiel, M.N. Kopylovich, Y.Yu . Karabach, M.F.C. Guedes da Silva, A.J.L. Pombeiro,
“Oxidation of Benzylic Alcohols in Aqueous Solutions Catalyzed by Cu II-1,3,5triazapentadienate Complexes” VI International Congress of Young Chemists (YoungCheM
2008), Cracow, Poland, 2008, P19-60, p.106.
2009
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R. Wanke, P. Smolenski, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro, “Cu(I)
Complexes Bearing the New Sterically Demanding and Coordination Flexible Scorpionate
(TPMSPh) Ligand and the Water-Soluble Phosphine 1,3,5-Triaza-7-Phosphaadamantane (PTA)
or Related Ligands”, 6th European Workshop on Phosphorus Chemistry (EWPC-6), Florence,
Italy, 2009, OC32, p.43.
K.T. Mahmudov, M.N. Kopylovich, M.F.C. Guedes da Silva, P.J. Figiel, Y.Yu. Karabach,
A.J.L. Pombeiro, “Two Complexes of Copper(II) withy Ortho-Hydroxy Substituted
Phenylhydrazono-b-Diketones and Their Catalytic Activity in Some Oxidative Reactions”,
XXIV International Chugaev Conference on Coordination Chemistry, St. Petersburg, Russia,
2009, pp. 410-411.
L.M.D.R.S. Martins, C. Dinoi, P. Smolenski, M.F.C. Guedes da Silva, E.C.B. Alegria, R. Poli,
A.J.L. Pombeiro, “Electrochemical Behaviour of New Molybdenum Complexes Bearing the
Tris(1-pyrazol)methanesulfonate Ligand”, XI Iberic Meeting of Electrochemistry / XXX Meeting
of the Electrochemistry Group of the Spanish Royal Chemical Society, Tenerife, Spain, 2009,
S4-06.
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T.F.S. Silva, G.S. Mishra, M.F. Guedes da Silva, R. Wanke, L.M.D.R.S. Martins, A.J.L.
Pombeiro,”Water-soluble Cu(II) Complexes Bearing the 2,2,2-Tris(1-pyrazolyl)ethanol or
2,2,2-Tris(1-pyrazolyl)ethylmethanesulfonate. X-ray Structural Characterization and
Application in the Mild Catalytic Peroxidative Oxidation of Cyclohexane”, XII Regional
Seminar of PhD Students on Organometallic and Coordination Chemistry, Szklarska Poreba,
Poland, 2009, OP18.
R.R. Fernandes, J.A.L. da Silva, M.F.C. Guedes da Silva, J.J.R. Fraústo da Silva, A.J.L.
Pombeiro, “Bioinspired Oxidations Catalysed by Non-Heme Fe, Cu and V Metal Centres”, XII
Regional Seminar of PhD Students on Organometallic and Coordination Chemistry, Szklarska
Poreba, Poland, 2009, OP24.
K. V. Luzyanin, A. G. Tskhovrebov, M. F. C. Guedes da Silva, M. Haukka, V. Yu. Kukushkin,
A. J. L. Pombeiro, “Metal-mediated [2+3] Cycloaddition of Nitrones to Palladium-bound
Isonitriles”, 8th Inorganic Chemistry Conference, Curia, Portugal, 2009, p. 124.
M. Gajewska, K.V. Luzyanin, M.F.C. Guedes da Silva, Q. Li, J. Cui, A.J.L. Pombeiro,
“Synthesis, Characterization and Biological Activity of Diorganotin(IV) Complexes with
Oximehydroxamate Ligands”, VII International Congress of Young Chemists (YoungChem
2009), Warsaw, Poland, 2009, P07, p.66.
P. J. Figiel, M.N. Kopylovich, J. Lasri, M.F.C. Guedes da Silva, A.J.L. Pombeiro, “Green
Protocols for the Oxidation of Alcohols Catalysed by Copper(II) 1,3,5-Triazapentadienato
Complexes”, 10th European Meeting on Environmental Chemistry (EMEC), Limoges, France,
2009, ID:147, p.87.
2010
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E.C.B.A. Alegria, M.F.C. Guedes da Silva, M.L. Kuznetov, L.M.D.R.S. Martins, C. Sousa
A.J.L. Pombeiro “Electrochemical, Termodynamic and Kinetic Studies of the Acylated
Cyanoimido-Complexes trans- Mo(NCN){NCNC(O)R}(dppe)2Cl” XII Iberic Meeting of
Electrochemistry & XVI Meeting of the Portuguese Electrochemical Society, I.S.E.L., 8–11,
September, 2010, Lisbon, Portugal. (Oral)
R.R. Fernandes, J. Lasri, M.F.C. Guedes da Silva, A.M.F. Palavra, J.A.L. da Silva, A.J.L.
Pombeiro, “Oxadiazoline and ketoimine Pd(II) complexes as highly efficient catalysts for
Suzuki-Miyaura cross-couplings in scCO2” Green Solvents Conference, Berchtesgaden
(Germany), 10-13 October 2010. Book of Abstract: P37. (Oral)
M. Gajewska, K.V. Luzyanin, K.T. Mahmudov, M.N. Kopylovich, M.F.C. Guedes da Silva, Q.
Li, J. Cui, A.J.L. Pombeiro “Synthesis, characterization and biological activity of
diorganotin(IV) complexes with polyfunctional ligands” XXIV International Conference on
Organometallic Chemistry, July, 2010, Taipei, PS2-164.
L.M.D.R.S. Martins, T.F.S. Silva, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Greener
cyclohexane partial oxidation: use of Co scorpionate catalysts” XVI Encontro Luso-Galego de
Química, Aveiro-Portugal, November 10th-12th, 2010, Book of Abstracts CT4. (Oral)
B.G.M. Rocha, R. Wanke, M.F.C. Guedes da Silva, L.M.D.R.S Martins. A.J.L. Pombeiro
“Synthesis and coordination chemistry of the sterically hindered scorpionate ligand Li[Tpms Ph]
towards NiII, ZnII and CuII metal centres” 2PYCheM, P. Y. C. M., Ed Aveiro, Portugal 2010.
(Oral)
E.C.B.A. Alegria, X. Shang, X. Meng, Q. Li, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Redox
properties of antitumor active organotin(IV) complexes containing 1-(4-chlorophenyl)-1cyclopentanecarboxylato ligands” XII Iberian Meeting of Electrochemistry & XVI Meeting of
the Portuguese Electrochemical Society, I.S.E.L., 8–11, September, 2010, Lisbon, Portugal.
M.F.C. Guedes da Silva, A.M. Kirillov, P. Smoleński, Ł. Jaremko, M. Haukka, Z. Ma, A.J.L.
Pombeiro “Copper compounds bearing 1,3,5-triaza-7-phosphaadamantane (PTA) and derived
ligands: synthesis, structural features and applications” 24th International Conference on
Organometallic Chemistry (ICOMC), July 18-23, 2010, Taipei, Taiwan. PS2-052.
M.N. Kopylovich, K.T. Mahmudov, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, M.L.
Kuznetsov, T.F.S. Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro “Electrochemical behaviour of
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para-substituted 3-(phenylhydrazo)pentane-2,4-diones” XII Iberic Meeting of Electrochemistry
& XVI Meeting of the Portuguese Electrochemical Society, September 8–11, 2010, ISEL Lisboa, p. 99.
M.F.C. Guedes da Silva, K.V. Luzyanin, M.L. Kuznetsov, A.G. Tskhovrebov, V.Yu.
Kukushkin, A.J.L. Pombeiro “Heterocarbene-palladium(II) complexes upon [2 + 3] metalmediated cycloaddition of nitrones to isonitriles” 24th International Conference on
Organometallic Chemistry, July 18th–23rd, 2010, Taipei, Taiwan. PS1-056.
K.V. Luzyanin, A.G. Tskhovrebov, M. Haukka, M.F.C. Guedes da Silva, A.J.L. Pombeiro,
V.Yu. Kukushkin “A route to novel palladocarbenes based on [2 + 3] cycloaddition of nitrones
to palladium-bound isonitriles” Development of new pharmaceuticals and biologically active
species based on naturally occurred compounds. ChemWasteChem – Chemistry and full
transformation of wood biomass, June 14th–18th, 2010, St. Petersburg, Russia. p.349.
K.V. Luzyanin, A.G. Tskhovrebov, M.F.C. Guedes da Silva, M. Haukka, A.J.L. Pombeiro,
V.Yu. Kukushkin “First example of the metal-mediated [2+3] cycloaddition of nitrones to
palladium-bound isonitriles” National Favorsky Conference on Organic Chemistry, March
23rd–26th, 2010, St. Petersburg, Russia.
L.M.D.R.S. Martins, T.F.S. Silva, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Coordination
chemistry of the C-scorpionate 2,2,2-tris(1-pyrazolyl)ethylmethanesulfonate towards the first
row transition metals” 3rd EuCheMS Chemistry Congress, Nürnberg-Germany, August 29th September 2nd, 2010, poster VIIb.061, p.94.
D.S. Nesterov, M.F.C. Guedes da Silva, J. Jezierska, A.J.L. Pombeiro “Polynuclear selfassembled Cu4, Cu6 and Cu8 complexes with aminoalcohols” 3rd EuCheMS Chemistry Congress,
Nurnberg, Germany, 2010.
T.F.S. Silva, K.V. Luzyanin, M.V. Kirillova, M.F.C. Guedes da Silva, L.M.D.R.S. Martins,
A.J.L. Pombeiro “Dioxovanadium complexes with scorpionate or pyrazole ligands as catalysts
for the carboxylation of alkanes” V7 – 7th International Vanadium Symposium, Toyama-Japan,
October 6th-9th, 2010. p.27.
T.F.S. Silva, T.C.O. Mac Leod, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro
“Vanadium-pyrazole
or
-tris(pyrazolyl)ethanol
complexes
immobilized
on
a
poly(dimethylsiloxane) membrane as supported catalysts for oxidation of cyclohexane” V7 – 7th
International Vanadium Symposium, Toyama-Japan, October 6th-9th, 2010. p.28.
T.F.S. Silva, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Electrochemical
behaviour of cobalt towards tris(1-pyrazolyl)methanesulfonate, 2,2,2-tris(1-pyrazolyl)ethanol or
tris(3-phenylpyrazolyl)methane complexes” XII Iberian Meeting of Electrochemistry & XVI
Meeting of the Portuguese Electrochemical Society, Lisbon-Portugal, September 9th-11th, 2010.
PE 06.
T.F.S. Silva, K.V. Luzyanin, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro
“Electrochemical behaviour of the novel scorpionate and pyrazole dioxovanadium complexes”
XII Iberian Meeting of Electrochemistry & XVI Meeting of the Portuguese Electrochemical
Society, Lisbon-Portugal, September 9th-11th, 2010. PE 08.
T.F.S. Silva, K.V. Luzyanin, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro
“New functionalized C-scorpionate cobalt complexes” 3rd EuCheMS Chemistry Congress,
Nürnberg-Germany, August 29th-September 2nd, 2010, poster VIIb.081. P.94.
A.J.L. Pombeiro, T.F.S. Silva, K.V. Luzyanin, L.M.D.R.S. Martins, M.F.C. Guedes da Silva,
“Cyclohexane Functionalization to Cyclohexanol and Cyclohexanone Catalysed by HydroSoluble Scorpionate Complexes” ICOMC - 24th International Conference on Organometallic
Chemistry, Taipei - Taiwan, July 18th-23rd, 2010. PS1-163.
P. Smoleński, A. Lis, M.F.C. Guedes da Silva, A.M. Kirillov, A.J.L. Pombeiro “Design of
silver(I)-PTA and copper(I)-PTA coordination polymers through controlled N,P-coordination of
1,3,5-triaza-7-phosphaadamantane (PTA) with various heterocycle ligands” XVII International
Winter School on Coordination Chemistry, December 6-10, 2010, Karpacz, Poland. P-31.
Curriculum Vitae
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151
2011
152
153
154
155
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157
2012
158
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P. Smoleński, A.M. Kirillov, Z. Ma, M.F.C. Guedes da Silva, M. Haukka, A.J.L. Pombeiro
“Synthesis, crystal structures and photoluminescence of new copper(I) iodide complexes
derived from N-alkyl-1,3,5-triaza-7-phosphaadamantanes” Excited States of Transition
Elements and Workshop on Luminescence, September 4-9, 2010, Wroclaw-Piechowice, Poland.
K.V. Luzyanin, M.L. Kuznetsov, A.G. Tskhovrebov, M.F.C. Guedes da Silva, A.J.L. Pombeiro,
V.Yu. Kukushkin “Heterocarbene-palladium(II) complexes upon [2 + 3] metal-mediated
cycloaddition of nitrones to isonitriles” 24th International Conference on Organometallic
Chemistry, July 18th–23rd, 2010, Taipei, Taiwan. PS1–056.
B.G.M. Rocha, K.V. Luzyanin, R. Wanke, M.F.C.G. Silva, L.M.D.R.S. Martins, A.J.L.
Pombeiro, “Bulky Tris(phenylpyrazolyl)methanesulfonate Copper Complexes with Unsaturated
Molecules”, 8th International School of Organometallic Chemistry, Camerino, Italy, August 2731st, 2011, p49.
E.C.B. Alegria, T. F. S. Silva, M. Fátima Guedes da Silva, L.M. D. R.S. Martins, A.J. L.
Pombeiro, “V, Re, Fe, Co, Ni, Cu and Zn complexes bearing 2,2,2-tris(1-pyrazolyl)ethyl
methanesulfonate scorpionates. Application as catalysts for the Baeyer-Villiger oxidation of
ketones under mild conditions” 5th EuCheMS Conference on Nitrogen Ligands in Coordination
Chemistry, Metal-Organic Chemistry, Bioinorganic Chemistry, Materials and Catalysis,
Granada – Spain, 4 – 8 Setembro 2011.
L.M.D.R.S. Martins, T.F.S. Silva, M.F.C.G. Silva, A.R. Fernandes, A. Silva, P.M. Borralho, S.
Santos, C.M.P. Rodrigues, A.J.L. Pombeiro, “Cobalt Complexes Bearing Scorpionate Ligands:
Synthesis, Characterization and Applications as Catalysts for the Peroxidative Oxidation of
Cyclohexane and as in vitro Tumor-Inhibitors”, 5th EuCheMS Conference on Nitrogen Ligands
in Coordination Chemistry, Metal-Organic Chemistry, Bioinorganic Chemistry, Materials and
Catalysis, Granada, Spain, 2011, P88, p. 184.
L.M.D.R.S. Martins, M. Fátima Guedes da Silva, T.F.S. Silva, C. Pettinari, F. Marchetti, A.
Cerquetella, A..L. Pombeiro “ELECTROCHEMICAL BEHAVIOUR OF C-SCORPIONATE
RUTHENIUM(II) COMPOUNDS” XXXII Reunión del Grupo de Electroquímica de la Real
Sociedada Española de Química – XIII Encontro Ibérico de Electroquímica, Murcia - Spain, 7 –
9 Setembro 2011.
X. Shang, E.C.B.A. Alegria, M.Fátima C. Guedes da Silva, M.L. Kuznetsov, X. Meng, Q. Li,
A.J.L. Pombeiro “Electrochemical behavior, theoretical study and antitumor activity of
organotin(IV) complexes bearing cyclopentanecarboxylato ligands” 62nd Annual Meeting of the
International Society of Electrochemistry, Niigata - Japan, 11 – 16 Setembro 2011 (oral
presentation by MFCGS)
P. Smoleński, A. M. Kirillov, A. Lis, Ł. Jaremko, M. F. C. Guedes da Silva, A. J. L. Pombeiro.
“Engineering coordination and supramolecular metal-organic networks by aqueous medium
selfassembly using 1,3,5-triaza-7-phosphaadamantane (PTA) with copper(I) and silver(I) salts”
XXIII International Conference on Coordination and Bioinorganic Chemistry, June 5-10, 2011,
Smolenice, Slovakia.
E.C.B.A. Alegria, X.i Shang,M. Fatima C. Guedes da Silva, M.L. Kuznetsov, Q. Li, A.J.L.
Pombeiro “REDOX PROPERTIES OF ORGANOTIN(IV) CYCLOALKYLHYDROXAMATE
COMPLEXES WITH DIFFERENT RING SIZES: ANTI-TUMOR ACTIVITY AND
REDUCTION POTENTIAL” XIV Iberian Meeting of Electrochemistry & XVII Meeting of the
Portuguese Electrochemical Society, 11 - 14 of April, 2012, Funchal, Madeira Island,
PORTUGAL.
M. Fátima C. Guedes da Silva, M. Gajewska, X. Shang, K.V. Luzyanin, Q. Li, J. Cui, A.J.L.
Pombeiro “Diorganotin(IV) Complexes Bearing Hydroxamate- or Carboxylate-type
Ligands:Structural and Biological Characterization XXV International Conference on
Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (S2. 6;
invited Satellite Communication presented by MFCGS).
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164
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166
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T. B. Anisimova, K.V. Luzyanin, M. Fátima C. Guedes da Silva, V. Yu. Kukushkin, A.J.L.
Pombeiro “Addition of the Amino Acid Esters to PdII-Complexed Isonitriles Leading to the
Chiral Aminocarbene Complexes” XXV International Conference on Organometallic Chemistry
(XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (F2.9; poster with flash presented by
TBA).
A.C. Silva, D.V. Luís, S. Santos, P.M. Borralho, C.M. Rodrigues, G. Cabral, P. Videira, A.S.
Rodrigues, M.Gajewska, M. Fátima C. Guedes da Silva, C. Monteiro, A.J.L. Pombeiro,
Alexandra
R.
Fernandes
“BIOLOGICAL
CHARACTERIZATION
OF
ANTIPROLIFERATIVE POTENCIAL OF A CYCLIC TRINUCLEAR ORGANOTIN(IV)
COMPLEX” XXV International Conference on Organometallic Chemistry (XXV-ICOMC), 2-7
Septembre 2012 Lisbon, Portugal (F3.27; poster with flash presented by ACS).
A.V.M. Nunes, E.C.B.A. Alegria, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L.
Pombeiro “New Trinuclear Mixed-Valence Cobalt(II)/(III) Complex Derived from
Arylhydrazone of Dimedone” XXV International Conference on Organometallic Chemistry
(XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.21; poster presented by AVMN).
Z.Ma, W. Lu, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “A Novel Palladium Compound
Assembled by PdCl2 and a Functionalized Cryptand” XXV International Conference on
Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.50;
poster presented by ZM).
B.G.M. Rocha, E.A. Valishina, M. Fátima C. Guedes da Silva, V. Yu. Kukushkin, A.J.L.
Pombeiro, K. V. Luzyanin, “New platinum-(acyclic aminocarbene) complexes derived from the
metal-mediated addition of hydrazones to isocyanides”XXV International Conference on
Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.61;
poster presented by BGMR).
O.V. Nesterova, M. Fátima C. Guedes da Silva, D.S. Nesterov, M.V. Kirillova, A.J.L.
Pombeiro, “Synthesis, Structure and Catalytic Activity of Novel Fe(III), Mn(III) and Cu(II)
Schiff Base Complexes” XXV International Conference on Organometallic Chemistry (XXVICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.84; poster presented by OVN).
A. Mizar, M.F.C. Guedes da Silva, M. N. Kopylovich, S. Mukherjee, K. T. Mahmudov, A.J.L.
Pombeiro “Water-Soluble Copper(II) Complexes with a Sulfonic-Functionalized Arylhydrazone
of -Diketone and Their Application in Peroxidative Allylic Oxidation” XXV International
Conference on Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon,
Portugal (PA.100; poster presented by AM).
T.C.O. Mac Leod, M.N. Kopylovich, M.F.C. Guedes Da Silva, K.T. Mahmudov, A.J.L.
Pombeiro “Copper(II) Complexes of Arylhydrazones of -Diketones Immobilized on Layered
Double Hydroxides as Catalysts for Oxidation of Alkanes” XXV International Conference on
Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.119;
poster presented by TCOML).
T.F.S. Silva, T.C.O. Mac Leod, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L.
Pombeiro “Oxo-Vanadium(IV) Complexes as Catalysts for Oxidation of Cyclohexane:
Homogeneous or Supported Systems” XXV International Conference on Organometallic
Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.136; poster presented by
TFSS).
P. Smolenski, A. Kirillov, S. Wieczorek, M.F.C. Guedes da Silva, Z. Ma, A.J.L. Pombeiro
“Coordination Engeenering with 1,3,5-Triaza-7-phosphaadamantane (PTA) Towards Unusual
Metal-Organic Networks” XXV International Conference on Organometallic Chemistry (XXVICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.164; poster presented by PS).
S.W. Wieczorek, A. Kirillov, M. Fátima C. Guedes da Silva, P. Smolenski, A.J.L. Pombeiro
“First Three-Dimensional Metal-Organic Frameworks Driven by 1,3,5-Triaza-7phosphaadamantane” XXV International Conference on Organometallic Chemistry (XXVICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.172; poster presented by SWW).
Curriculum Vitae
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T.F.S. Silva, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, B. J. Hwang, M.L. Kuznetsov,
A.J.L. Pombeiro “Cobalt Complexes Bearing C-Scorpionate or Pyrazole Ligands as Catalysts
for the Peroxidative Oxidation of Cyclohexane. EXAFS and Teorectical Studies” XXV
International Conference on Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012
Lisbon, Portugal (PA.267; poster presented by TFSS).
B.G.M. Rocha, T. C. O. Mac Leod, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L.
Pombeiro “Nitroaldol Reaction Studies of NiII, ZnII and CuII Complexes Bearing a Sterically
Hindered Scorpionate Ligand (TPMSph-“ XXV International Conference on Organometallic
Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.315; poster presented by
BGMR).
Z. Ma, F. Mai, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “A Novel Compound
Assembled by a Double-Helicate Terpyridine Silver(I) Compound and a Functionalized
Tetrapyridyl Cyclam” XXV International Conference on Organometallic Chemistry (XXVICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PB.5; poster presented by ZM).
M. Sutradhar, M. V. Kirillova, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “A Novel Mixed
Valence Hexanuclear Oxovanadium(IV,V) Complex Acts as Highly Efficient Catalyst in
Alkane Oxidation” XXV International Conference on Organometallic Chemistry (XXVICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PB.122; poster presented by MS).
K.T.
Mahmudov,
M.
Gajewska,
M.
Fátima
C.
Guedes
da
Silva,
M.N. Kopylovich, A.J.L. Pombeiro “ISOMORPHOUS HYBRID ORGANOTIN(IV)-NITRATE
CLUSTERS” XXV International Conference on Organometallic Chemistry (XXV-ICOMC), 27 Septembre 2012 Lisbon, Portugal (PB.197; poster presented by KTM).
K.T. Mahmudov, A.J.L. Pombeiro, M.J. Gajewska, M. Fátima C. Guedes da Silva,
A.M. Maharramov, I.N. Aliyeva, M.N. Kopylovich, “COMPOSITE OLIGOMER
CONSTRUCTED FROM TRI- AND TETRANUCLEAR BUTYLTIN(IV) OXOCLUSTERS”
XXV International Conference on Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre
2012 Lisbon, Portugal (PB.258; poster presented by KTM).
J.F. Silva, A.C. Silva, D.V. Luís, S. Santos, P.M. Borralho, C.M. Rodrigues, G. Cabral, P.
Videira, A.S. Rodrigues, J. Lasri, A. Charmier, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro,
Alexandra R. Fernandes “Characterization of the Antiproliferative Potential and Biological
Targets of a New Platinum Complex” XXV International Conference on Organometallic
Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PB.293; poster presented by
JFS).
T.B. Anisimova, M.F.C. Guedes Da Silva, A.J.L. Pombeiro, V.Yu. Kukushkin, K.V. Luzyanin,
“NOVEL CHIRAL AMINOCARBENE COMPLEXES DERIVED FROM THE COUPLING
OF AMINO ACID ESTERS WITH ISONITRILES”, International Conference Catalysis in
Organic Synthesis - ICCOS-2012, September 15-20, 2012, Moscow. P15. (poster presented by
TBA).
M.
Fátima
C.
Guedes
da
Silva,
K.T.
Mahmudov, M.N.
Kopylovich,
A.J.L. Pombeiro “Discrimination of Metal-Organic Architectures Bearing an Arylhydrazone of
-Diketone” Post-conference Symposium “Frontiers of Organometallic Chemistry” Septembre, SaintPetersburg, Russia (poster presented by MFCGS).
A. Silva, D. Luís, S. Santos, T. Silva, M.F.C. Guedes da Silva, L. Martins, A.J.L. Pombeiro, P.
Borralho, C.M. Rodrigues, G. Cabral, P. Videira, C. Monteiro7, A.R. Fernandes “Biological
characterization of the antiproliferative potential of Co(II) and Tin(IV) coordination
compounds” SantoriniConference Biologie Prospective – Systems Biology and Personalized
Health Science and Translation, 30 Sept – 2 Oct 2012, Santorini, Greece.
Curriculum Vitae
Maria de Fátima Costa Guedes da Silva
46 / 47
V- OTHER WORKS
V.1
V.2
V.3
V.4
M. Fátima C. Guedes da Silva, “Síntese e Electroquímica de Complexos Nitrílicos de Rénio(I)",
Tese de Mestrado, IST, 1989.
M. Fátima C. Guedes da Silva, "Química e Electroquímica Molecular de Complexos Derivados
da Activação de Nitrilos, Metilenoamidas e Diazoalcanos", Tese de Doutoramento, IST, 1993.
M. Fátima C. Guedes da Silva, "Book Review: Inorganic Syntheses, Volume 29", Inorganica
Chimica Acta, 206 (1993) 237.
M. Fátima C. Guedes da Silva, “Voltametría Cíclica – Aplicações ao Estudo de Mecanismos de
Reacções Induzidas por Transferência Electrónica” Química, 70 (1998) 21-26.
2636 citations (158 publications found); average citations per publication = 16.685;
h-index = 27 (ISI Web of Knowledge, February 18th, 2013)
Published Items in Each Year
The latest 20 years are displayed.
Results found: 158
Sum of the Times Cited : 2636
Sum of Times Cited without self-citation : 1976
Citing Article : 1373
Citing Articles without self-citations : 1245
Average Citations per Item : 16.685
h-index : 27
Citations in Each Year